公开(公告)号：US06284127B1

公开(公告)日：2001-09-04

申请号：US09416038

申请日：1999-10-12

申请人： Bruce R. Cook ,  Jack W. Johnson ,  Guang Cao ,  Rich A. McEvoy ,  Richard H. Ernst

发明人： Bruce R. Cook ,  Jack W. Johnson ,  Guang Cao ,  Rich A. McEvoy ,  Richard H. Ernst

IPC分类号： G25

CPC分类号： C10G2/30 ,  C10G2400/10

摘要： A process for dewaxing waxy hydrocarbonaceous materials, such as hydrocarbon fuel and lubricating oil fractions to reduce their cloud and pour points comprises reacting the material with hydrogen in the presence of a dewaxing catalyst comprising at least one metal catalytic component and ferrierite in which at least a portion of its cation exchange positions are occupied by one or more trivalent rare earth metal cations. The rare earth ion exchanged ferrierite catalyst has good selectivity for lubricating oil production, particularly when dewaxing a Fischer-Tropsch wax hydroisomerate. Preferably at least 10% and more preferably at least 15% of the ferreirite cation exchange capacity is occupied by one or more trivalent rare earth metal cations.

摘要翻译： 用于脱蜡蜡质烃类材料（例如烃燃料和润滑油馏分）以降低其云和倾点的方法包括在包含至少一种金属催化组分和镁碱沸石的脱蜡催化剂存在下使材料与氢反应，其中至少一种 其阳离子交换位置的一部分被一种或多种三价稀土金属阳离子占据。 稀土离子交换的镁碱沸石催化剂对于润滑油生产具有良好的选择性，特别是当脱蜡费 - 托蜡蜡加氢异构体时。 优选地，铁氰化物阳离子交换容量的至少10％，更优选至少15％被一种或多种三价稀土金属阳离子占据。

公开(公告)号：US6013171A

公开(公告)日：2000-01-11

申请号：US018019

申请日：1998-02-03

申请人： Bruce R. Cook ,  Jack W. Johnson ,  Guang Cao ,  Rich A. McEvoy ,  Richard H. Ernst

发明人： Bruce R. Cook ,  Jack W. Johnson ,  Guang Cao ,  Rich A. McEvoy ,  Richard H. Ernst

IPC分类号： B01J29/65 ,  B01J29/67 ,  C10G2/00 ,  C10G45/64 ,  C10G65/04 ,  C10G25/00

CPC分类号： C10G2/30 ,  B01J2229/186 ,  B01J2229/40 ,  B01J29/655 ,  B01J29/67 ,  C10G2400/10 ,  Y10S208/95

摘要： A process for dewaxing waxy hydrocarbonaceous materials, such as hydrocarbon fuel and lubricating oil fractions to reduce their cloud and pour points comprises reacting the material with hydrogen in the presence of a dewaxing catalyst comprising at least one metal catalytic component and ferrierite in which at least a portion of its cation exchange positions are occupied by one or more trivalent rare earth metal cations. The rare earth ion exchanged ferrierite catalyst has good selectivity for lubricating oil production, particularly when dewaxing a Fischer-Tropsch wax hydroisomerate. Preferably at least 10% and more preferably at least 15% of the ferreirite cation exchange capacity is occupied by one or more trivalent rare earth metal cations.

摘要翻译： 用于脱蜡蜡质烃类材料（例如烃燃料和润滑油馏分）以降低其云和倾点的方法包括在包含至少一种金属催化组分和镁碱沸石的脱蜡催化剂存在下使材料与氢反应，其中至少一种 其阳离子交换位置的一部分被一种或多种三价稀土金属阳离子占据。 稀土离子交换的镁碱沸石催化剂对于润滑油生产具有良好的选择性，特别是当脱蜡费 - 托蜡蜡加氢异构体时。 优选地，铁氰化物阳离子交换容量的至少10％，更优选至少15％被一种或多种三价稀土金属阳离子占据。

公开(公告)号：US5948719A

公开(公告)日：1999-09-07

申请号：US18168

申请日：1998-02-03

申请人： Jack W. Johnson ,  Bruce R. Cook ,  Guang Cao ,  Rich A. McEvoy ,  Richard H. Ernst

发明人： Jack W. Johnson ,  Bruce R. Cook ,  Guang Cao ,  Rich A. McEvoy ,  Richard H. Ernst

IPC分类号： B01J29/65 ,  B01J29/67 ,  B01J21/00

CPC分类号： B01J29/67 ,  B01J29/655 ,  B01J2229/186 ,  B01J2229/40 ,  Y10S423/23

摘要： Ferrierite is ion exchanged with trivalent rare earth metals by a hydrothermal ion exchange method. The ion exchange is carried out by contacting ferrierite, in which its cation exchange positions are occupied by hydrogen or a hydrogen precursor, with an aqueous solution of one or more rare earth metal cations at a temperature above the boiling point of the solution. After the ion exchange, preferably at least 10% and more preferably at least 15% of the ferrierite cation exchange capacity is occupied by a trivalent rare earth metal cation. When combined with a catalytic metal, such as a Group VIII noble metal, the trivalent rare earth metal ion exchanged ferrierite is useful as a dewaxing catalyst having good selectivity for lubricating oil fractions, particularly when dewaxing a Fischer-Tropsch wax hydroisomerate.

摘要翻译： 镁碱沸石与三价稀土金属通过水热离子交换法进行离子交换。 离子交换是通过在高于溶液沸点的温度下将其阳离子交换位置被氢或氢前体占据的镁碱沸石与一种或多种稀土金属阳离子的水溶液接触来进行的。 离子交换后，优选至少10％，更优选至少15％的镁碱沸石阳离子交换容量被三价稀土金属阳离子占据。 当与催化金属如VIII族贵金属组合时，三价稀土金属离子交换的镁碱沸石可用作对润滑油馏分具有良好选择性的脱蜡催化剂，特别是当脱蜡费 - 托蜡蜡加氢异构体时。