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1.发明授权Manganese carbonyl-sulfonyl chloride photoinitiators for radiation polymerizable unsaturated compounds 失效用于辐射聚合不饱和化合物的羰基 - 磺酰氯锰光催化剂
公开(公告)号：US4141808A
公开(公告)日：1979-02-27
申请号：US897065
申请日：1978-04-17
CPC分类号： C08F2/50 , G03F7/029 , Y10S430/114 , Y10S430/124 , Y10S430/126
摘要： This invention relates to radiation curable compositions of radiation polymerizable unsaturated materials, and particularly concerns photoinitiators therefor comprising manganese carbonyl admixed with any of a variety of sulfonyl chloride compounds. The monomers initiated with these materials have high polymerization rates which permit faster curing cycles.
摘要翻译： 本发明涉及可辐射聚合的不饱和材料的可辐射固化组合物，特别涉及包含与任何一种磺酰氯化合物混合的锰羰基的光引发剂。 用这些材料引发的单体具有高聚合速率，其允许更快的固化周期。
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2.发明授权Radiation curable compositions containing 5-halo-6-halomethyluracil derivatives as photoinitiators 失效含有5-卤代-6-卤代甲基尿嘧啶衍生物作为光引发剂的可辐射固化组合物
公开(公告)号：US4189366A
公开(公告)日：1980-02-19
申请号：US3568
申请日：1979-01-15
CPC分类号： C08F2/50 , Y10T428/3162 , Y10T428/31649
摘要： Ethylenically unsaturated compositions such as acrylic and methacrylic acid esters, vinyl esters, vinyl halides, unsaturated amides such as acrylamide, vinyl aromatics such as styrene, and various aliphatic and aromatic polyesters containing any of the above or other modifying components such as maleic, fumaric, itaconic, citraconic and the like, are very effectively and rapidly cured with certain 5-halo-6-halomethyluracil photoinitiators. These curable systems have extensive utility in the surface coatings industry, particularly in regard to cured protective coatings.
摘要翻译： 乙烯基不饱和组合物如丙烯酸和甲基丙烯酸酯，乙烯基酯，乙烯基卤化物，不饱和酰胺如丙烯酰胺，乙烯基芳族化合物如苯乙烯，以及包含任何上述或其它改性成分如马来酸，富马酸， 衣康酸，柠康酸等，被某些5-卤代-6-卤代甲基尿嘧啶光引发剂非常有效和快速地固化。 这些可固化体系在表面涂料工业中具有广泛的用途，特别是在固化的保护涂层方面。
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3.发明授权Photocurable compositions containing s-aryl arylcarbothioic acid esters as photoinitiators 失效含有S-芳基芳基羰基硫酸酯的光固化性组合物作为光引发剂
公开(公告)号：US4012302A
公开(公告)日：1977-03-15
申请号：US658328
申请日：1976-02-17
IPC分类号： C08F2/00 , C08F2/50 , C08F299/04 , C09D4/00 , C09D11/00 , C09D11/10 , G03F7/031 , C08L1/00 , C08F2/46 , C08F8/18
CPC分类号： G03F7/031 , C08F299/0435 , C09D11/101 , C09D4/00 , Y10S430/122 , Y10S525/92
摘要： Compositions comprising a photocurable ethylenically unsaturated compound and an S-aryl arylcarbothioic acid ester or a bis-S-aryl aryl-dicarbothioic acid ester.
摘要翻译： 包含可光固化烯键式不饱和化合物和S-芳基芳基硫代羧酸酯或双-S-芳基芳基二硫代硫酸酯的组合物。
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4.发明授权Stabilized photopolymerizable polymeric compositions containing a photoinitiator and a nitrone derivative 失效含有光引发剂和硝酮衍生物的稳定的可光聚合的聚合物组合物
公开(公告)号：US3988229A
公开(公告)日：1976-10-26
申请号：US608812
申请日：1975-08-28
CPC分类号： C08F2/50 , C08K5/32 , Y10S430/12
摘要： The invention relates to stabilized photopolymerizable or photocrosslinkable polymeric compositions having improved storage stability. These compositions are useful as coating and moldable compositions which are hardenable by ultraviolet radiation. These coating and moldable compositions comprise mixtures of photopolymerizable or photocrosslinkable unsaturated compounds, at least one photoinitiator and a particular nitrone.
