公开(公告)号：US10047300B2

公开(公告)日：2018-08-14

申请号：US14347492

申请日：2012-10-12

申请人： INDIAN OIL CORPORATION LTD.

发明人： Madhusudan Sau ,  Ganesh Vitthalrao Butley ,  Yamini Gupta ,  Karumanchi Ramesh ,  Mainak Sarkar ,  Arangarasu Arun ,  Saeed Ahmed ,  Brijesh Kumar ,  Ravinder Kumar Malhotra

IPC分类号： C10G32/02 ,  C10G21/20 ,  C10G27/04 ,  C10G45/22 ,  C10G49/18

摘要： A novel process for metal content reduction of hydrocarbon oil is disclosed, which is primarily aimed at reduction of vanadium and nickel. The process uses electricity to accelerate the demetallation process, but only the flow of electrons of the electric current is used to expedite the reaction, instead of the electrolysis effect of the electric current. The process is carried out by adding inter-phase surface active reagent and phase transfer catalyst at a relatively low temperature range of 80 to 200° C. and achieves metal content reduction for vanadium and nickel. Aqueous phase alcoholic derivatives of amine solution is treated with hydrogen sulfide, carbon dioxide, etc. by additive reaction to render it more suitable for carrying more electric current and make them more active for metal reduction.

公开(公告)号：US20140231271A1

公开(公告)日：2014-08-21

申请号：US14347492

申请日：2012-10-12

申请人： INDIAN OIL CORPORATION LTD.

发明人： Madhusudan Sau ,  Ganesh Vitthalrao Butley ,  Yamini Gupta ,  Karumanchi Ramesh ,  Mainak Sarkar ,  Arangarasu Arun ,  Saeed Ahmed ,  Brijesh Kumar ,  Ravindra Kumar Malhotra

IPC分类号： C10G32/02

CPC分类号： C10G32/02 ,  C10G21/20 ,  C10G27/04 ,  C10G45/22 ,  C10G49/18 ,  C10G2300/1037 ,  C10G2300/205

摘要： A novel process for metal content reduction of hydrocarbon oil is disclosed, which is primarily aimed at reduction of vanadium and nickel. The process uses electricity to accelerate the demetallation process, but only the flow of electrons of the electric current is used to expedite the reaction, instead of the electrolysis effect of the electric current. The process is carried out by adding inter-phase surface active reagent and phase transfer catalyst at a relatively low temperature range of 80 to 200° C. and achieves metal content reduction for vanadium and nickel. Aqueous phase alcoholic derivatives of amine solution is treated with hydrogen sulfide, carbon dioxide, etc. by additive reaction to render it more suitable for carrying more electric current and make them more active for metal reduction.

摘要翻译： 公开了一种用于烃油的金属含量降低的新方法，其主要目的在于还原钒和镍。 该过程使用电力来加速脱金属过程，但是仅使用电流的电流来加速反应，而不是电流的电解效应。 该方法通过在80〜200℃的较低温度范围内添加相间表面活性剂和相转移催化剂进行，并实现钒和镍的金属含量降低。 通过添加反应，用硫化氢，二氧化碳等处理胺溶液的水相醇衍生物，使其更适合携带更多的电流，并使其更具有金属还原活性。

公开(公告)号：US20140248191A1

公开(公告)日：2014-09-04

申请号：US14347534

申请日：2012-10-12

申请人： INDIAN OIL CORPORATION LTD.

发明人： Madhusudan Sau ,  Ganesh V. Butley ,  Yamini Gupta ,  Karumanchi Ramesh ,  Mainak Sarkar ,  Arangarasu Arun ,  Brijesh Kumar ,  Ravinder Kumar Malhotra

IPC分类号： B01J19/08

CPC分类号： B01J19/088 ,  B01J12/00 ,  B01J19/087 ,  B01J19/18 ,  B01J2219/0805 ,  B01J2219/0809 ,  B01J2219/0815 ,  B01J2219/0835 ,  B01J2219/0841 ,  B01J2219/0869 ,  B01J2219/0877 ,  B01J2219/0884 ,  C10G21/00 ,  C10G27/04 ,  C10G32/02 ,  C10G53/14

摘要： A reactor assembly (1) for improving reaction between two immiscible phases for metal reduction of hydrocarbons is disclosed, which is a modification of a CSTR type reactor assembly. A third gaseous phase is also present in the reactor. Metal plates (5) are provided, mounted on supporting rods (6) which are electrically insulated from the rest of the reactor. The metal plates are made of the same metal to avoid detachment of metal atoms from metal plates. The metal plates serve as the means of transferring only the electrons from the metal plates to the liquids in which they are fully immersed, so that the reaction is made more efficient.

摘要翻译： 公开了用于改进用于金属还原烃的两个不混溶相之间的反应的反应器组件（1），其是CSTR型反应器组件的改进。 第三个气相也存在于反应器中。 提供金属板（5），安装在与反应器的其余部分电绝缘的支撑杆（6）上。 金属板由相同的金属制成，以避免金属原子与金属板分离。 金属板作为仅将电子从金属板传递到完全浸入其中的液体的手段，使得反应更有效率。