摘要:
A process for preparing peroxydisulfates by electrolysis in a diaphragm cell uses a diaphragm, the active part of which comprises a cation exchange polymer made up of a membrane with a sulfonated polystyrene base resin supported by a polypropylene fabric. The process is applicable to the preparation of peroxydisulfates of alkali metals and of ammonium.
摘要:
A process for producing amino alcohols by electrosynthesis of nitro alcohols.Reduction of the nitro group is performed in three stages on a cathode made of a material having a strong hydrogen overpotential. During the second stage of reduction, the electronegative potential is higher, and in the last stage the sulfuric solution of amino alcohol obtained is subjected to a purification operation by electro-electrodialysis (EED), followed by an elimination of water.The process is particularly useful for the production of 2-nitro-2-methyl-1-propanol, 2-nitro-2-methyl-1, 3-propanediol, 2-nitro-2-ethyl-1, 3-propanediol, 2-nitro-1-butanol, tris(hydroxymethyl) nitromethane.
摘要:
A process for reducing aliphatic nitro compounds to the corresponding nitroalcohols. Chemical electroreduction is performed on a bimetallic cathode consisting of a copper support metal and a zinc or cadmium active element.
摘要:
Potassium superperoxide compositions contain an additive product selected from the oxides of alkaline-earth metals and magnesium, particularly calcium oxide CaO, incorporated preferably in a concentration between 2 and 30% by weight, based on the weight of the total composition. These compositions of KO.sub.2 are used to regenerate breathable atmospheres, particularly as regenerating charges in closed circuit individual rebreathing devices.
摘要:
A process for the preparation of sodium percarbonate is disclosed in which concentrated hydrogen peroxide is caused to act generally in the presence of a crystallization modifier on a fluid suspension of sodium carbonate decahydrate in a substantially saturated solution of sodium carbonate, the sodium carbonate decahydrate being in a quantity such that the enthalpy of its dissolution compensates for the enthalpy of crystallization or formation of the sodium percarbonate or other exothermic phenomena. The process is applicable to obtaining sodium percarbonate, of which the elementary particle is a regular rhombohedric crystal.
摘要:
Bleaching agent activators which function to release active oxygen. The activator is an amidine of the formula: ##STR1## wherein X is hydrogen, a halogen, an alkyl, aryl, alkylaryl, cycloalkyl, thioalkyl, oxylalkyl, acyl, an inorganic acid radical such as SO.sub.3 H, or an organoinorganic radical, R.sub.1, R.sub.2 and R.sub.3 designate hydrogen, an alkyl, aryl, alkylaryl, cycloalkyl or acyl radical; HA designates an inorganic or organic monoacid or the equivalent part of a polyacid. This class of amidines improves the effectiveness, at regular or moderate temperature, of liquid or solid bleaching agents, such as hydrogen peroxide, alkaline perborates and percarbonates.
摘要:
An oxygen chemical generation respiration apparatus of the cartridge type intended to receive an absorbing mass in the form of pellets such as potassium superoxide pellets, is provided with a central connector (5) for intake of the gases to be purified, vertically extended as an intake conduit (5') to a clearance space (9) above the housing bottom at the level of a lower perforated wall (7) supporting the regenerating charge, this conduit coming out in the center of this wall to which it is fastened; the upper part (6) of the cartridge housing, on the output side of the gases to be treated, is provided with a series of radiators (11) parallel to the direction of circulation of the gas flows in the regenerating charge, fastened to the housing walls (12) and whose length is less than the spacing between the two walls (7) and (8).
摘要:
In a process of making sodium perborate, crystallization is performed in the presence of an organic polymer with a high potential content of free carboxylic groups derived from maleic anhydride, selected from the copolymers of maleic anhydride with an organic compound with an ethylene bond. The process is applicable to obtaining sodium perborate crystals of high apparent density of good resistance to abrasion and of limited, relatively high granulometric size.