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公开(公告)号：US20130023635A1
公开(公告)日：2013-01-24
申请号：US13185128
申请日：2011-07-18
IPC分类号： B01J31/12 , C07F15/00 , C07D409/04 , C08F4/64 , C07D401/04
CPC分类号： C07D409/04 , B01J31/183 , B01J2531/0244 , B01J2531/48 , C07D401/04 , C07F7/003 , C08F10/00 , C08F4/64144
摘要： A catalyst system useful for polymerizing olefins is disclosed. The catalyst system comprises an activator and a Group 4 metal complex. The complex incorporates a dianionic, tridentate heterocyclic-8-anilinoquinoline ligand. In one aspect, a supported catalyst system is prepared by first combining a boron compound having Lewis acidity with excess alumoxane to produce an activator mixture, followed by combining the activator mixture with a support and the dianionic, tridentate Group 4 metal complex. The Group 4 metal complexes are easy to synthesize, support, and activate, and they enable facile production of high-molecular-weight polyolefins.
摘要翻译： 公开了一种可用于烯烃聚合的催化剂体系。 催化剂体系包括活化剂和第4族金属络合物。 络合物包含二偶氮三齿杂环-8-苯胺基喹啉配体。 一方面，通过首先将具有路易斯酸性的硼化合物与过量的铝氧烷组合以产生活化剂混合物，然后将活化剂混合物与载体和二偶氮三齿金属络合物组合来制备负载型催化剂体系。 第4族金属络合物易于合成，支持和活化，并且能够容易地生产高分子量聚烯烃。
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公开(公告)号：US20120016092A1
公开(公告)日：2012-01-19
申请号：US12804122
申请日：2010-07-14
申请人： Sandor Nagy , Linda N. Winslow , Shahram Mihan , Lenka Lukesova , Ilya E. Nifant'ev , Pavel V. Ivchenko , Vladimir V. Bagrov
发明人： Sandor Nagy , Linda N. Winslow , Shahram Mihan , Lenka Lukesova , Ilya E. Nifant'ev , Pavel V. Ivchenko , Vladimir V. Bagrov
CPC分类号： C08F10/00 , C07F7/00 , C08F4/659 , C08F110/02 , C08F2500/10 , C08F2500/04 , C08F2500/17 , C08F2500/20 , C08F4/64148 , C08F4/64113 , C08F4/64134
摘要： Catalysts useful for polymerizing olefins are disclosed. The catalysts comprise a transition metal complex, an optional activator, and an optional support. The complex is the reaction product of a Group 3-6 transition metal source, an optional alkylating agent, and a ligand precursor comprising a 2-imino-8-anilinoquinoline or a 2-aminoalkyl-8-anilinoquinoline. The catalysts, which are easy to synthesize by in-situ metallation of the ligand precursor, offer polyolefin manufacturers good activity and the ability to make high-molecular-weight ethylene copolymers that have little or no long-chain branching.
摘要翻译： 公开了可用于聚合烯烃的催化剂。 催化剂包括过渡金属络合物，任选的活化剂和任选的载体。 络合物是3-6族过渡金属源，任选的烷基化剂和包含2-亚氨基-8-苯胺基喹啉或2-氨基烷基-8-苯胺基喹啉的配体前体的反应产物。 易于通过配体前体的原位金属化合成的催化剂为聚烯烃制造商提供了良好的活性和制备具有很少或不具有长链支化的高分子量乙烯共聚物的能力。
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公开(公告)号：US08153544B2
公开(公告)日：2012-04-10
申请号：US12460640
申请日：2009-07-22
申请人： Sandor Nagy , Linda N. Winslow , Shahram Mihan , Reynald Chevalier , Lenka Lukesova , Ilya E. Nifant'ev , Pavel V. Ivchenko , Karen L. Neal-Hawkins
发明人： Sandor Nagy , Linda N. Winslow , Shahram Mihan , Reynald Chevalier , Lenka Lukesova , Ilya E. Nifant'ev , Pavel V. Ivchenko , Karen L. Neal-Hawkins
CPC分类号： C08F10/00 , C08F4/64144 , C08F4/64151 , C08F4/64158 , C08F4/64155 , C08F4/64148
摘要： A method of preparing supported catalysts useful for olefin polymerization is described. The catalysts comprise a Group 4 metal complex that incorporates a tridentate dianionic ligand. An activator mixture is first made from a boron compound having Lewis acidity and an excess of an alumoxane. The activator mixture is then combined with a support and the Group 4 metal complex to give a supported catalyst. The method provides an active, supported catalyst capable of making high-molecular-weight polyolefins.
