Fungicidal piperidine derivatives
    2.
    发明授权
    Fungicidal piperidine derivatives 失效
    杀真菌哌啶衍生物

    公开(公告)号:US4673683A

    公开(公告)日:1987-06-16

    申请号:US772714

    申请日:1985-09-05

    摘要: R.sup.2 and R.sup.3 are hydrogen or alkyl,R.sup.4 is hydrogen, alkyl, alkenyl, alkynyl, haloalkyl, haloalkenyl, unsubstituted or substituted aralkyl, COR.sup.5, CO.sub.2 R.sup.6 or CONR.sup.7 R.sup.8,R.sup.5 and R.sup.6 are alkyl, unsubstituted or substituted aryl or unsubstituted or substituted aralkyl,R.sup.7 and R.sup.8 are hydrogen, alkyl, unsubstituted or substituted aryl or unsubstituted or substituted aralkyl andn is 0, 1, 2 or 3,and its plant-tolerated acid addition salts, excluding the compounds where, simultaneously, R.sup.4 is hydrogen, acetyl or propionyl, n is 0 or 1 and R.sup.1, R.sup.2 and R.sup.3 are hydrogen, and fungicides containing the novel piperidines and salts.

    摘要翻译: 其中R1是氢,烷基或卤素,R2和R3是氢或烷基,R4是氢,烷基,烯基,炔基,卤代烷基,卤代烯基,未取代的或取代的芳烷基,COR5,CO2R6或CONR7R8,R5和R6是烷基 ,未取代或取代的芳基或未取代或取代的芳烷基,R 7和R 8为氢,烷基,未取代或取代的芳基或未取代或取代的芳烷基,n为0,1,2或3及其植物耐受酸加成盐, 其中R4同时为氢,乙酰基或丙酰基,n为0或1,R1,R2和R3为氢的化合物,以及含有新颖的哌啶类和盐类的杀真菌剂。

    Breaking down aromatic compounds in industrial wastewaters
    3.
    发明授权
    Breaking down aromatic compounds in industrial wastewaters 有权
    打破工业废水中的芳香族化合物

    公开(公告)号:US06258281B1

    公开(公告)日:2001-07-10

    申请号:US09336722

    申请日:1999-06-21

    IPC分类号: C02F178

    CPC分类号: C02F1/78 Y10S210/909

    摘要: A process for breaking down aromatics in industrial wastewaters that contain small amounts of aromatics by reaction with an ozone-containing oxygen stream at a temperature of from 40 to 70° C. and at a pH of from 4 to 7, involves treating industrial wastewaters that contain small amounts of aromatics in two stages with an oxygen stream that contains from 5 to 8% by volume of ozone with thorough mixing by causing the wastewater to flow upward through two reaction zones, the overflow of the wastewater at the top of the first reaction zone entering the second reaction zone at the base, the purified wastewater being obtained at the top of the second reaction zone, the ozone-containing oxygen stream first entering at the base of the second reaction zone, and the waste gas obtained at the top of the second reactor being introduced at the base of the first reaction zone, and, furthermore, a gas containing less than 0.2% by volume of ozone being obtained at the top of the first reaction zone.

    摘要翻译: 在-40〜70℃,pH4〜7的温度下,通过与含臭氧的氧气流反应而含有少量芳族化合物的工业废水中的芳族化合物的分解方法涉及处理工业废水, 在两个阶段中含有少量芳烃,其中含有5-8%(体积)臭氧的氧气,通过使废水通过两个反应区向上流动而充分混合,第一反应顶部的废水溢出 进入第二反应区的第二反应区的第二反应区的第二反应区的净化废水,在第二反应区的顶部得到的纯化废水,首先进入第二反应区的碱的含臭氧的氧流, 第二反应器被引入第一反应区的底部,此外,在第一反应区的顶部获得含有小于0.2体积%的臭氧的气体。

    Oxidized polyethylene and use as lubricant for polyvinylchloride
    5.
    发明授权
    Oxidized polyethylene and use as lubricant for polyvinylchloride 失效
    氧化聚乙烯并用作聚氯乙烯的润滑剂

    公开(公告)号:US5064908A

    公开(公告)日:1991-11-12

    申请号:US608621

    申请日:1990-11-06

    CPC分类号: C08L27/06 C08F8/06 C08L23/30

    摘要: Oxidized polyethylenes useful as lubricants in the extrusion of polyvinyl chloride are prepared by oxidation of finely divided polyethylene of high density at elevated temperatures with an oxidation gas of air and/or oxygen, the polyethylene used containing from 0.015 to 0.5% by weight of a free radical former organic compound in admixture and being contacted per hour with an oxidation gas which per kilogram of polyethylene contains from 30 to 600, in particular from 80 to 300, mg of ozone, with or without a reduced pressure treatment at elevated temperatures after the oxidation.

