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公开(公告)号：US08894194B2
公开(公告)日：2014-11-25
申请号：US13379960
申请日：2009-06-26
IPC分类号： C09D11/00 , C09D11/30 , C08F212/08
CPC分类号： C09D11/30 , C08F212/08 , C08F220/06 , C08F220/28
摘要： The present disclosure includes compositions, methods, and systems including an ink-jet ink comprising a liquid vehicle, a colorant dispersed or dissolved in a liquid vehicle, and self cross-linkable latex particles dispersed in the liquid vehicle. The self cross-linkable latex particle can have at least 0.1 wt % of the self cross-linkable monomer on the surface of the self cross-linkable latex particle providing cross-linking sites on the surface of the self cross-linkable latex particle, and can form an intra- and inter-particle cross-linked latex polymer film after printing the ink-jet ink on a substrate and upon at least partial depletion of the liquid vehicle or a liquid vehicle component.
摘要翻译： 本公开包括组合物，方法和系统，包括包含液体载体，分散或溶解在液体载体中的着色剂和分散在液体载体中的自交联胶乳颗粒的喷墨油墨。 自交联胶乳颗粒可以在自交联胶乳颗粒的表面上具有至少0.1重量％的自交联单体，其提供在自交联胶乳颗粒的表面上的交联位点，以及 在将喷墨油墨印刷在基材上并且至少部分消耗液体载体或液体载体组分之后，可以形成颗粒内和颗粒间交联的胶乳聚合物膜。
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2.发明授权Latex polymer with specific composition for inkjet printing on vinyl media 有权具有特殊组成的胶乳聚合物用于乙烯基介质上的喷墨印刷公开(公告)号：US08258204B2
公开(公告)日：2012-09-04
申请号：US12685530
申请日：2010-01-11
申请人： Sivapackia Ganapathiappan , Howard S. Tom , Hou Ng
发明人： Sivapackia Ganapathiappan , Howard S. Tom , Hou Ng
IPC分类号： C09D11/10
CPC分类号： B41M7/00 , B41M7/0054 , C09D11/30 , C09D11/322
摘要： An inkjet printing composition comprises an aqueous liquid vehicle; at least one pigment having a concentration of about 1 to 5 wt %; and a latex polymer having a concentration of about 2.5 to 8 wt % and comprising a polymerized mixture of styrene, butyl acrylate, at least one of methacrylonitrile and acrylonitrile, methacrylic acid, and ethylene glycol dimethacrylate. An inkjet ink printing system comprises a vinyl medium; the at least one inkjet printing composition; and a heating device, wherein the system is configured such that upon applying heat from the heating device to the inkjet ink printed on the vinyl medium, the latex particles fuse, thereby forming a printed image with a film encapsulating at least a portion of the pigment on the vinyl medium. A method of forming a printed image of the latex polymer using the inkjet ink printing system is also provided.
摘要翻译： 喷墨印刷组合物包含水性液体载体; 至少一种浓度为约1至5重量％的颜料; 和具有约2.5至8重量％的浓度并包含苯乙烯，丙烯酸丁酯，至少一种甲基丙烯腈和丙烯腈，甲基丙烯酸和乙二醇二甲基丙烯酸酯的聚合混合物的胶乳聚合物。 一种喷墨油墨印刷系统，包括乙烯基介质; 所述至少一种喷墨印刷组合物; 以及加热装置，其中所述系统构造成使得在将加热装置的热量加热到印刷在所述乙烯基介质上的喷墨油墨时，所述胶乳颗粒熔化，由此形成具有包封所述颜料的至少一部分的膜的印刷图像 在乙烯基介质上。 还提供了使用喷墨油墨印刷系统形成胶乳聚合物的印刷图像的方法。
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公开(公告)号：US20120092412A1
公开(公告)日：2012-04-19
申请号：US13379960
申请日：2009-06-26
CPC分类号： C09D11/30 , C08F212/08 , C08F220/06 , C08F220/28
摘要： The present disclosure includes compositions, methods, and systems including an ink-jet ink comprising a liquid vehicle, a colorant dispersed or dissolved in a liquid vehicle, and self cross-linkable latex particles dispersed in the liquid vehicle. The self cross-linkable latex particle can have at least 0.1 wt % of the self cross-linkable monomer on the surface of the self cross-linkable latex particle providing cross-linking sites on the surface of the self cross-linkable latex particle, and can form an intra- and inter-particle cross-linked latex polymer film after printing the ink-jet ink on a substrate and upon at least partial depletion of the liquid vehicle or a liquid vehicle component.
