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    SEGMENTED UREA AND SILOXANE COPOLYMERS AND THEIR PREPARATION METHODS
    1.
    发明申请
    SEGMENTED UREA AND SILOXANE COPOLYMERS AND THEIR PREPARATION METHODS 审中-公开
    分离的尿素和硅氧烷共聚物及其制备方法

    公开(公告)号：US20080027201A1

    公开(公告)日：2008-01-31

    申请号：US11776686

    申请日：2007-07-12

    Applicant: Iskender Yilgor ,  Emel Yilgor ,  Garth Wilkes ,  Jignesh Sheth

    Inventor： Iskender Yilgor ,  Emel Yilgor ,  Garth Wilkes ,  Jignesh Sheth

    IPC: C08G77/455 ,  C08G77/458

    CPC classification number: C08G77/458 ,  C08G18/10 ,  C08G18/61 ,  C08G18/3228 ,  C08G18/50

    Abstract: Using novel synthetic techniques, siloxane-urea segmented copolymers are made. The copolymers advantageously contain a polyether interface, with controlled morphologies and properties. High molecular weight, high strength siloxane-urea copolymers with a high content of urea hard segment may be prepared. Polymer properties that can independently be controlled include modulus, ultimate tensile strength, level of equilibrium water absorption and refractive index.

    Abstract translation: 使用新的合成技术制备硅氧烷 - 尿素分段共聚物。 共聚物有利地包含具有受控形态和性质的聚醚界面。 可以制备具有高含量的尿素硬链段的高分子量，高强度硅氧烷 - 脲共聚物。 可独立控制的聚合物性能包括模数，极限拉伸强度，平衡吸水率和折射率。

    Segmented urea and siloxane copolymers and their preparation methods
    2.
    发明授权
    Segmented urea and siloxane copolymers and their preparation methods 有权
    分段尿素和硅氧烷共聚物及其制备方法

    公开(公告)号：US07262260B2

    公开(公告)日：2007-08-28

    申请号：US11152844

    申请日：2005-06-15

    Applicant: Iskender Yilgor ,  Emel Yilgor ,  Garth L. Wilkes ,  Jignesh P. Sheth

    Inventor： Iskender Yilgor ,  Emel Yilgor ,  Garth L. Wilkes ,  Jignesh P. Sheth

    IPC: C08G77/26

    CPC classification number: C08G18/10 ,  C08G18/61 ,  C08G77/458 ,  C08G18/3228 ,  C08G18/50

    Abstract: Using novel synthetic techniques, siloxane-urea segmented copolymers are made. The copolymers advantageously contain a polyether interface, with controlled morphologies and properties. High molecular weight, high strength siloxane-urea copolymers with urea hard segment contents ranging from 5 to over 60% by weight may be prepared. Polymer properties that can independently be controlled include modulus (1.0 to 120 MPa), ultimate tensile strength (1.5 to 25 MPa), level of equilibrium water absorption (˜0 to 100% by weight) and refractive index (1.43 to 1.46).

    Abstract translation: 使用新的合成技术制备硅氧烷 - 尿素分段共聚物。 共聚物有利地包含具有受控形态和性质的聚醚界面。 可以制备高分子量，高强度硅氧烷 - 尿素共聚物，尿素硬链段含量范围为5-60重量％。 可以独立控制的聚合物性质包括模量（1.0至120MPa），极限拉伸强度（1.5至25MPa），平衡吸水度（〜0至100重量％）和折射率（1.43至1.46）。

    Segmented urea and siloxane copolymers and their preparation methods
    3.
    发明申请
    Segmented urea and siloxane copolymers and their preparation methods 有权
    分段尿素和硅氧烷共聚物及其制备方法

    公开(公告)号：US20060014916A1

    公开(公告)日：2006-01-19

    申请号：US11152844

    申请日：2005-06-15

    Applicant: Iskender Yilgor ,  Emel Yilgor ,  Garth Wilkes ,  Jignesh Sheth

    Inventor： Iskender Yilgor ,  Emel Yilgor ,  Garth Wilkes ,  Jignesh Sheth

    IPC: C08G77/04 ,  C08G77/46

    CPC classification number: C08G18/10 ,  C08G18/61 ,  C08G77/458 ,  C08G18/3228 ,  C08G18/50

    Abstract: Using novel synthetic techniques, siloxane-urea segmented copolymers are made. The copolymers advantageously contain a polyether interface, with controlled morphologies and properties. High molecular weight, high strength siloxane-urea copolymers with urea hard segment contents ranging from 5 to over 60% by weight may be prepared. Polymer properties that can independently be controlled include modulus (1.0 to 120 MPa), ultimate tensile strength (1.5 to 25 MPa), level of equilibrium water absorption (˜0 to 100% by weight) and refractive index (1.43 to 1.46).

