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公开(公告)号：US5202468A
公开(公告)日：1993-04-13
申请号：US896721
申请日：1992-06-09
IPC分类号： C07C69/14
摘要： The object of the invention is a process for the preparation of methyl acetate starting from the methyl formate, characterized in that methyl formate is converted at a temperature of 170.degree. to 220.degree. C. in the presence of:a) a catalyst based on rhodium,b) an iodine-containing promoter selected from among the alkaline, alkaline earth, phosphonium or ammonium iodides and the mixtures of covalent compounds of iodine supplemented with a phosphine or a tertiary amine.c) a solvent selected from a cyclic N-alkyl amide.
摘要翻译： 本发明的目的是从甲酸甲酯制备乙酸甲酯的方法，其特征在于甲酸甲酯在170℃至220℃的温度下在以下存在下转化：a）基于铑的催化剂 ，b）选自碱金属，碱土金属，碘化鏻或碘化铵的含碘促进剂和补充有膦或叔胺的碘的共价化合物的混合物。 c）选自环状N-烷基酰胺的溶剂。
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公开(公告)号：US4892976A
公开(公告)日：1990-01-09
申请号：US219926
申请日：1988-07-15
申请人： Jean Cordier , Bernard Dussart , Francis Petit , Yves Castanet , Serge Melloul , Andre Mortreux
发明人： Jean Cordier , Bernard Dussart , Francis Petit , Yves Castanet , Serge Melloul , Andre Mortreux
IPC分类号： B01J27/08 , B01J27/128 , B01J31/28 , C07B61/00 , C07C45/00 , C07C45/49 , C07C47/02 , C07C47/06 , C07C67/00
CPC分类号： C07C45/49
摘要： The process for the preparation of an aldehyde of formula R--CHO in which R is an alkyl group of C.sub.1 -C.sub.7 comprises according to the invention the reaction on an alkyl formate of formula H--COOR in which R has the meaning given above, of a gas constituted mainly by CO, in the presence of(a) a catalyst based on a metal chosen from among Rh, Ru, Ir, mixtures of them or a mixture of Rh and/or Ru and/or Ir with Co, Ni or Fe,(b) a promoter chosen from among iodides and mixtures of covalent compounds of iodine and a phosphine or a tertiary amine,(c) a solvent consisting of a cyclic N-alkyl amide.
摘要翻译： 制备其中R为C 1 -C 7烷基的式R-CHO的醛的方法包括根据本发明的式H-COOR烷基甲酸酯的反应，其中R具有上述含义， 在（a）基于选自Rh，Ru，Ir的金属的催化剂，它们的混合物或Rh和/或Ru和/或Ir与Co，Ni或其混合物的混合物的存在下，主要由CO构成的气体 Fe，（b）选自碘化物的促进剂和碘和膦或叔胺的共价化合物的混合物，（c）由环状N-烷基酰胺组成的溶剂。
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公开(公告)号：US5214205A
公开(公告)日：1993-05-25
申请号：US868186
申请日：1992-04-14
申请人： Yves Castanet , Bruno Seuillet , Andre Mortreux , Francis Petit
发明人： Yves Castanet , Bruno Seuillet , Andre Mortreux , Francis Petit
摘要： The invention relates to a process for the preparation of acetic anhydride, characterized in that a gas containing essentially CO, at a pressure of at least 1 MPa, is reacted with methyl formate in the presence ofa) a rhodium-based catalyst,b) two iodine-containing promoters of different kind, successively ionic and covalent, andc) an N-substituted cyclic amide as solvent.
摘要翻译： 本发明涉及一种制备乙酸酐的方法，其特征在于在a）铑基催化剂存在下，使基本上含有至少1MPa压力的CO的气体与甲酸甲酯反应，b） 两种不同种类的含碘促进剂，连续离子和共价，和c）N-取代的环状酰胺作为溶剂。
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公开(公告)号：US5194676A
公开(公告)日：1993-03-16
申请号：US674745
申请日：1991-03-26
摘要： Saturated carboxylic esters are produced from alkyl formate and an olefin, without the presence of substantial amounts of carbon monoxide, at a temperature of 120.degree. to 280.degree. C., under a pressure of 1 to 3,000 bars, in the presence of a catalyst based on ruthenium coordinated by ligands selected from carbon monoxide, halogen atoms and amines, and in the presence of an amide as a solvent. The catalyst is selected from catalysts consisting essentially of RuCl.sub.3.3H.sub.2 O; catalysts consisting essentially of the combination of an RuCl.sub.3.3H.sub.2 O together with at least one stabilizer selected from iodine, covalent iodides and quaternary ammonium halides; catalysts comprising Ru.sub.3 (CO).sub.12 together with at least one stabilizer such as is mentioned above; and catalysts selected from RuI.sub.3, [RuCl.sub.2 (CO).sub.3 ].sub.2, Ru(NH.sub.3).sub.6 Cl.sub.3 and [Ru(NH.sub.3).sub.5 Cl]Cl.sub.2, comprising, where appropriate, in addition, at least one stabilizer such as is mentioned above.