摘要翻译： 本公开包括组合物，方法和系统，包括包含液体载体，分散或溶解在液体载体中的着色剂和分散在液体载体中的自交联胶乳颗粒的喷墨油墨。 自交联胶乳颗粒可以在自交联胶乳颗粒的表面上具有至少0.1重量％的自交联单体，其提供在自交联胶乳颗粒的表面上的交联位点，以及 在将喷墨油墨印刷在基材上并且至少部分消耗液体载体或液体载体组分之后，可以形成颗粒内和颗粒间交联的胶乳聚合物膜。
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公开(公告)号：US09133344B2
公开(公告)日：2015-09-15
申请号：US13379950
申请日：2009-06-26
IPC分类号： B41J2/01 , C09B47/04 , B41J2/21 , B41J11/00 , C09B7/00 , C09D7/12 , C09D11/101 , C09D11/328 , C08K5/00
CPC分类号： C09B47/045 , B41J2/2107 , B41J11/002 , C08K5/0091 , C09B7/00 , C09D7/63 , C09D11/101 , C09D11/328
摘要： The present disclosure is drawn to methods and compositions directed at durable ink-jet inks. As such, an ink-jet ink can have a liquid vehicle, a colorant dispersed or dissolved in the liquid vehicle, a high Tg polymer having a Tg of at least 45.degree. C. dispersed in the liquid vehicle, and a near-infrared absorbing dye in the liquid vehicle. The ink can be formulated such that when printed on a substrate and irradiated with a near-infrared energy source, the near-infrared absorbing dye generates enough heat to uniformly melt the high Tg polymer, thereby enhancing the durability of ink-jet ink printed on the substrate.
摘要翻译： 本公开涉及针对耐久喷墨油墨的方法和组合物。 因此，喷墨油墨可以具有液体载体，分散或溶解在液体载体中的着色剂，Tg高达45度的高Tg聚合物。 C.分散在液体载体中的液体载体中的近红外吸收染料。 油墨可以配制成使得当印刷在基底上并用近红外能量源照射时，近红外吸收染料产生足够的热量以均匀熔化高Tg聚合物，从而提高印刷在上的喷墨油墨的耐久性 底物。
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公开(公告)号：US08944579B2
公开(公告)日：2015-02-03
申请号：US13384856
申请日：2009-08-18
IPC分类号： B41J2/01 , C08F220/28 , B41J2/21 , C09D11/30 , C09D133/06 , B41M5/00 , B41M7/00 , C08F212/08
CPC分类号： C08F220/28 , B41J2/2107 , B41M5/0023 , B41M7/009 , C08F212/08 , C09D11/30 , C09D133/062 , C08F2220/1825 , C08F2220/283 , C08F220/44 , C08F222/1006
摘要： The present disclosure includes compositions, methods, and systems having an ink-jet ink including a liquid vehicle, a colorant dispersed or dissolved in the liquid vehicle, inter-crosslinkable latex particles dispersed in the liquid vehicle, and an inter-particle crosslinker. The inter-crosslinkable latex particles can have at least one hydrophobic monomer; at least one acidic monomer; at least one inter-crosslinkable monomer including at least one keto group; the inter-crosslinkable monomer having the structure described in Formula 1. Additionally, the inter-crosslinkable latex particles can be intra-crosslinked forming an inter-particle crosslinked latex polymer film after printing and upon at least partial depletion of the liquid vehicle or liquid vehicle component.
