公开(公告)号：US11370879B2

公开(公告)日：2022-06-28

申请号：US16220069

申请日：2018-12-14

Applicant: International Business Machines Corporation

Inventor： Brandon M. Kobilka ,  Jacob T. Porter ,  Scott B. King ,  Jason T. Wertz

IPC: C08G61/12 ,  H01L51/00 ,  C07C13/70 ,  C07D513/04 ,  C07D409/10 ,  C07D495/04

Abstract: In an embodiment, a composition is provided that includes an indenofluorene moiety; an alkyl radical, an aryl radical, or a heteroaryl radical chemically bound to the indenofluorene moiety; and an electron donor moiety bound to the indenofluorene moiety. In another embodiment, a device is provided that includes compositions described herein. In another embodiment, a method of forming a donor-acceptor small molecule or a donor-acceptor copolymer is provided that includes forming an indenofluorene moiety; forming an electron donor moiety; and reacting the indenofluorene moiety with the electron donor moiety in a cross-coupling reaction.

公开(公告)号：US11312820B2

公开(公告)日：2022-04-26

申请号：US17130246

申请日：2020-12-22

Applicant: International Business Machines Corporation

Inventor： Brandon M. Kobilka ,  Jacob T. Porter ,  Scott B. King ,  Jason T. Wertz

IPC: C08G61/12 ,  H01L51/00 ,  C07C13/70 ,  C07D513/04 ,  C07D409/10 ,  C07D495/04

Abstract: In an embodiment, a composition is provided that includes an indenofluorene moiety; an alkyl radical, an aryl radical, or a heteroaryl radical chemically bound to the indenofluorene moiety; and an electron donor moiety bound to the indenofluorene moiety. In another embodiment, a device is provided that includes compositions described herein. In another embodiment, a method of forming a donor-acceptor small molecule or a donor-acceptor copolymer is provided that includes forming an indenofluorene moiety; forming an electron donor moiety; and reacting the indenofluorene moiety with the electron donor moiety in a cross-coupling reaction.

公开(公告)号：US10752776B2

公开(公告)日：2020-08-25

申请号：US16135131

申请日：2018-09-19

Applicant: International Business Machines Corporation

Inventor： Brandon M. Kobilka ,  Jacob T. Porter ,  Jason T. Wertz ,  Joseph Kuczynski

IPC: C08L87/00 ,  C08L57/00 ,  C08K5/5317 ,  C08K5/5313

Abstract: A bio-renewable flame-retardant compound is disclosed. The bio-renewable flame-retardant compound includes a cyclic structure formed in a reaction with a bio-renewable diene.

公开(公告)号：US10689578B2

公开(公告)日：2020-06-23

申请号：US16237695

申请日：2019-01-01

Applicant: International Business Machines Corporation

Inventor： Brandon M. Kobilka ,  Joseph Kuczynski ,  Jacob T. Porter ,  Jason T. Wertz

IPC: C09K21/12 ,  C07C15/04 ,  C07D317/12 ,  C08K5/5337 ,  C08K5/5317 ,  C08K5/5313 ,  C12P7/26 ,  C12P7/22 ,  C07F9/08 ,  C07F9/655 ,  C07F9/6558 ,  C07F9/12 ,  C07F9/14 ,  C07F9/145 ,  C07F9/40 ,  C07F9/42 ,  C09K21/14

Abstract: A flame-retardant vanillin-derived cross-linker, a process for forming a flame-retardant polymer, and an article of manufacture comprising a material that contains the flame-retardant vanillin-derived cross-linker are disclosed. The flame-retardant vanillin-derived cross-linker can be synthesized from vanillin obtained from a bio-based source, and can have at least one phosphoryl or phosphonyl moiety with phenyl, allyl, epoxide, propylene carbonate, or thioether substituents. The process for forming the flame-retardant polymer can include reacting a diol vanillin derivative and a flame-retardant phosphorus-based molecule to form the flame-retardant vanillin-derived cross-linker, and binding the flame-retardant vanillin-derived cross-linker to a polymer. The material in the article of manufacture can be flame-retardant, and contain flame-retardant vanillin-derived cross-linkers. Examples of materials that can be in the article of manufacture can include resins, plastics, adhesives, polymers, etc.

公开(公告)号：US20200087515A1

公开(公告)日：2020-03-19

申请号：US16135131

申请日：2018-09-19

Applicant: International Business Machines Corporation

Inventor： Brandon M. Kobilka ,  Jacob T. Porter ,  Jason T. Wertz ,  Joseph Kuczynski

IPC: C08L87/00 ,  C08L57/00 ,  C08K5/5313 ,  C08K5/5317

Abstract: A bio-renewable flame-retardant compound, a process for forming a bio-renewable flame-retardant compound, and an article of manufacture comprising a bio-renewable flame-retardant compound are disclosed. The bio-renewable flame-retardant compound includes a cyclic structure formed in a reaction with a bio-renewable diene. The process for forming a bio-renewable flame-retardant compound includes the selection and reaction of a bio-renewable diene, a dienophile, and optionally a phosphorus compound to form a cyclic compound, reacting the cyclic compound with a phosphorus compound to form a cyclic flame-retardant compound, and forming a bio-renewable flame-retardant polymer that includes the bio-renewable flame-retardant compound. The article of manufacture includes a material containing the bio-renewable flame-retardant compound.

