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    Catalyst and process for the synthesis of saturated carboxylic esters
    1.
    发明授权
    Catalyst and process for the synthesis of saturated carboxylic esters 失效
    用于饱和羧酸酯合成的催化剂和方法

    公开(公告)号：US5194676A

    公开(公告)日：1993-03-16

    申请号：US674745

    申请日：1991-03-26

    申请人： Yves Castanet ,  Christophe Legrand ,  Andre Mortreux ,  Francis Petit

    发明人： Yves Castanet ,  Christophe Legrand ,  Andre Mortreux ,  Francis Petit

    IPC分类号： B01J27/13 ,  B01J31/02 ,  C07B61/00 ,  C07C67/303 ,  C07C67/38 ,  C07C69/24

    CPC分类号： C07C69/24 ,  C07C67/38

    摘要： Saturated carboxylic esters are produced from alkyl formate and an olefin, without the presence of substantial amounts of carbon monoxide, at a temperature of 120.degree. to 280.degree. C., under a pressure of 1 to 3,000 bars, in the presence of a catalyst based on ruthenium coordinated by ligands selected from carbon monoxide, halogen atoms and amines, and in the presence of an amide as a solvent. The catalyst is selected from catalysts consisting essentially of RuCl.sub.3.3H.sub.2 O; catalysts consisting essentially of the combination of an RuCl.sub.3.3H.sub.2 O together with at least one stabilizer selected from iodine, covalent iodides and quaternary ammonium halides; catalysts comprising Ru.sub.3 (CO).sub.12 together with at least one stabilizer such as is mentioned above; and catalysts selected from RuI.sub.3, [RuCl.sub.2 (CO).sub.3 ].sub.2, Ru(NH.sub.3).sub.6 Cl.sub.3 and [Ru(NH.sub.3).sub.5 Cl]Cl.sub.2, comprising, where appropriate, in addition, at least one stabilizer such as is mentioned above.

    摘要翻译： 在120至280℃的温度下，在1至3,000巴的压力下，在催化剂基的存在下，将饱和羧酸酯由甲酸烷基酯和烯烃生产，而不存在大量的一氧化碳 在由选自一氧化碳，卤素原子和胺的配体和在作为溶剂的酰胺存在下配位的钌上。 催化剂选自基本上由RuCl 3·3H 2 O组成的催化剂; 基本上由RuCl 3·3H 2 O与至少一种选自碘，共价碘化物和季铵卤化物的稳定剂的组合组成的催化剂; 包含Ru 3（CO）12的催化剂以及如上所述的至少一种稳定剂; 以及选自RuI 3，[RuCl 2（CO）3] 2，Ru（NH 3）6 Cl 3和[Ru（NH 3）5 Cl] Cl 2的催化剂，在适当的情况下还包括至少一种如上所述的稳定剂。

    Process for the preparation of aldehydes
    3.
    发明授权
    Process for the preparation of aldehydes 失效
    醛的制备方法

    公开(公告)号：US4892976A

    公开(公告)日：1990-01-09

    申请号：US219926

    申请日：1988-07-15

    申请人： Jean Cordier ,  Bernard Dussart ,  Francis Petit ,  Yves Castanet ,  Serge Melloul ,  Andre Mortreux

    发明人： Jean Cordier ,  Bernard Dussart ,  Francis Petit ,  Yves Castanet ,  Serge Melloul ,  Andre Mortreux

    IPC分类号： B01J27/08 ,  B01J27/128 ,  B01J31/28 ,  C07B61/00 ,  C07C45/00 ,  C07C45/49 ,  C07C47/02 ,  C07C47/06 ,  C07C67/00

    CPC分类号： C07C45/49

    摘要： The process for the preparation of an aldehyde of formula R--CHO in which R is an alkyl group of C.sub.1 -C.sub.7 comprises according to the invention the reaction on an alkyl formate of formula H--COOR in which R has the meaning given above, of a gas constituted mainly by CO, in the presence of(a) a catalyst based on a metal chosen from among Rh, Ru, Ir, mixtures of them or a mixture of Rh and/or Ru and/or Ir with Co, Ni or Fe,(b) a promoter chosen from among iodides and mixtures of covalent compounds of iodine and a phosphine or a tertiary amine,(c) a solvent consisting of a cyclic N-alkyl amide.