摘要翻译： 在120至280℃的温度下，在1至3,000巴的压力下，在催化剂基的存在下，将饱和羧酸酯由甲酸烷基酯和烯烃生产，而不存在大量的一氧化碳 在由选自一氧化碳，卤素原子和胺的配体和在作为溶剂的酰胺存在下配位的钌上。 催化剂选自基本上由RuCl 3·3H 2 O组成的催化剂; 基本上由RuCl 3·3H 2 O与至少一种选自碘，共价碘化物和季铵卤化物的稳定剂的组合组成的催化剂; 包含Ru 3（CO）12的催化剂以及如上所述的至少一种稳定剂; 以及选自RuI 3，[RuCl 2（CO）3] 2，Ru（NH 3）6 Cl 3和[Ru（NH 3）5 Cl] Cl 2的催化剂，在适当的情况下还包括至少一种如上所述的稳定剂。
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公开(公告)号：US5847228A
公开(公告)日：1998-12-08
申请号：US875080
申请日：1997-07-17
申请人： Eric Monflier , Andre Mortreux , Yves Castanet
发明人： Eric Monflier , Andre Mortreux , Yves Castanet
IPC分类号： B01J31/20 , B01J31/22 , C07B61/00 , C07C45/49 , C07C45/50 , C07C47/02 , C07C47/11 , C07C47/225 , C07C47/228 , C07C67/29 , C07C67/293 , C07C67/313 , C07C67/347 , C07C69/14 , C07C69/67
CPC分类号： C07C67/293 , C07C45/49 , C07C45/50 , C07C67/347
摘要： The invention relates to a process for the hydroformylation of an olefin chosen from the alkenes represented by the formula CnH.sub.2n in which n is an integer less than or equal to 30, or chosen from functionalized olefins, by a CO/H.sub.2 gas mixture in a two-phase medium, this process consisting in placing in contact, on the one hand, an aqueous solution containing a catalytic system consisting of a water-soluble transition metal complex and a water-soluble phosphine, and, on the other hand, an olefin, in heating the reaction mixture obtained with stirring, after it has been placed under a pressure of the CO/H.sub.2 gas mixture, in which process a modified cyclodextrin is introduced into the aqueous solution containing the catalytic system.
摘要翻译： PCT No.PCT / FR96 / 00069 Sec。 371日期1997年7月17日 102（e）日期1997年7月17日PCT 1996年1月16日PCT PCT。 公开号WO96 / 22267 日期：1996年7月25日本发明涉及一种烯烃加氢甲酰化的方法，该烯烃选自式CnH2n所代表的烯烃，其中n为小于或等于30的整数，或选自官能化烯烃，通过CO / H 2 气体混合物在两相介质中，该方法一方面包含含有由水溶性过渡金属络合物和水溶性膦组成的催化体系的水溶液，另一方面 在将CO 2 / H 2气体混合物的压力放置在CO / H 2气体混合物的压力下，在搅拌下加热获得的反应混合物，在该方法中将改性的环糊精引入到含有催化体系的水溶液中。
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6.发明申请Block copolymer preparation method, block copolymers thus obtained and use thereof as compatibilizers 审中-公开嵌段共聚物制备方法，由此获得的嵌段共聚物和其作为增容剂的用途公开(公告)号：US20070260009A1
公开(公告)日：2007-11-08
申请号：US11818644
申请日：2007-06-15
IPC分类号： C08G73/02
CPC分类号： C08F297/02 , C08F297/026 , C08L53/00
摘要： The invention relates to a method of preparing a block copolymer, the first block of which is a polymer or a copolymer having at least one diene and the second block of which is a polymer with a polar monomer. The inventive method is characterised in that: first, the polymerisation or the copolymerisation of the first block is carried out in the presence of a catalyst comprising the product of the reaction of a rare earth alcoholate and an alkylating agent selected from among organolithiums, organomagnesiums, organozincs, organoaluminiums and borons; and, secondly, the copolymerisation of the polar monomer is performed with the first block in the presence of the same catalyst. The invention also relates to a block copolymer consisting of a first block comprising a polymer or a linear copolymer having at least one diene and a second block comprising a polymer presenting several hydroxy, epoxy and/or alkoxysilyl functions. Said copolymers can be used as compatibilisers in an elastomer matrix comprising a mineral filler.
