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公开(公告)号：US20210008524A1
公开(公告)日：2021-01-14
申请号：US16947620
申请日：2020-08-10
发明人： Jürgen BAUER , Ralf DOTZEL , Joerg Werner MUENCH , Ralitsa PUROVA , Wilhelm SCHWIEGER , Thangaraj SELVAM , Ameen SHAHID
IPC分类号： B01J23/30 , B01J21/16 , B01J37/02 , B01D53/94 , F01N3/20 , B01J23/72 , B01J29/76 , B01J29/04 , B01J37/34 , F01N13/16 , B01J37/00 , B01J21/18 , B01D53/86 , F01N3/28 , B01J35/04 , B01J37/04 , B01J37/08
摘要： A SCR catalyst composition comprises a SCR catalyst; and a binder comprising a porous inorganic material, wherein the porous inorganic material comprises a disordered arrangement of delaminated layers, has a disordered porous structure, and has a multimodal pore size distribution comprising at least a first modal maximum having a macroporous or mesoporous pore size and a second modal maximum having a microporous pore size. The SCR catalyst composition can be manufactured using the method comprising the steps of: (i) providing an inorganic material having a layered structure; (ii) contacting the material with a cationic surfactant to form a swollen material; (iii) agitating the swollen material to form an agitated material; and (iv) calcining the agitated material to recover a delaminated inorganic material, wherein an SCR catalyst is mixed with the inorganic material prior to step (iv).
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公开(公告)号：US20200038850A1
公开(公告)日：2020-02-06
申请号：US16498479
申请日：2018-03-29
发明人： Juergen BAUER , Ralf DOTZEL , Joerg Werner MUENCH , Ralitsa PUROVA , Wilhelm SCHWIEGER , Thangaraj SELVAM , Ameen SHAHID
IPC分类号： B01J29/76 , B01D53/94 , B01J37/00 , B01J37/30 , B01J37/10 , B01J35/04 , F01N3/035 , F01N3/28 , F01N3/022 , F01N3/20
摘要： A composite material comprises a macroporous silicate-based material at least partially substituted with at least one microporous zeolite, wherein the microporous zeolite is functionalised with either copper, iron or both copper and iron, and wherein the composite material is in the form of particles. The composite material can be obtained using a method comprising the steps of: (i) providing a mixture comprising a silicate-containing scaffold having a macroporous structure, an aluminium source and an organic template; (ii) hydrothermally treating the mixture to form a microporous zeolite-containing structure substantially retaining the macroporous structure of the silicate-containing scaffold; (iii) incorporating copper, iron or both copper and iron into the zeolite. The cate-containing scaffold can be a diatomaceous earth.
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公开(公告)号：US20220250928A1
公开(公告)日：2022-08-11
申请号：US17661353
申请日：2022-04-29
发明人： Juergen BAUER , John Leonello CASCI , Ralf DOTZEL , Joerg MUENCH , Ralitsa PUROVA , Wilhelm SCHWIEGER , Ameen SHAHID , Selvam THANGARAJ , Tobias WEISSENBERGER,
IPC分类号： C01B39/48 , B01J35/04 , F01N3/20 , F01N3/28 , C01B39/14 , C01B39/04 , C01B39/02 , B01J35/10 , B01J35/00 , B01J37/02 , B01J37/00 , B01J37/10 , B01J29/04 , B01J29/72 , B01J29/74 , B01J29/78 , B01J29/76
摘要： The present invention further provides a method of making an metal-loaded aluminosilicate zeolite having a maximum pore opening defined by eight tetrahedral atoms from pre-existing aluminosilicate zeolite crystallites, wherein the metal is present in a range of from 0.5 to 5.0 wt. % based on the total weight of the metal-loaded aluminosilicate zeolite.
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4.发明申请公开(公告)号：US20200223708A1
公开(公告)日：2020-07-16
申请号：US16739615
申请日：2020-01-10
发明人： Juergen BAUER , John Leonello CASCI , Ralf DOTZEL , Joerg MUENCH , Ralitsa PUROVA , Wilhelm SCHWIEGER , Ameen SHAHID , Selvam THANGARAJ , Tobias WEISSENBERGER
摘要： The present invention provides an iron-loaded aluminosilicate zeolite having a maximum pore opening defined by eight tetrahedral atoms and having the framework type CHA, AEI, AFX, ERI or LTA, wherein the iron (Fe) is present in a range of from about 0.5 to about 5.0 wt. % based on the total weight of the iron-loaded aluminosilicate zeolite, wherein an ultraviolet-visible absorbance spectrum of the iron-loaded synthetic aluminosilicate zeolite comprises a band at approximately 280 nm, wherein a ratio of an integral, peak-fitted ultraviolet-visible absorbance signal measured in arbitrary units (a.u.) for the band at approximately 280 nm to an integral peak-fitted ultraviolet-visible absorbance signal measured in arbitrary units (a.u.) for a band at approximately 340 nm is >about 2. The present invention further provides a method of making an metal-loaded aluminosilicate zeolite having a maximum pore opening defined by eight tetrahedral atoms from pre-existing aluminosilicate zeolite crystallites, wherein the metal is present in a range of from 0.5 to 5.0 wt. % based on the total weight of the metal-loaded aluminosilicate zeolite.
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公开(公告)号：US20180280937A1
公开(公告)日：2018-10-04
申请号：US15937942
申请日：2018-03-28
发明人： Juergen BAUER , Ralf DOTZEL , Joerg Werner MUENCH , Ralitsa PUROVA , Wilhelm SCHWIEGER , Thangaraj SELVAM , Ameen SHAHID
IPC分类号： B01J23/30 , B01J21/16 , B01J35/04 , B01J37/08 , B01J37/04 , B01J37/02 , B01J37/00 , B01D53/94
摘要： A SCR catalyst composition comprises a SCR catalyst; and a binder comprising a porous inorganic material, wherein the porous inorganic material comprises a disordered arrangement of delaminated layers, has a disordered porous structure, and has a multimodal pore size distribution comprising at least a first modal maximum having a macroporous or mesoporous pore size and a second modal maximum having a microporous pore size. The SCR catalyst composition can be manufactured using the method comprising the steps of: (i) providing an inorganic material having a layered structure; (ii) contacting the material with a cationic surfactant to form a swollen material; (iii) agitating the swollen material to form an agitated material; and (iv) calcining the agitated material to recover a delaminated inorganic material, wherein an SCR catalyst is mixed with the inorganic material prior to step (iv).
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