    摘要翻译： 制备其中R为C 1 -C 7烷基的式R-CHO的醛的方法包括根据本发明的式H-COOR烷基甲酸酯的反应，其中R具有上述含义， 在（a）基于选自Rh，Ru，Ir的金属的催化剂，它们的混合物或Rh和/或Ru和/或Ir与Co，Ni或其混合物的混合物的存在下，主要由CO构成的气体 Fe，（b）选自碘化物的促进剂和碘和膦或叔胺的共价化合物的混合物，（c）由环状N-烷基酰胺组成的溶剂。

    Process for producing methyl acetate from methyl formate
    4.
    发明授权
    Process for producing methyl acetate from methyl formate 失效
    从甲酸甲酯生产乙酸甲酯的方法

    公开(公告)号：US5202468A

    公开(公告)日：1993-04-13

    申请号：US896721

    申请日：1992-06-09

    申请人： Jean A. Cordier ,  Francis P. Petit ,  Yves Castanet ,  Serge Melloul ,  Andre Mortreux

    发明人： Jean A. Cordier ,  Francis P. Petit ,  Yves Castanet ,  Serge Melloul ,  Andre Mortreux

    IPC分类号： C07C69/14

    CPC分类号： C07C69/14 ,  C07C67/36

    摘要： The object of the invention is a process for the preparation of methyl acetate starting from the methyl formate, characterized in that methyl formate is converted at a temperature of 170.degree. to 220.degree. C. in the presence of:a) a catalyst based on rhodium,b) an iodine-containing promoter selected from among the alkaline, alkaline earth, phosphonium or ammonium iodides and the mixtures of covalent compounds of iodine supplemented with a phosphine or a tertiary amine.c) a solvent selected from a cyclic N-alkyl amide.

    摘要翻译： 本发明的目的是从甲酸甲酯制备乙酸甲酯的方法，其特征在于甲酸甲酯在170℃至220℃的温度下在以下存在下转化：a）基于铑的催化剂 ，b）选自碱金属，碱土金属，碘化鏻或碘化铵的含碘促进剂和补充有膦或叔胺的碘的共价化合物的混合物。 c）选自环状N-烷基酰胺的溶剂。

    Process for the hydroformylation of an olefin in a two-phase medium
    5.
    发明授权
    Process for the hydroformylation of an olefin in a two-phase medium 失效
    在两相介质中烯烃加氢甲酰化的方法

    公开(公告)号：US5847228A

    公开(公告)日：1998-12-08

    申请号：US875080

    申请日：1997-07-17

    申请人： Eric Monflier ,  Andre Mortreux ,  Yves Castanet

    发明人： Eric Monflier ,  Andre Mortreux ,  Yves Castanet

    IPC分类号： B01J31/20 ,  B01J31/22 ,  C07B61/00 ,  C07C45/49 ,  C07C45/50 ,  C07C47/02 ,  C07C47/11 ,  C07C47/225 ,  C07C47/228 ,  C07C67/29 ,  C07C67/293 ,  C07C67/313 ,  C07C67/347 ,  C07C69/14 ,  C07C69/67

    CPC分类号： C07C67/293 ,  C07C45/49 ,  C07C45/50 ,  C07C67/347

    摘要： The invention relates to a process for the hydroformylation of an olefin chosen from the alkenes represented by the formula CnH.sub.2n in which n is an integer less than or equal to 30, or chosen from functionalized olefins, by a CO/H.sub.2 gas mixture in a two-phase medium, this process consisting in placing in contact, on the one hand, an aqueous solution containing a catalytic system consisting of a water-soluble transition metal complex and a water-soluble phosphine, and, on the other hand, an olefin, in heating the reaction mixture obtained with stirring, after it has been placed under a pressure of the CO/H.sub.2 gas mixture, in which process a modified cyclodextrin is introduced into the aqueous solution containing the catalytic system.