摘要翻译： 本发明涉及一种制备嵌段共聚物的方法，其第一嵌段是具有至少一个二烯的聚合物或共聚物，第二嵌段是具有极性单体的聚合物。 本发明的方法的特征在于：首先，第一嵌段的聚合或共聚是在催化剂的存在下进行的，所述催化剂包括稀土醇化物和选自有机锂，有机镁， 有机铝，有机铝和硼; 其次，在相同的催化剂存在下，用第一嵌段进行极性单体的共聚。 本发明还涉及由包含聚合物或具有至少一个二烯的线性共聚物的第一嵌段和包含具有若干羟基，环氧和/或烷氧基甲硅烷基官能团的聚合物的第二嵌段组成的嵌段共聚物。 所述共聚物可以用作包含矿物填料的弹性体基质中的相容剂。
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7.发明申请Novel Catalytic Aluminum-Free Combination for Polymerizing Alpha-Olefins and Polymerization Method Using Same 失效用于聚合α-烯烃的新型催化无铝组合和使用其的聚合方法公开(公告)号：US20080269438A1
公开(公告)日：2008-10-30
申请号：US11922403
申请日：2006-06-21
申请人： Andre Mortreux , Regis Gauvin , Estelle Gautier
发明人： Andre Mortreux , Regis Gauvin , Estelle Gautier
CPC分类号： C08F10/00 , C08F10/14 , C08F4/645 , C08F4/64072
摘要： The invention concerns a novel catalytic combination for polymerizing alpha-olefins based on a titanium diamidide complex. The invention also concerns a method for polymerizing alpha-olefins using said catalytic combination, in the absence of any aluminum-containing compound. The inventive catalytic combination comprises: component A which is a dichlorinated titanium diamidide complex of general formula (I) wherein R represents a methyl group (component A2) or an isopropyl group (component A1); component B which is a dialkylmagnesium whereof the reaction with component A enables an alkylated component AA to be obtained: and as activator of said component AA, component C which is trispentafluorophenylboran (B(C6F5)3).
摘要翻译： 本发明涉及一种用于聚合基于钛二酰胺络合物的α-烯烃的新型催化剂组合。 本发明还涉及在没有任何含铝化合物的情况下使用所述催化组合聚合α-烯烃的方法。 本发明的催化剂组合包括：组分A，其为通式（I）的二氯化钛二酰胺络合物，其中R表示甲基（组分A2）或异丙基（组分A1）; 作为与组分A的反应的二烷基镁的组分B可以得到烷基化组分AA：和作为所述组分AA的活化剂，组分C是三氟苯基硼烷（B（C 6 H 6） 5 3）。
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8.发明授权
公开(公告)号：US6118025A
公开(公告)日：2000-09-12
申请号：US254218
申请日：1999-12-27
IPC分类号： B01J31/24 , C07B53/00 , C07B61/00 , C07C213/00 , C07C215/00 , C07C215/30 , C07B57/00
CPC分类号： C07C213/00 , C07B2200/07
摘要： The invention concerns a method for preparing an optically active alcohol of formula (I) in which the carbon atom indicated by the symbol * can have the configuration (R) or (S) and X represents a non-substituted amino group or a mono- or di-(C.sub.1 -C.sub.4)alkylamino group optionally salified from corresponding ketones by catalytic hydrogenation in the presence of a rhodium complex.