    Abstract translation: 使用新的合成技术制备硅氧烷 - 尿素分段共聚物。 共聚物有利地包含具有受控形态和性质的聚醚界面。 可以制备高分子量，高强度硅氧烷 - 尿素共聚物，尿素硬链段含量范围为5-60重量％。 可以独立控制的聚合物性质包括模量（1.0至120MPa），极限拉伸强度（1.5至25MPa），平衡吸水度（〜0至100重量％）和折射率（1.43至1.46）。

    POLYURETHANEUREA SEGMENTED COPOLYMERS
    4.
    发明申请
    POLYURETHANEUREA SEGMENTED COPOLYMERS 审中-公开
    聚氨酯分离共聚物

    公开(公告)号：US20060276613A1

    公开(公告)日：2006-12-07

    申请号：US11382832

    申请日：2006-05-11

    Applicant: Iskender Yilgor ,  Emel Yilgor ,  Derek Klinedinst ,  Garth Wilkes

    Inventor： Iskender Yilgor ,  Emel Yilgor ,  Derek Klinedinst ,  Garth Wilkes

    IPC: C08G18/48

    CPC classification number: C08G18/4854 ,  C08G18/10 ,  C08G18/3228

    Abstract: Novel segmented polyurethaneurea copolymers were synthesized using a poly(ethylene-butylene)glycol based soft segment. Dynamic mechanical analysis (DMA), small angle X-ray scattering (SAXS) and atomic force microscopy (AFM) established the presence of a microphase-separated structure in which hard microdomains are dispersed throughout a soft segment matrix. Wide angle X-ray scattering (WAXS) and differential scanning calorimetry (DSC) results suggest the materials are amorphous. Samples that are made with HMDI/DY and have hard segment contents in the range of 16-23 wt % surprisingly exhibit near-linear mechanical deformation behavior in excess of 600% elongation. They also show very high levels of recoverability even though their hysteresis is also considerable. The materials are both melt processable and solution processable.

    Abstract translation: 使用聚（乙烯 - 丁烯）乙二醇基软链段合成新的分段聚氨酯脲共聚物。 动态力学分析（DMA），小角度X射线散射（SAXS）和原子力显微镜（AFM）建立了微相分离结构的存在，其中硬微区分散在整个软段基质中。 广角X射线散射（WAXS）和差示扫描量热法（DSC）结果表明材料是无定形的。 用HMDI / DY制成并且具有在16-23重量％范围内的硬链段含量的样品令人惊讶地表现出超过600％伸长率的近似线性的机械变形行为。 即使它们的滞后也是可观的，它们也显示出非常高水平的可恢复性。 材料均可熔融加工，溶液可加工。

    Triblock copolymers and their production methods
    5.
    发明申请
    Triblock copolymers and their production methods 审中-公开
    三嵌段共聚物及其制备方法

    公开(公告)号：US20060047083A1

    公开(公告)日：2006-03-02

    申请号：US11202372

    申请日：2005-08-12

    Applicant: Iskender Yilgor ,  Emel Yilgor ,  Thomas Ward

    Inventor： Iskender Yilgor ,  Emel Yilgor ,  Thomas Ward

    IPC: C08F297/00

    CPC classification number: C08G18/4277 ,  C08G18/10 ,  C08G18/4833 ,  C08G18/61 ,  C08L53/00 ,  C08G18/3228 ,  C08G18/3206 ,  C08L2666/02

    Abstract: A new family of triblock (A-B-A type) thermoplastic, polyurethane, polyurethaneurea, polyurea and polyamide copolymers has been prepared. (A) blocks represent the hard segments, such as urethane, urea, urethaneurea or amide type segments. (B) blocks represent the soft segments, such as aliphatic polyethers, aliphatic polyesters, polydimethylsiloxanes, polyalkanes or their copolymers. These novel material display very interesting microphase morphologies, mechanical properties, solubility characteristics and melt behavior.

    Abstract translation: 已经制备了新的三嵌段（A-B-A型）热塑性，聚氨酯，聚氨酯脲，聚脲和聚酰胺共聚物。 （A）嵌段表示硬链段，例如氨基甲酸酯，脲，氨基脲或酰胺型链段。 （B）嵌段代表软链段，例如脂族聚醚，脂族聚酯，聚二甲基硅氧烷，聚烷烃或它们的共聚物。 这些新型材料显示非常有趣的微相形态，机械性能，溶解度特性和熔体行为。

    L3-silica/polyurethane thermally insulating nanocomposite
    9.
    发明申请
    L3-silica/polyurethane thermally insulating nanocomposite 审中-公开
    L3-二氧化硅/聚氨酯绝热纳米复合材料

    公开(公告)号：US20050137315A1

    公开(公告)日：2005-06-23

    申请号：US10842251

    申请日：2004-05-10

    Applicant: Ilhan Aksay ,  Christopher Wahl ,  Daniel Dabbs ,  Iskender Yilgor

    Inventor： Ilhan Aksay ,  Christopher Wahl ,  Daniel Dabbs ,  Iskender Yilgor

    IPC: C08K3/34 ,  C08K3/36

    CPC classification number: C08K3/36 ,  C08L75/04

    Abstract: The present invention provides thermal insulator composites based upon nanostructured L3-silica microparticles and polyurethane foam chemistry that are both easy to process and have superior insulating properties for use in household and commercial refrigeration, construction, and shipping applications. The composite material retains many of the attractive processing characteristics of polyurethane foams such as volume expansion and shape-filling during polymerization and demonstrates a total thermal conductivity between 32 and 44% that of commercially available polyurethane foams.

    Abstract translation: 本发明提供了基于纳米结构的三亚硫酸钠微粒和聚氨酯泡沫化学物质的热绝缘体复合材料，其易于加工并具有优异的绝缘性能，用于家用和商业制冷，建筑和运输应用 。 复合材料在聚合过程中保留了聚氨酯泡沫的许多有吸引力的加工特性，例如体积膨胀和形状填充，并表现出市售聚氨酯泡沫的总热导率为32-44％。

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