    摘要翻译： PCT No.PCT / FR96 / 00069 Sec。 371日期1997年7月17日 102（e）日期1997年7月17日PCT 1996年1月16日PCT PCT。 公开号WO96 / 22267 日期：1996年7月25日本发明涉及一种烯烃加氢甲酰化的方法，该烯烃选自式CnH2n所代表的烯烃，其中n为小于或等于30的整数，或选自官能化烯烃，通过CO / H 2 气体混合物在两相介质中，该方法一方面包含含有由水溶性过渡金属络合物和水溶性膦组成的催化体系的水溶液，另一方面 在将CO 2 / H 2气体混合物的压力放置在CO / H 2气体混合物的压力下，在搅拌下加热获得的反应混合物，在该方法中将改性的环糊精引入到含有催化体系的水溶液中。

    Process for the preparation of a catalyst for the polymerization of olefins
    6.
    发明授权
    Process for the preparation of a catalyst for the polymerization of olefins 失效
    制备烯烃聚合催化剂的方法

    公开(公告)号：US5574116A

    公开(公告)日：1996-11-12

    申请号：US214691

    申请日：1994-03-18

    申请人： Karel Bujadoux ,  Jean-Michel Brusson ,  Francis Petit ,  Andre Mortreux

    发明人： Karel Bujadoux ,  Jean-Michel Brusson ,  Francis Petit ,  Andre Mortreux

    IPC分类号： C08F4/654 ,  C08F10/00

    CPC分类号： C08F10/00

    摘要： A process is disclosed for the polymerization of olefins, using (i) a catalyst and (ii) an organometallic activator from Groups I, II or III of the Periodic Table at temperatures between 20.degree. and 250.degree. C., and pressure up to 200 bar, in solution, or in suspension in an inert liquid hydrocarbon, at temperatures between 160.degree. and 350.degree. C., under pressures of between 400 and 3000 bar, in a continuous manner in a reactor where the mean residence time of the catalyst is between 1 and 150 seconds. The catalyst comprises at least one titanium compound, at least one halogen-containing organoaluminum compound and at least one inorganic magnesium compound in suspension in at least one .alpha.,.omega.-dihaloalkane. The titanium compound is essentially a titanium (III) compound, the total content of titanium (II) and titanium (IV) being less than or equal to 15% of the total content of titanium. The catalyst is obtained by a process comprising, in a first step, the reduction of a titanium (IV) compound in an .alpha.,.omega.-dihaloalkane by means of a molar excess of at least one halogen-containing organoaluminum compound, in the absence of an ether, and, in a second step, the addition to the reaction mixture of a compound which forms a magnesium halide in situ without supplementary reduction of the titanium compound obtained in the first step. Molar ratios of the .alpha.,.omega.-dihaloalkane, the titanium compound, halogen-containing organoaluminum, and the compound which forms a magnesium halide in situ are also described.

    摘要翻译： 公开了一种用于烯烃聚合的方法，其使用（i）催化剂和（ii）在20℃至250℃之间的元素周期表第I，II或III族的有机金属活化剂，压力高达200 在惰性液体烃中，160-150℃的温度下，在400-3000巴的压力下，在反应器中连续地在惰性液体烃中悬浮或悬浮，其中催化剂的平均停留时间为 1到150秒之间。 催化剂包含至少一种钛化合物，至少一种含卤素的有机铝化合物和至少一种α，ω-二卤代烷烃中的悬浮液中的至少一种无机镁化合物。 钛化合物基本上是钛（III）化合物，钛（II）和钛（IV）的总含量小于或等于钛总含量的15％。 该催化剂是通过一种方法获得的，该方法包括在第一步骤中，通过摩尔过量的至少一种含卤素的有机铝化合物在α，ω-二卤代烷烃中还原钛（IV）化合物， 醚，并且在第二步中，在没有补充还原第一步中获得的钛化合物的情况下向原位形成镁卤化物的化合物的反应混合物加入。 还描述了α，ω-二卤代烷烃，钛化合物，含卤素的有机铝和原位形成卤化镁的化合物的摩尔比。