摘要翻译： 本发明涉及具有改善的储存稳定性的稳定的可光聚合或光可交联的聚合物组合物。 这些组合物可用作可通过紫外线辐射固化的涂层和可模塑组合物。 这些涂层和可模制组合物包含可光聚合或可光致交联的不饱和化合物，至少一种光引发剂和特定硝酮的混合物。
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5.发明授权Amorphous aromatic polyester modified with amine and UV curable composition containing the same 失效用胺改性的无定形芳族聚酯和含有它的可UV固化组合物
公开(公告)号：US4395539A
公开(公告)日：1983-07-26
申请号：US401756
申请日：1982-07-26
IPC分类号： C08F299/04 , C08G63/685 , G03F7/032 , C08G69/44
CPC分类号： G03F7/032 , C08F299/0435 , C08G63/6856
摘要： The present invention provides a novel linear amorphous aromatic polyester comprising units derived from (i) terephthalic acid, (ii) 1,2-propanediol or mixtures of 1,2-propanediol with up to 20 mole percent of ethylene glycol, based upon the total of 1,2-propanediol and ethylene glycol, and (iii) about 5 to 30 mole percent, based upon the total of (i), (ii), and (iii), of a glycol which contains a tertiary amine group, the amine containing glycol having a specified structure and the polyester having an inherent viscosity of about 0.05 to 0.5 dl/g when measured in 60:40 phenol:tetrachloroethane at a concentration of 0.5 g/100 ml at 25.degree. C. The novel polyester is useful as a crosslinking resin and as a photoinitiator for UV curable coating and ink compositions.Also provided is a specified ultraviolet radiation curable coating composition. The composition comprises a mixture ofA. about 4.5 to 49.5% by weight of the novel amine-modified polyester described above;B. about 50 to 95 percent by weight of a photopolymerizable or photocrosslinkable ethylenically unsaturated compound; andC. about 0.5 to 25 percent by weight of a photoinitiator.The photoinitiator is selected from the group consisting of benzil, lower alkyl substituted benzil, benzoin ethers, haloalkyl ketones, aromatic ketones, lower alkyl substituted aromatic ketones, aromatic ketones in combination with amines, and mixtures thereof. The ethylenically unsaturated compound is most preferably selected from the group consisting of glycidyl acrylate, glycidyl methacrylate, methyl acrylate, methyl methacrylate, ethyl acrylate, ethyl methacrylate, and mixtures thereof. The coating composition provided by the present invention gives clear insoluble coatings which are useful as protective and/or decorative coatings.
摘要翻译： 本发明提供一种新型的线性无定形芳族聚酯，其包含衍生自（i）对苯二甲酸，（ii）1,2-丙二醇或1,2-丙二醇与至多20摩尔％乙二醇的混合物的单元，基于总计 的1,2-丙二醇和乙二醇，和（iii）基于含有叔胺基团的二醇的总计（i），（ii）和（iii））约5至30摩尔％， 具有特定结构的含胺二醇和当在25℃下浓度为0.5g / 100ml的60:40苯酚：四氯乙烷中测定时，特性粘度为约0.05至0.5dl / g的聚酯。新型聚酯是有用的 作为交联树脂和用作UV固化涂料和油墨组合物的光引发剂。 还提供了一种特定的紫外线辐射固化涂料组合物。 该组合物包含A.约4.5至49.5重量％的上述新型胺改性聚酯的混合物; B.约50至95重量％的可光聚合或可光致交联的烯键式不饱和化合物; 和C.约0.5至25重量％的光引发剂。 光引发剂选自苯偶酰，低级烷基取代的苯偶酰，苯偶姻醚，卤代烷基酮，芳族酮，低级烷基取代的芳族酮，芳族酮与胺的组合及其混合物。 烯键式不饱和化合物最优选选自丙烯酸缩水甘油酯，甲基丙烯酸缩水甘油酯，丙烯酸甲酯，甲基丙烯酸甲酯，丙烯酸乙酯，甲基丙烯酸乙酯及其混合物。 由本发明提供的涂料组合物提供可用作保护和/或装饰涂料的透明不溶性涂料。
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公开(公告)号：US4264709A
公开(公告)日：1981-04-28
申请号：US4520
申请日：1979-01-18
CPC分类号： G03F7/0295 , Y10S430/117 , Y10S430/12 , Y10S430/121 , Y10S430/126
摘要： This invention relates to a series of photoinitiator combinations comprising mixtures of a primary photoinitiator in combination with N-halosuccinimides, N-haloacetanilides and N-halobenzanilides and photopolymerizable composition containing such combinations.