    摘要翻译: 在聚氯乙烯挤出中可用作润滑剂的氧化聚乙烯通过在高温下用空气和/或氧气的氧化气体氧化高密度的细碎聚乙烯制备,所用聚乙烯含有0.015-0.5重量%的游离 基础前体的有机化合物混合并每小时与氧化气体接触,氧化气体每千克聚乙烯含有30至600,特别是80至300毫克臭氧,在氧化后在升高的温度下进行或不进行减压处理 。

    Manufacture of .alpha.-naphthol
    6.
    发明授权
    Manufacture of .alpha.-naphthol 失效
    制造{60-萘酚

    公开(公告)号:US4171458A

    公开(公告)日:1979-10-16

    申请号:US876759

    申请日:1978-02-10

    CPC分类号: C07C37/76 C07C37/0555

    摘要: Process for the manufacture of .alpha.-naphthol by hydrolyzing .alpha.-naphthyl esters of aliphatic carboxylic acids in a distillation column by means of steam in counter-current at a particular temperature, and in a certain ratio, in the presence of naphtholsulfonic acids and/or sulfonic acids of naphthyl esters. The .alpha.-naphthol obtainable by the process of the invention is a valuable starting material for the manufacture of dyes, drugs and insecticides, e.g. .alpha.-naphthyl N-methylcarbamate.

    摘要翻译: 通过在特定温度下以一定比例的蒸汽在蒸馏塔中水解脂肪族羧酸的α-萘基酯,并在一定比例的存在下,在萘酚磺酸和/或 萘酯的磺酸。 通过本发明的方法可获得的α-萘酚是用于制备染料,药物和杀虫剂的有价值的起始材料,例如, α-萘基N-甲基氨基甲酸酯。

    Preparation of N-substituted pyrrolidin-2-ones
    9.
    发明授权
    Preparation of N-substituted pyrrolidin-2-ones 失效
    N-取代的吡咯烷-2-酮的制备

    公开(公告)号:US5101044A

    公开(公告)日:1992-03-31

    申请号:US577589

    申请日:1990-09-04

    CPC分类号: C07D207/267 C07D207/38

    摘要: A process for the preparation of N-substituted pyrrolidin-2-ones of the general formula I ##STR1## where R.sup.1 is C.sub.1 - to C.sub.20 -alkyl, C.sub.6 - to C.sub.10 aryl or C.sub.7 - to C.sub.12 -aralkyl comprises hydrogenolytically cleaving 5-iminopyrrolidin-2-ones of the general formula II ##STR2## in which the R.sup.1 radicals are identical or different C.sub.1 - to C.sub.20 -alkyl, C.sub.6 - to C.sub.10 -aryl or C.sub.7 - to C.sub.12 -aralkyl, at super-atmospheric pressure and elevated temperature in the presence of a hydrogenation catalyst to give the pyrrolidin-2-ones I; specifically, the 5-iminopyrrolidin-2-ones of the formula II are obtained by reacting .beta.-cyanopropionic acid esters of the general formula III ##STR3## where R.sup.2 is C.sub.1 - to C.sub.20 -alkyl, C.sub.7 - to C.sub.12 -aralkyl or C.sub.6 - to C.sub.10 -aryl, with an amine of the general formula IVR.sup.1 --NH.sub.2 IVwhere R.sup.1 is as defined above.

    摘要翻译: 制备通式I的N-取代吡咯烷-2-酮的方法,其中R 1是C 1 -C 20烷基,C 6至C 10芳基或C 7 -C 12芳烷基包括氢解裂解5-亚氨基吡咯烷 其中R 1基团是相同或不同的C 1〜C 20 - 烷基,C 6〜C 10 - 芳基或C 7〜C 12 - 芳烷基,在超大气压下和升高的 在加氢催化剂存在下,得到吡咯烷-2-酮I; 具体地,式II的5-亚氨基吡咯烷-2-酮通过使通式III的β-氰基丙酸酯反应获得,其中R 2是C 1 -C 20烷基,C 7到C 12 - 芳烷基或C 6 - 至C10-芳基,与通式IV的R 1 -NH 2 IV的胺反应,其中R1如上定义。