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公开(公告)号：US06197891B1
公开(公告)日：2001-03-06
申请号：US08717233
申请日：1996-09-26
申请人： James Anthony Schwindeman , Eric John Granger , Robert Charles Morrison , Conrad William Kamienski , Robert James Letchford
发明人： James Anthony Schwindeman , Eric John Granger , Robert Charles Morrison , Conrad William Kamienski , Robert James Letchford
IPC分类号： C08F3604
摘要： A process for the preparation of hydrocarbon solutions of monofunctional ether initiators of the following general structure: M—Qn—Z—O—[A(R1R2R3)] wherein M is an alkali metal selected from the group consisting of lithium, sodium and potassium; Q is a saturated or unsaturated hydrocarbyl group derived by incorporation of a compound selected from the group consisting of conjugated diene hydrocarbons, alkenylsubstituted aromatic hydrocarbons, and mixtures thereof into the M—Z linkage; Z is a branched or straight chain hydrocarbon group which contains 3-25 carbon atoms, optionally containing aryl or substituted aryl groups; A is an element selected from carbon and silicon; R1, R2, and R3 are independently selected from hydrogen, alkyl, substituted alkyl groups containing lower alkyl, lower alkylthio, and lower dialkylamino groups, aryl or substituted aryl groups containing lower alkyl, lower alkylthio, and lower dialkylamino groups, and n is an integer from 1 to 5, monofunctional ethers produced by the process, use of the initiators in a polymerization process and polymers produced by the polymerization process.
摘要翻译： 一种制备以下一般结构的单官能醚引发剂的烃溶液的方法：其中M是选自锂，钠和钾的碱金属; Q是通过将选自共轭二烯烃，烯基取代的芳烃及其混合物的化合物引入到M-Z键中衍生的饱和或不饱和烃基; Z是含有3-25个碳原子的支链或直链烃基，任选含有芳基或取代的芳基; A是选自碳和硅的元素; R 1，R 2和R 3独立地选自氢，烷基，含有低级烷基，低级烷硫基和低级二烷基氨基的取代烷基，含有低级烷基，低级烷硫基和低级二烷基氨基的芳基或取代芳基，n是 1至5的整数，通过该方法产生的单官能醚，在聚合方法中使用引发剂和通过聚合方法制备的聚合物。
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公开(公告)号：US5821307A
公开(公告)日：1998-10-13
申请号：US652215
申请日：1996-05-23
申请人： James Anthony Schwindeman , Conrad William Kamienski , Eric John Granger , Robert Charles Morrison
发明人： James Anthony Schwindeman , Conrad William Kamienski , Eric John Granger , Robert Charles Morrison
IPC分类号： C08C19/44 , C08F4/46 , C08F12/04 , C08F12/06 , C08F36/04 , C08F279/02 , C08F297/04 , C07C43/115
摘要： A process for the preparation of hydrocarbon solutions of monofunctional ether initiators of the following general structure: M--Q.sub.n --Z--OA(R.sup.1 R.sup.2 R.sup.3) wherein M is defined as an alkali metal, selected from the group consisting of lithium, sodium and potassium, Q is an aromatic substituted saturated hydrocarbyl group produced by the incorporation of one or more alkenyl substituted aromatic hydrocarbons containing 8-25 carbon atoms into the M--Z linkage; Z is a branched or straight chain hydrocarbon group which contains 3-25 carbon atoms, optionally containing aryl or substituted aryl groups; A is an element selected from carbon and silicon; R.sup.1, R.sup.2, and R.sup.3 are independently selected from hydrogen, alkyl, substituted alkyl groups containing lower alkyl, lower alkylthio, and lower dialkylamino groups, aryl or substituted aryl groups containing lower alkyl, lower alkylthio, and lower dialkylamino groups, and n is an integer from 1 to 5, monofunctional ethers produced by the process, use of the initiators in a polymerization process and polymers produced by the polymerization process.