    Catalytic composition for the polymerization of olefins and its process of preparation
    7.
    发明授权
    Catalytic composition for the polymerization of olefins and its process of preparation 失效
    用于烯烃聚合的催化组合物及其制备方法

    公开(公告)号：US5068014A

    公开(公告)日：1991-11-26

    申请号：US369229

    申请日：1989-06-22

    申请人： Jean M. Brusson ,  Karel Bujadoux ,  Francis Petit ,  Jean M. Fuchs ,  Andre Mortreux

    发明人： Jean M. Brusson ,  Karel Bujadoux ,  Francis Petit ,  Jean M. Fuchs ,  Andre Mortreux

    IPC分类号： C08F4/60 ,  C08F4/62 ,  C08F4/642 ,  C08F4/655 ,  C08F10/00

    CPC分类号： C08F10/00

    摘要： Process for the preparation of a catalytic composition for the polymerization of olefins. At least partial electrochemical oxidation of aluminum in a solvent of .alpha.,.omega.-dihalogeno-alkane and simultaneously the electrochemical reduction of a compound of titanium (IV) occur in process.The catalytic composition comprises at least one titanium compound, at least one halogenated organo-aluminum compound and at least one inorganic magnesium compound in suspension in at least one .alpha.,.omega.-dihalogeno-alkane. The titanium compound is essentially a titanium (III) compound. The overall content of titanium (II) and titanium (IV) is less than or equal to 15% of the total titanium content.

    摘要翻译： 制备烯烃聚合催化组合物的方法。 在α，ω-二卤代烷烃的溶剂中铝的至少部分电化学氧化，同时发生钛（IV）化合物的电化学还原。 所述催化剂组合物包含至少一种钛化合物，至少一种卤化有机铝化合物和至少一种α，ω-二卤代烷烃中悬浮液中的至少一种无机镁化合物。 钛化合物基本上是钛（III）化合物。 钛（II）和钛（IV）的总含量小于或等于总钛含量的15％。

    Catalytic composition for the polymerization of olefins and its process of preparation
    8.
    发明授权
    Catalytic composition for the polymerization of olefins and its process of preparation 失效
    用于烯烃聚合的催化组合物及其制备方法

    公开(公告)号：US5356848A

    公开(公告)日：1994-10-18

    申请号：US117319

    申请日：1993-09-07

    申请人： Jean M. Brusson ,  Karel Bujadoux ,  Francis Petit ,  Jean M. Fuchs ,  Andre Mortreux

    发明人： Jean M. Brusson ,  Karel Bujadoux ,  Francis Petit ,  Jean M. Fuchs ,  Andre Mortreux

    IPC分类号： C08F4/60 ,  C08F4/62 ,  C08F4/642 ,  C08F4/655 ,  C08F10/00 ,  B01J31/00

    CPC分类号： C08F10/00

    摘要： Process for the preparation of a catalytic composition for the polymerization of olefins. At least partial electrochemical oxidation of aluminum in a solvent of .alpha.,.omega.-dihalogeno-alkane and simultaneously the electrochemical reduction of a compound of titanium (IV) occur in process.The catalytic composition comprises at least one titanium compound, at least one halogenated organo-aluminum compound and at least one inorganic magnesium compound in suspension in at least one .alpha.,.omega.-dihalogeno-alkane. The titanium compound is essentially a titanium (III) compound. The overall content of titanium (II) and titanium (IV) is less than or equal to 15% of the total titanium content.

    摘要翻译： 制备烯烃聚合催化组合物的方法。 在α，ω-二卤代烷烃的溶剂中铝的至少部分电化学氧化，同时发生钛（IV）化合物的电化学还原。 所述催化剂组合物包含至少一种钛化合物，至少一种卤化有机铝化合物和至少一种α，ω-二卤代烷烃中悬浮液中的至少一种无机镁化合物。 钛化合物基本上是钛（III）化合物。 钛（II）和钛（IV）的总含量小于或等于总钛含量的15％。