摘要翻译： PCT No.PCT / FR97 / 01592 Sec。 371 1999年12月27日第 102（e）日期1999年12月27日PCT 1997年9月10日提交PCT本发明涉及制备式（I）的光学活性醇的方法，其中由符号*表示的碳原子可以具有（R）或 （S），X表示在铑络合物的存在下通过催化氢化由相应的酮任选盐化的未取代的氨基或单或二（C1-C4）烷基氨基。
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公开(公告)号：US5574116A
公开(公告)日：1996-11-12
申请号：US214691
申请日：1994-03-18
CPC分类号： C08F10/00
摘要： A process is disclosed for the polymerization of olefins, using (i) a catalyst and (ii) an organometallic activator from Groups I, II or III of the Periodic Table at temperatures between 20.degree. and 250.degree. C., and pressure up to 200 bar, in solution, or in suspension in an inert liquid hydrocarbon, at temperatures between 160.degree. and 350.degree. C., under pressures of between 400 and 3000 bar, in a continuous manner in a reactor where the mean residence time of the catalyst is between 1 and 150 seconds. The catalyst comprises at least one titanium compound, at least one halogen-containing organoaluminum compound and at least one inorganic magnesium compound in suspension in at least one .alpha.,.omega.-dihaloalkane. The titanium compound is essentially a titanium (III) compound, the total content of titanium (II) and titanium (IV) being less than or equal to 15% of the total content of titanium. The catalyst is obtained by a process comprising, in a first step, the reduction of a titanium (IV) compound in an .alpha.,.omega.-dihaloalkane by means of a molar excess of at least one halogen-containing organoaluminum compound, in the absence of an ether, and, in a second step, the addition to the reaction mixture of a compound which forms a magnesium halide in situ without supplementary reduction of the titanium compound obtained in the first step. Molar ratios of the .alpha.,.omega.-dihaloalkane, the titanium compound, halogen-containing organoaluminum, and the compound which forms a magnesium halide in situ are also described.
摘要翻译： 公开了一种用于烯烃聚合的方法，其使用（i）催化剂和（ii）在20℃至250℃之间的元素周期表第I，II或III族的有机金属活化剂，压力高达200 在惰性液体烃中，160-150℃的温度下，在400-3000巴的压力下，在反应器中连续地在惰性液体烃中悬浮或悬浮，其中催化剂的平均停留时间为 1到150秒之间。 催化剂包含至少一种钛化合物，至少一种含卤素的有机铝化合物和至少一种α，ω-二卤代烷烃中的悬浮液中的至少一种无机镁化合物。 钛化合物基本上是钛（III）化合物，钛（II）和钛（IV）的总含量小于或等于钛总含量的15％。 该催化剂是通过一种方法获得的，该方法包括在第一步骤中，通过摩尔过量的至少一种含卤素的有机铝化合物在α，ω-二卤代烷烃中还原钛（IV）化合物， 醚，并且在第二步中，在没有补充还原第一步中获得的钛化合物的情况下向原位形成镁卤化物的化合物的反应混合物加入。 还描述了α，ω-二卤代烷烃，钛化合物，含卤素的有机铝和原位形成卤化镁的化合物的摩尔比。
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10.发明授权Catalytic composition for the polymerization of olefins and its process of preparation 失效用于烯烃聚合的催化组合物及其制备方法
公开(公告)号：US5068014A
公开(公告)日：1991-11-26
申请号：US369229
申请日：1989-06-22
CPC分类号： C08F10/00
摘要： Process for the preparation of a catalytic composition for the polymerization of olefins. At least partial electrochemical oxidation of aluminum in a solvent of .alpha.,.omega.-dihalogeno-alkane and simultaneously the electrochemical reduction of a compound of titanium (IV) occur in process.The catalytic composition comprises at least one titanium compound, at least one halogenated organo-aluminum compound and at least one inorganic magnesium compound in suspension in at least one .alpha.,.omega.-dihalogeno-alkane. The titanium compound is essentially a titanium (III) compound. The overall content of titanium (II) and titanium (IV) is less than or equal to 15% of the total titanium content.
摘要翻译： 制备烯烃聚合催化组合物的方法。 在α，ω-二卤代烷烃的溶剂中铝的至少部分电化学氧化，同时发生钛（IV）化合物的电化学还原。 所述催化剂组合物包含至少一种钛化合物，至少一种卤化有机铝化合物和至少一种α，ω-二卤代烷烃中悬浮液中的至少一种无机镁化合物。 钛化合物基本上是钛（III）化合物。 钛（II）和钛（IV）的总含量小于或等于总钛含量的15％。
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