公开(公告)号：US20230219870A1

公开(公告)日：2023-07-13

申请号：US17983165

申请日：2022-11-08

申请人： IOWA STATE UNIVERSITY RESEARCH FOUNDATION, INC. ,  CORNELL UNIVERSITY ,  UCHICAGO ARGONNE, LLC

发明人： Aaron David SADOW ,  Uddhav KANBUR ,  Frederic A. PERRAS ,  Alexander L. PATERSON ,  Andrew KOCEN ,  Geoffrey W. COATES ,  Anne M. LAPOINTE ,  Massimiliano DELFERRO ,  Ryan A. HACKLER ,  Jessica RODRIGUEZ

IPC分类号： C07C29/36

CPC分类号： C07C29/36

摘要： Disclosed herein is the selective functionalization of one or more hydrocarbons ranging from the longest macromolecules to methane as the smallest. Functionalization is achieved through C-H activation of the one or more hydrocarbons and is carried out by the catalytic complex described herein. Also disclosed is the compound of formula (I) and the compound of formula (II).

公开(公告)号：US20220213007A1

公开(公告)日：2022-07-07

申请号：US17554666

申请日：2021-12-17

申请人： IOWA STATE UNIVERSITY RESEARCH FOUNDATION, INC.

发明人： Aaron David SADOW ,  Uddhav KANBUR

IPC分类号： C07C4/06 ,  C07C51/15 ,  C07C67/24 ,  C07C231/02 ,  C07C29/50 ,  C07C17/06 ,  C07C41/01 ,  C07C45/45 ,  B01J21/12 ,  B01J31/16 ,  B01J31/14

摘要： Disclosed herein is a process for the conversion of polymers, oligomers, or mixtures thereof into shorter alkanes, carboxylic acids, alcohols, alkyl halides or aldehydes. This process includes contacting the polymers, oligomers, or mixtures thereof with the compound of formula (I): Al(R1)3  (I) where R1 is independently selected at each occurrence thereof from the group consisting of H, aryl, C1-C8 alkyl, and C1-C8 alkoxy, as a reaction mixture, in the presence of a catalyst selected from the group consisting of a transition metal catalyst, a lanthanide series metal catalyst, or combinations thereof.