摘要翻译： 描述了制备用于烯烃聚合的负载型催化剂的方法。 催化剂包含掺入三齿二离子配体的第4族金属络合物。 活化剂混合物首先由具有路易斯酸度和过量的铝氧烷的硼化合物制成。 然后将活化剂混合物与载体和第4族金属络合物结合，得到负载型催化剂。 该方法提供了能够制备高分子量聚烯烃的活性的负载型催化剂。
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公开(公告)号：US07858718B1
公开(公告)日：2010-12-28
申请号：US12460621
申请日：2009-07-22
申请人： Sandor Nagy , Linda N. Winslow , Shahram Mihan , Reynald Chevalier , Lenka Lukesova , Ilya E. Nifant'ev , Pavel V. Ivchenko , Michael W. Lynch
发明人： Sandor Nagy , Linda N. Winslow , Shahram Mihan , Reynald Chevalier , Lenka Lukesova , Ilya E. Nifant'ev , Pavel V. Ivchenko , Michael W. Lynch
CPC分类号： C07F7/00 , C08F10/00 , C08F210/16 , Y10S526/901 , Y10S526/941 , C08F2/06 , C08F210/08 , C08F2500/17 , C08F210/14 , C08F4/64144
摘要： Catalysts useful for polymerizing olefins are disclosed. The catalysts comprise an activator and a Group 4 metal complex that incorporates a dianionic, tridentate 2-aryl-8-anilinoquinoline ligand. In one aspect, supported catalysts are prepared by first combining a boron compound having Lewis acidity with excess alumoxane to produce an activator mixture, followed by combining the activator mixture with a support and the tridentate, dianionic Group 4 metal complex. The catalysts are easy to synthesize, support, and activate, and they enable facile production of high-molecular-weight polyolefins.
摘要翻译： 公开了可用于聚合烯烃的催化剂。 催化剂包含活化剂和含有二阴离子，三齿2-芳基-8-苯胺基喹啉配体的第4族金属络合物。 在一个方面，通过首先将具有路易斯酸性的硼化合物与过量的铝氧烷组合以产生活化剂混合物，然后将活化剂混合物与载体和三齿的二阴离子第4族金属络合物组合来制备负载型催化剂。 催化剂易于合成，支持和活化，并且能够容易地生产高分子量聚烯烃。
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5.发明申请Catalysts based on 2-(2-aryloxy)quinoline or 2-(2-aryloxy)dihydroquinoline ligands 失效基于2-（2-芳氧基）喹啉或2-（2-芳氧基）二氢喹啉配体的催化剂公开(公告)号：US20110021727A1
公开(公告)日：2011-01-27
申请号：US12460628
申请日：2009-07-22
申请人： Sandor Nagy , Linda N. Winslow , Shahram Mihan , Reynald Chevalier , Lenka Lukesova , Ilya E. Nifant'ev , Pavel V. Ivchenko
发明人： Sandor Nagy , Linda N. Winslow , Shahram Mihan , Reynald Chevalier , Lenka Lukesova , Ilya E. Nifant'ev , Pavel V. Ivchenko
CPC分类号： C07F7/00 , C08F10/00 , C08F210/16 , C08F210/08 , C08F4/64155 , C08F4/64158 , C08F4/64151
摘要： Catalysts useful for polymerizing olefins are disclosed. The catalysts comprise an activator and a Group 4 metal complex that incorporates a dianionic, tridentate 2-(2-aryloxy)quinoline or 2-(2-aryloxy)dihydroquinoline ligand. In one aspect, supported catalysts are prepared by first combining a boron compound having Lewis acidity with excess alumoxane to produce an activator mixture, followed by combining the activator mixture with a support and the tridentate, dianionic Group 4 metal complex. The catalysts are easy to synthesize, support, and activate, and they enable facile production of high-molecular-weight polyolefins.