摘要翻译： 一种制备以下一般结构的单官能醚引发剂的烃溶液的方法：M-Qn-Z-OA（R1R2R3）其中M定义为碱金属，选自锂，钠和钾，Q 是通过将含有8-25个碳原子的一个或多个烯基取代的芳族烃引入到MZ连接中而产生的芳族取代的饱和烃基; Z是含有3-25个碳原子的支链或直链烃基，任选含有芳基或取代的芳基; A是选自碳和硅的元素; R 1，R 2和R 3独立地选自氢，烷基，含有低级烷基，低级烷硫基和低级二烷基氨基的取代烷基，含有低级烷基，低级烷硫基和低级二烷基氨基的芳基或取代芳基，n是 1至5的整数，通过该方法产生的单官能醚，在聚合过程中使用引发剂和通过聚合方法制备的聚合物。
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3.发明授权Protected functionalized heterotelechelic polymers and processes for preparing the same 失效受保护的官能化杂多炔类聚合物及其制备方法公开(公告)号：US06362284B1
公开(公告)日：2002-03-26
申请号：US09195895
申请日：1998-11-19
IPC分类号： C08F832
CPC分类号： C08F8/00 , C08C19/02 , C08C19/44 , C08F8/04 , C08F8/42 , C08F36/04 , C08F12/00 , C08F4/48 , C08F4/72 , C08F4/46
摘要： Protected, functionalized heterotelechelic polymers, hydrogenated and/or deprotected analogues thereof, and processes to prepare these polymers. Monomers are polymerized using a protected functionalized initiator to form a living polymer, and the living polymer is reacted with an electrophile to form heterotelechelic polymers.
摘要翻译： 受保护的官能化杂多炔类聚合物，其氢化和/或去保护的类似物，以及制备这些聚合物的方法。 使用保护的官能化引发剂聚合单体以形成活性聚合物，并且使活性聚合物与亲电试剂反应以形成异极乙烯基聚合物。
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公开(公告)号：US6107414A
公开(公告)日：2000-08-22
申请号：US196289
申请日：1998-11-19
摘要： Protected, functionalized heterotelechelic polymers, hydrogenated and/or deprotected analogues thereof, and processes to prepare these polymers. Monomers are polymerized using a protected functionalized initiator to form a living polymer, and the living polymer is reacted with an electrophile to form heterotelechelic polymers.
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5.发明授权Protected functionalized telechelic polymers and processes for making the same 失效受保护的功能化遥爪聚合物和制造相同的方法
公开(公告)号：US5965681A
公开(公告)日：1999-10-12
申请号：US107678
申请日：1998-06-30
CPC分类号： C08C19/44 , C08F36/04 , Y10T428/31551 , Y10T428/31591 , Y10T428/31725 , Y10T428/31757 , Y10T428/31783 , Y10T428/31902 , Y10T442/2484 , Y10T442/2787 , Y10T442/2811
摘要： Protected, functionalized telechelic polymers, hydrogenated and/or deprotected analogues thereof, and processes to prepare these polymers are disclosed. In the invention, a lithium initiator is added to a compound having at least two independently polymerizable vinyl groups to form a dilithium initiator. Monomer is then added to grow or polymerize polymer arms having living ends and the living ends functionalized.
摘要翻译： 公开了保护的官能化遥爪聚合物，其氢化和/或去保护的类似物，以及制备这些聚合物的方法。 在本发明中，将锂引发剂加入具有至少两个独立可聚合的乙烯基的化合物中以形成二锂引发剂。 然后加入单体以生长或聚合具有活性末端并且活性末端官能化的聚合物臂。
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公开(公告)号：US5910547A
公开(公告)日：1999-06-08
申请号：US893951
申请日：1997-07-16
摘要： Protected, functionalized heterotelechelic polymers, hydrogenated and/or deprotected analogues thereof, and processes to prepare these polymers. Monomers are polymerized using a protected functionalized initiator to form a living polymer, and the living polymer is reacted with an electrophile to form heterotelechelic polymers.