摘要翻译： 本公开内容包括具有包括液体载体，分散或溶解在液体载体中的着色剂，分散在液体载体中的相互交联的胶乳颗粒和颗粒间交联剂的喷墨油墨的组合物，方法和系统。 相互交联的胶乳颗粒可以具有至少一种疏水单体; 至少一种酸性单体; 至少一种包含至少一个酮基的相互交联的单体; 具有式1所述结构的相互交联的单体。此外，交联后胶乳颗粒可以在印刷后形成颗粒间交联的胶乳聚合物膜，并且至少部分消耗液体载体或液体载体 零件。
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公开(公告)号：US20120147108A1
公开(公告)日：2012-06-14
申请号：US13383691
申请日：2009-09-03
IPC分类号： B41J2/01
CPC分类号： B41M7/009 , B41J2/2107 , B41J11/002 , B41M5/0047 , B41M5/0064 , B41M7/0027 , C09D11/033 , C09D11/322
摘要： An ink-jet ink printing method and associated system can comprise a printer including an ink-jet ink. The ink comprises an aqueous liquid vehicle, 1 wt % to 5 wt % pigment, 1 wt % to 5 wt % acrylic polymer particles, 0.3 wt % to 3 wt % urethane polymer particles, and is formulated to print on a vinyl medium. The system also includes a heating device. Upon applying heat to the ink-jet ink printed on the vinyl medium, the polymer particles in the printed ink fuse, and form a film encapsulating at least a portion of the pigment on the vinyl print medium.
摘要翻译： 喷墨印刷方法和相关系统可以包括包括喷墨墨水的打印机。 油墨包含水性液体载体，1重量％至5重量％的颜料，1重量％至5重量％的丙烯酸聚合物颗粒，0.3重量％至3重量％的聚氨酯聚合物颗粒，并配制成在乙烯基介质上印刷。 该系统还包括加热装置。 在对印刷在乙烯基介质上的喷墨油墨进行加热时，印刷油墨中的聚合物颗粒熔化，并形成在乙烯基印刷介质上包封颜料的至少一部分的膜。
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公开(公告)号：US20120116012A1
公开(公告)日：2012-05-10
申请号：US13384586
申请日：2009-07-30
CPC分类号： C09D11/324 , C01P2004/50 , C08K9/08 , C08K9/10 , C09C3/10 , C09D7/62 , C09D7/63 , C09D7/67 , C09D7/68 , C09D11/322
摘要： Polymer-encapsulated pigment which includes a pigment core and a polymer shell, the shell being a polymerized polymer including hydrophobic monomers and acidic monomers, and also including a specific cross-linking agent.
摘要翻译： 聚合物包封的颜料包括颜料芯和聚合物壳，壳是包含疏水性单体和酸性单体的聚合聚合物，并且还包括特定的交联剂。
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公开(公告)号：US20120092428A1
公开(公告)日：2012-04-19
申请号：US13379950
申请日：2009-06-26
CPC分类号： C09B47/045 , B41J2/2107 , B41J11/002 , C08K5/0091 , C09B7/00 , C09D7/63 , C09D11/101 , C09D11/328
摘要： The present disclosure is drawn to methods and compositions directed at durable ink-jet inks. As such, an ink-jet ink can comprise a liquid vehicle, a colorant dispersed or dissolved in the liquid vehicle, a high Tg polymer having a Tg of at least 45° C. dispersed in the liquid vehicle, and a near-infrared absorbing dye in the liquid vehicle. The ink can be formulated such that when printed on a substrate and irradiated with a near-infrared energy source, the near-infrared absorbing dye generates enough heat to uniformly melt the high Tg polymer, thereby enhancing the durability of ink-jet ink printed on the substrate.