摘要翻译： 公开了可用于聚合烯烃的催化剂。 催化剂包含活化剂和含有二偶氮三齿2-（2-芳氧基）喹啉或2-（2-芳氧基）二氢喹啉配体的第4族金属络合物。 在一个方面，通过首先将具有路易斯酸性的硼化合物与过量的铝氧烷组合以产生活化剂混合物，然后将活化剂混合物与载体和三齿的二阴离子第4族金属络合物组合来制备负载型催化剂。 催化剂易于合成，支持和活化，并且能够容易地生产高分子量聚烯烃。
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公开(公告)号：US20110021344A1
公开(公告)日：2011-01-27
申请号：US12460640
申请日：2009-07-22
申请人： Sandor Nagy , Linda N. Winslow , Shahram Mihan , Reynald Chevalier , Lenka Lukesova , Ilya E. Nifant'ev , Pavel V. Ivchenko , Karen L. Neal-Hawkins
发明人： Sandor Nagy , Linda N. Winslow , Shahram Mihan , Reynald Chevalier , Lenka Lukesova , Ilya E. Nifant'ev , Pavel V. Ivchenko , Karen L. Neal-Hawkins
IPC分类号： B01J31/22
CPC分类号： C08F10/00 , C08F4/64144 , C08F4/64151 , C08F4/64158 , C08F4/64155 , C08F4/64148
摘要： A method of preparing supported catalysts useful for olefin polymerization is described. The catalysts comprise a Group 4 metal complex that incorporates a tridentate dianionic ligand. An activator mixture is first made from a boron compound having Lewis acidity and an excess of an alumoxane. The activator mixture is then combined with a support and the Group 4 metal complex to give a supported catalyst. The method provides an active, supported catalyst capable of making high-molecular-weight polyolefins.
摘要翻译： 描述了制备用于烯烃聚合的负载型催化剂的方法。 催化剂包含掺入三齿二离子配体的第4族金属络合物。 活化剂混合物首先由具有路易斯酸度和过量的铝氧烷的硼化合物制成。 然后将活化剂混合物与载体和第4族金属络合物结合，得到负载型催化剂。 该方法提供了能够制备高分子量聚烯烃的活性的负载型催化剂。
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7.发明授权Catalysts based on 2-(2-aryloxy)quinoline or 2-(2-aryloxy)dihydroquinoline ligands 失效基于2-（2-芳氧基）喹啉或2-（2-芳氧基）二氢喹啉配体的催化剂公开(公告)号：US08158733B2
公开(公告)日：2012-04-17
申请号：US12460628
申请日：2009-07-22
申请人： Sandor Nagy , Linda N. Winslow , Shahram Mihan , Reynald Chevalier , Lenka Lukesova , Ilya E. Nifant'ev , Pavel V. Ivchenko
发明人： Sandor Nagy , Linda N. Winslow , Shahram Mihan , Reynald Chevalier , Lenka Lukesova , Ilya E. Nifant'ev , Pavel V. Ivchenko
CPC分类号： C07F7/00 , C08F10/00 , C08F210/16 , C08F210/08 , C08F4/64155 , C08F4/64158 , C08F4/64151
摘要： Catalysts useful for polymerizing olefins are disclosed. The catalysts comprise an activator and a Group 4 metal complex that incorporates a dianionic, tridentate 2-(2-aryloxy)quinoline or 2-(2-aryloxy)dihydroquinoline ligand. In one aspect, supported catalysts are prepared by first combining a boron compound having Lewis acidity with excess alumoxane to produce an activator mixture, followed by combining the activator mixture with a support and the tridentate, dianionic Group 4 metal complex. The catalysts are easy to synthesize, support, and activate, and they enable facile production of high-molecular-weight polyolefins.