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7.发明授权Functionalized initiators for anionic polymerization, protected functionalized polymers, deprotected analogues thereof, and methods of making the same 失效用于阴离子聚合的官能化引发剂，保护的官能化聚合物，其去保护的类似物及其制备方法公开(公告)号：US06812295B2
公开(公告)日：2004-11-02
申请号：US10801367
申请日：2004-03-16
IPC分类号： C08F818
摘要： The present invention provides functionalized electrophiles, their analogous initiators, and processes for preparing these compounds. The present invention also relates to homotelechelic, heteroelechelic, and radial functional polydiene polymers, polyarylene polymers and polydiene/polyarylene copolymers, their optionally hydrogenated analogues, their optionally deprotected analogs, and process for preparing these functionalized polymers.
摘要翻译： 本发明提供功能化的亲电子试剂，它们的类似的引发剂，以及制备这些化合物的方法。 本发明还涉及同基亚类，异亚烯基和径向功能性聚二烯聚合物，聚亚芳基聚合物和聚二烯/聚亚芳基共聚物，它们任选氢化的类似物，它们任选脱保护的类似物，以及制备这些官能化聚合物的方法。
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8.发明授权Amine anionic polymerization initiators and functionalized polymers derived therefrom 失效胺阴离子聚合引发剂和衍生自其的官能化聚合物
公开(公告)号：US6121474A
公开(公告)日：2000-09-19
申请号：US256737
申请日：1999-02-24
申请人： James Anthony Schwindeman , Eric John Granger , Roderic Paul Quirk , Randy W. Hall , Robert James Letchford
发明人： James Anthony Schwindeman , Eric John Granger , Roderic Paul Quirk , Randy W. Hall , Robert James Letchford
IPC分类号： C08C19/44 , C08F4/46 , C08F8/42 , C08F36/04 , C08F257/02 , C08F279/02 , C07F7/02 , C07F7/10
CPC分类号： C08F279/02 , C08C19/44 , C08F257/02 , C08F36/04 , C08F4/46 , C08F8/42
摘要： Protected amine anionic polymerization initiators useful in the preparation of polymers having a protected amine functional group. The initiators are very soluble in hydrocarbon solvents.
摘要翻译： 用于制备具有受保护的胺官能团的聚合物的受保护的胺阴离子聚合引发剂。 引发剂非常易溶于烃溶剂。
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公开(公告)号：US06444190B2
公开(公告)日：2002-09-03
申请号：US09262093
申请日：1999-03-04
申请人： Anne Pautard-Cooper , Eric John Granger , Philip Franklin Sims , James Anthony Schwindeman , John Francis Engel , Terry Lee Rathman
发明人： Anne Pautard-Cooper , Eric John Granger , Philip Franklin Sims , James Anthony Schwindeman , John Francis Engel , Terry Lee Rathman
IPC分类号： C01B624
CPC分类号： C07D295/023 , C07D211/22
摘要： Novel reduction compositions are prepared from an active hydride, an additive, and a Lewis base in a hydrocarbon solvent. Such compositions can provide a superior reducing system for organic substrates.
摘要翻译： 在烃溶剂中由活性氢化物，添加剂和路易斯碱制备新的还原组合物。 这样的组合物可为有机基材提供优异的还原体系。
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10.发明授权Functionalized initiators for anionic polymerization, protected functionalized polymers, deprotected analogues thereof, and methods of making the same 失效用于阴离子聚合的官能化引发剂，保护的官能化聚合物，其去保护的类似物及其制备方法公开(公告)号：US06720391B2
公开(公告)日：2004-04-13
申请号：US10062331
申请日：2002-02-01
IPC分类号： C08F818
摘要： The present invention provides functionalized electrophiles, their analogous initiators, and processes for preparing these compounds. The present invention also relates to homotelechelic, heterotelechelic, and radial functional polydiene polymers, polyarylene polymers and polydiene/polyarylene copolymers, their optionally hydrogenated analogues, their optionally deprotected analogues, and processes for preparing these functionalized polymers.
摘要翻译： 本发明提供功能化的亲电子试剂，它们的类似的引发剂，以及制备这些化合物的方法。 本发明还涉及同基亚类，异触耳和径向功能聚二烯聚合物，聚亚芳基聚合物和聚二烯/聚亚芳基共聚物，它们任选氢化的类似物，它们任选脱保护的类似物，以及制备这些官能化聚合物的方法。
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