摘要翻译： 本公开涉及针对耐久喷墨油墨的方法和组合物。 因此，喷墨油墨可以包括液体载体，分散或溶解在液体载体中的着色剂，分散在液体载体中的Tg至少为45℃的高Tg聚合物和近红外吸收 在液体载体中染色。 油墨可以配制成使得当印刷在基底上并用近红外能量源照射时，近红外吸收染料产生足够的热量以均匀熔化高Tg聚合物，从而提高印刷在上的喷墨油墨的耐久性 底物。
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9.发明申请LATEX POLYMER WITH SPECIFIC COMPOSITION FOR INKJET PRINTING ON VINYL MEDIA 有权具有特殊组成的LATEX聚合物用于在VINYL介质上进行喷墨打印公开(公告)号：US20110171386A1
公开(公告)日：2011-07-14
申请号：US12685530
申请日：2010-01-11
申请人： Sivapackia Ganapathiappan , Howard S. Tom , Hou Ng
发明人： Sivapackia Ganapathiappan , Howard S. Tom , Hou Ng
CPC分类号： B41M7/00 , B41M7/0054 , C09D11/30 , C09D11/322
摘要： An inkjet printing composition comprises an aqueous liquid vehicle; at least one pigment having a concentration of about 1 to 5 wt %; and a latex polymer having a concentration of about 2.5 to 8 wt % and comprising a polymerized mixture of styrene, butyl acrylate, at least one of methacrylonitrile and acrylonitrile, methacrylic acid, and ethylene glycol dimethacrylate. An inkjet ink printing system comprises a vinyl medium; the at least one inkjet printing composition; and a heating device, wherein the system is configured such that upon applying heat from the heating device to the inkjet ink printed on the vinyl medium, the latex particles fuse, thereby forming a printed image with a film encapsulating at least a portion of the pigment on the vinyl medium. A method of forming a printed image of the latex polymer using the inkjet ink printing system is also provided.
摘要翻译： 喷墨印刷组合物包含水性液体载体; 至少一种浓度为约1至5重量％的颜料; 和具有约2.5至8重量％的浓度并包含苯乙烯，丙烯酸丁酯，至少一种甲基丙烯腈和丙烯腈，甲基丙烯酸和乙二醇二甲基丙烯酸酯的聚合混合物的胶乳聚合物。 一种喷墨油墨印刷系统，包括乙烯基介质; 所述至少一种喷墨印刷组合物; 以及加热装置，其中所述系统构造成使得在将加热装置的热量加热到印刷在所述乙烯基介质上的喷墨油墨时，所述胶乳颗粒熔化，由此形成具有包封所述颜料的至少一部分的膜的印刷图像 在乙烯基介质上。 还提供了使用喷墨油墨印刷系统形成胶乳聚合物的印刷图像的方法。
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10.发明申请公开(公告)号：US20110012955A1
公开(公告)日：2011-01-20
申请号：US12922088
申请日：2008-04-18
CPC分类号： C09D11/00 , B41M7/0054 , C09D11/54
摘要： Compositions, systems, and methods for improving dry rub resistance and resistance to highlighter smear of a printed image on a substrate are provided. The overcoating composition can comprise an aqueous-based liquid vehicle and about 0.5 wt % to about 40 wt % latex polymer particles dispersed in the liquid vehicle. The latex polymer particles can include about 18 wt % to about 99.5 wt % polymerized hydrophobic monomers selected from the group of 4-methylstyrene, cyclohexyl acrylate, isobornyl methacrylate, isobornyl acrylate, and combinations thereof, about 0.1 wt % to about 20 wt % polymerized acid monomers. The overcoating composition can be formulated to be ink-jetted onto the substrate and is substantially devoid of colorant.
摘要翻译： 提供了用于改善基材上的印刷图像的耐干摩擦性和抗荧光笔污迹的组合物，系统和方法。 外涂组合物可以包含水性液体载体和分散在液体载体中的约0.5重量％至约40重量％的胶乳聚合物颗粒。 胶乳聚合物颗粒可包括约18重量％至约99.5重量％的聚合疏水单体，其选自4-甲基苯乙烯，环己基丙烯酸酯，甲基丙烯酸异冰片酯，丙烯酸异冰片酯及其组合，约0.1重量％至约20重量％ 酸性单体。 外敷组合物可以配制成喷墨到基材上，并且基本上没有着色剂。
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