摘要翻译： 公开了可用于聚合烯烃的催化剂。 催化剂包含活化剂和含有二偶氮三齿2-（2-芳氧基）喹啉或2-（2-芳氧基）二氢喹啉配体的第4族金属络合物。 在一个方面，通过首先将具有路易斯酸性的硼化合物与过量的铝氧烷组合以产生活化剂混合物，然后将活化剂混合物与载体和三齿的二阴离子第4族金属络合物组合来制备负载型催化剂。 催化剂易于合成，支持和活化，并且能够容易地生产高分子量聚烯烃。
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公开(公告)号：US5968863A
公开(公告)日：1999-10-19
申请号：US599476
申请日：1996-01-23
IPC分类号： C07F7/10 , C07F7/00 , C07F7/28 , C07F17/00 , C08F4/60 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F10/00 , B01J31/00 , C07F7/04 , C07F7/08 , C07F7/24
CPC分类号： C07F17/00 , C08F10/00 , C08F4/65912 , C08F4/65927
摘要： It is possible to prepare in high yield and purity the racemic and meso forms of bridged chiral metallocenes with a stereoselective method, by synthesizing the sylil-, germyl- or stannyl-substituted ligands. These compounds can be prepared in their racemic and meso forms, and then selectively transformed in the corresponding metallocenes.
摘要翻译： 通过合成西尔基，甲锗烷基或者甲锡烷基取代的配体，可以通过立体选择性方法以高产率和纯度制备桥联手性金属茂的外消旋和内消旋形式。 这些化合物可以以其外消旋和内消旋形式制备，然后在相应的金属茂中选择性地转化。
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公开(公告)号：US20090062491A1
公开(公告)日：2009-03-05
申请号：US11886646
申请日：2006-03-15
CPC分类号： C07F17/00
摘要： A bridged metallocene compound of formula (I) wherein: M is an atom of a transition metal; X, is a hydrogen atom, a halogen atom, or a hydrocarbon-based group; R1 is a C1-C40 hydrocarbon radical; R2 and R3, form together a condensed 3-7 membered ring; R4 is a hydrogen atom or a C1-C40 hydrocarbon radical; W is an aromatic 5 or 6 membered ring.
摘要翻译： 式（I）的桥接茂金属化合物，其中：M是过渡金属的原子; X是氢原子，卤原子或烃基; R1是C1-C40烃基; R2和R3一起形成稠合的3-7元环; R4是氢原子或C1-C40烃基; W是芳族5或6元环。
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公开(公告)号：US07858717B2
公开(公告)日：2010-12-28
申请号：US12225200
申请日：2007-03-05
申请人： Luigi Resconi , Ilya E. Nifant'ev , Pavel V. Ivchenko , Vladimir Bagrov , Francesca Focante , Gilberto Moscardi
发明人： Luigi Resconi , Ilya E. Nifant'ev , Pavel V. Ivchenko , Vladimir Bagrov , Francesca Focante , Gilberto Moscardi
IPC分类号： C08F4/44
CPC分类号： C07F17/00 , C07F7/0838 , C08F4/65912 , C08F10/00 , C08F210/06 , C08F4/65927 , C08F210/16 , C08F2500/17
摘要： A bridged metallocene compound of formula (I) wherein: M is an atom of a transition metal selected from those belonging to group 3, 4, or to the lanthanide or actinide groups in the Periodic Table of the Elements; X, equal to or different from each other, is a hydrogen atom, a halogen atom, a R, OR, OSO2CF3, OCOR, SR, NR2 or PR2 group; L is a divalent bridging group; R1 and R2, equal to each other, are C1-C40 hydrocarbon radical; R3 is hydrogen or a are C1-C40 hydrocarbon radical and W is an aromatic 5 or 6 membered ring.
摘要翻译： 式（I）的桥接金属茂化合物，其中：M是选自族3,4中的过渡金属的原子，或元素周期表中的镧系元素或锕系元素基团; X，相同或不同，为氢原子，卤素原子，R，OR，OSO 2 CF 3，OCOR，SR，NR 2或PR 2基团; L是二价桥基; R1和R2相同，为C1-C40烃基; R3是氢或a是C1-C40烃基，W是芳族5或6元环。
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