公开(公告)号：US10584213B2

公开(公告)日：2020-03-10

申请号：US16100325

申请日：2018-08-10

Applicant: International Business Machines Corporation

Inventor： Jason T. Wertz ,  Brandon M. Kobilka ,  Joseph Kuczynski ,  Jacob T. Porter

IPC: C08G79/025 ,  C08G73/06 ,  C08G85/00 ,  C08J3/24 ,  C08L85/02

Abstract: An elastomer, a process for forming an elastomer, and an article of manufacture are disclosed. The elastomer comprises a phosphazene backbone and at least one polyhexahydrotriazine component. The process for forming the elastomer includes obtaining an amine-terminated cyclotriphosphazene, reacting it with a diamine to form a phosphazene-containing PHT polymer, and then reacting the phosphazene-containing PHT polymer with a side-chain modified cyclic phosphazene to form a PCPHT elastomer with halogen ligands. The PCPHT elastomer with halogen ligands is then reacted with an alkoxide to form a PCPHT elastomer with at least one ether-linked side chain. The article of manufacture comprises a material comprising an elastomer having a phosphazene backbone and at least one PHT component.

公开(公告)号：US20200071266A1

公开(公告)日：2020-03-05

申请号：US16674859

申请日：2019-11-05

Applicant: International Business Machines Corporation

Inventor： Brandon M. Kobilka ,  Joseph Kuczynski ,  Jacob T. Porter ,  Jason T. Wertz

IPC: C07C265/10 ,  C07C263/10 ,  C08G18/75 ,  C07C209/48 ,  C07C209/62 ,  C07C231/12 ,  C07C209/26 ,  C07C253/10 ,  C07C265/14

Abstract: A pinene-derived diisocyanate compound, a process for forming a pinene-derived polyurethane, and an article of manufacture that includes the polyurethane are disclosed. The process for forming the polyurethane includes forming a pinene-derived diisocyanate compound, and reacting the pinene-derived diisocyanate compound with a polyol in a polymerization compound.

公开(公告)号：US10413495B2

公开(公告)日：2019-09-17

申请号：US15353974

申请日：2016-11-17

Applicant: INTERNATIONAL BUSINESS MACHINES CORPORATION

Inventor： Scott B. King ,  Brandon M. Kobilka ,  Joseph Kuczynski ,  Jacob T. Porter ,  Jason T. Wertz

IPC: A61K8/40 ,  A61Q17/04 ,  A61K8/29 ,  A61K8/26 ,  A61K8/27 ,  A61K8/19 ,  A61K8/37 ,  A61K8/35 ,  A61K8/02

Abstract: A method for forming a photosensitizer product that is resistant to absorption by living tissue that may include binding a photosensitizer compound with an oxide-containing particle to provide the photosensitizer derivative having a microscale size, and mixing the photosensitizer derivative into a lotion. The microscale size of the photosensitizer derivative obstructs absorption by cell tissue.

公开(公告)号：US20190185497A1

公开(公告)日：2019-06-20

申请号：US15842356

申请日：2017-12-14

Applicant: International Business Machines Corporation

Inventor： Brandon M. Kobilka ,  Joseph Kuczynski ,  Jacob T. Porter ,  Jason T. Wertz

IPC: C07F9/32 ,  C07F9/40 ,  C07F9/655 ,  C08G79/04 ,  C08K5/5373 ,  C08K5/5357 ,  C08K5/5313 ,  C08J3/20

Abstract: A pinene-based flame retardant compound, a process for forming a flame retardant polymer, and an article of manufacture comprising a material that contains a pinene-based flame retardant polymer are disclosed. The pinene-based flame retardant compound includes a pinene derivative core and at least one flame retardant substituent having a phosphorus-based moiety. The process for forming the flame retardant polymer includes obtaining pinene, forming a derivative of pinene, obtaining a phosphorus-based compound, reacting the phosphorus-based compound and the pinene derivative to form a pinene-based flame retardant compound, and incorporating the pinene-based flame retardant compound into a polymer to form the pinene-based flame retardant polymer.

公开(公告)号：US20190177619A1

公开(公告)日：2019-06-13

申请号：US16276878

申请日：2019-02-15

Applicant: International Business Machines Corporation

Inventor： Brandon M. Kobilka ,  Joseph Kuczynski ,  Jacob T. Porter ,  Jason T. Wertz

IPC: C09K21/12 ,  C08K5/5317 ,  C09K21/14 ,  C08K5/372 ,  C08K5/5337 ,  C07F9/08 ,  C07C15/04 ,  C07F9/44 ,  C07F9/42 ,  C07F9/40 ,  C07F9/24 ,  C07F9/145 ,  C07F9/14 ,  C07F9/12 ,  C08K5/5313

Abstract: A flame-retardant vanillin-derived small molecule, a process for forming a flame-retardant polymer, and an article of manufacture comprising a material that contains the flame-retardant vanillin-derived small molecule are disclosed. The flame-retardant vanillin-derived small molecule can be synthesized from vanillin obtained from a bio-based source, and can have at least one phosphoryl or phosphonyl moiety with phenyl, allyl, or thioether substituents. The process for forming the flame-retardant polymer can include reacting a diol vanillin derivative and a flame-retardant phosphorus-based molecule to form the flame-retardant vanillin-derived small molecule, and binding the flame-retardant vanillin-derived small molecule to a polymer. The material in the article of manufacture can be flame-retardant, and contain the flame-retardant vanillin-derived small molecules. Examples of materials that can be in the article of manufacture can include resins, plastics, adhesives, polymers, etc.