摘要翻译： 本发明涉及一系列光引发剂组合，其包含与N-卤代琥珀酰亚胺，N-卤代乙酰苯胺和N-卤代苯甲酰苯胺组合的初级光引发剂和含有这种组合的光聚合组合物的混合物。
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7.发明授权
公开(公告)号：UST962006I4
公开(公告)日：1977-09-06
申请号：US757180
申请日：1977-01-06
CPC分类号： C08F2/48 , Y10T428/31638 , Y10T428/31649
摘要： the invention relates to photopolymerizable polymeric compositions useful as coating and moldable compositions which are hardenable by ultraviolet radiation. These coating and moldable compositions comprise mixtures of photopolymerizable or photocrosslinkable acrylates of bis-(hydroxyalkyl) terephthalates and isophthalates in combination with at least one ethylenically unsaturated monomer component and a photoinitiator.
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8.发明授权Photopolymerizable polymeric compositions containing halogen containing aromatic ketones 失效含有芳族酮的卤素的可光聚合聚合物组合物
公开(公告)号：US4040923A
公开(公告)日：1977-08-09
申请号：US692403
申请日：1976-06-03
CPC分类号： G03F7/0295 , C08F2/50 , C09D4/00 , Y10S430/125
摘要： The invention relates to photopolymerizable polymeric compositions useful as coating and moldable compositions which are hardenable by ultraviolet radiation. These coating and moldable compositions comprise mixtures of photopolymerizable or photocrosslinkable unsaturated compounds and at least one photoinitiator selected from the group consisting of haloalkyl carboalkoxy substituted aromatic ketones.
摘要翻译： 本发明涉及可用作可通过紫外线辐射固化的涂层和可模塑组合物的光聚合聚合物组合物。 这些涂层和可模制组合物包含可光聚合或可光致交联的不饱和化合物和至少一种选自卤代烷基烷氧基取代的芳族酮的光引发剂的混合物。
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9.发明授权Photopolymerizable polymeric compositions containing halogen containing aromatic ketones 失效含有芳族酮的卤素的可光聚合聚合物组合物
公开(公告)号：US3988228A
公开(公告)日：1976-10-26
申请号：US609124
申请日：1975-08-29
CPC分类号： C08F2/50
摘要： The invention relates to photopolymerizable polymeric compositions useful as coating and moldable compositions which are hardenable by ultraviolet radiation. These coating and moldable compositions comprise mixtures of photopolymerizable or photocrosslinkable unsaturated compounds and at least one photoinitiator selected from the group consisting of halo-alkyl substituted aromatic ketones.
摘要翻译： 本发明涉及可用作可通过紫外线辐射固化的涂层和可模塑组合物的光聚合聚合物组合物。 这些涂层和可模制组合物包含可光聚合或可光致交联的不饱和化合物和至少一种选自卤代 - 烷基取代的芳族酮的光引发剂的混合物。
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公开(公告)号：US4134809A
公开(公告)日：1979-01-16
申请号：US826615
申请日：1977-08-22
IPC分类号： C08F251/02 , C09D4/06 , C09D101/10 , C08L1/00 , C08L3/00
CPC分类号： C09D4/06 , C08F251/02 , C09D101/10 , Y10T428/31525 , Y10T428/31529 , Y10T428/31638 , Y10T428/31703
摘要： This invention describes novel radiation curable cellulose ester compositions comprising a carboxylated cellulose ester, a glycidyl acrylate or methacrylate, and an effective amount of a photoinitiator. These compositions, when cured, give hard, tough coatings with excellent adhesion to certain metals.
摘要翻译： 本发明描述了包含羧化纤维素酯，丙烯酸缩水甘油酯或甲基丙烯酸缩水甘油酯和有效量的光引发剂的新型可辐射固化的纤维素酯组合物。 当这些组合物固化时，产生具有优异粘附性的硬质坚硬涂层。
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