BORON OR ALUMINUM COMPLEXES
    1.
    发明申请
    BORON OR ALUMINUM COMPLEXES 有权
    硼或铝复合物

    公开(公告)号:US20110171112A1

    公开(公告)日:2011-07-14

    申请号:US12736195

    申请日:2009-03-19

    摘要: The present invention relates to boron and aluminum complexes, to the preparation thereof, and to the use thereof for solubilizing ionic compounds. The complexes have one of the following formulae: in which D represents B or Al; R1 represents R, RF, NO2, CN, C(═O)OR, RSO2, or RFSO2; —X1—, —X2—, —X3— and X4 each represent a divalent group >C═O, >C═NC≡N, >C═C(C≡N)2, >CR2R3 or >SO2; —Y1—, —Y2— and —Y3— each represent a divalent group —O—, >N(C≡N), >N(CORF), >N(SO2R4), >NR4, >N(COR4) or >N(SO2RF); R, R2 and R3 each represent H, an alkyl group, an aryl group, an alkylaryl group, an arylalkyl group, an oxaalkyl group or an alkenyl group; R4 represents an alkyl group, an aryl group, an alkylaryl group, a heteroaryl group, an arylalkyl group, an oxaalkyl group, an alkenyl group or an RFCH2— group; RF is a perfluoroalkyl group, a partially fluorinated alkyl group, or a partially or totally fluorinated phenyl group; each of the R′2 and R′3 groups represents R or F.

    摘要翻译: 本发明涉及硼和铝络合物,其制备方法及其用于增溶离子化合物的用途。 所述络合物具有下式之一:其中D表示B或Al; R1表示R,RF,NO2,CN,C(= O)OR,RSO2或RFSO2; -X1-,-X2-,-X3-和X4各自表示二价基团> C = O,> C =NC≡N,> C = C(C≡N)2,> CR2R3或> SO2; -Y1-,-Y2-和-Y3-各自表示二价基团-O - ,> N(C≡N),> N(CORF),> N(SO 2 R 4),NR 4,N(COR 4) N(SO2RF); R,R 2和R 3各自表示H,烷基,芳基,烷基芳基,芳烷基,氧杂烷基或烯基; R4表示烷基,芳基,烷基芳基,杂芳基,芳基烷基,氧杂烷基,烯基或RFCH2-基团; RF是全氟烷基,部分氟化的烷基或部分或全部氟化的苯基; R'2和R'3各自表示R或F.

    METHOD FOR PRODUCING A LITHIUM OR SODIUM BATTERY
    2.
    发明申请
    METHOD FOR PRODUCING A LITHIUM OR SODIUM BATTERY 审中-公开
    生产锂电池或钠电池的方法

    公开(公告)号:US20130298386A1

    公开(公告)日:2013-11-14

    申请号:US13704418

    申请日:2011-06-16

    IPC分类号: H01M4/139

    摘要: The invention relates to a method for producing a battery using A+ (Li+ or Na+) as an electrochemical carrier, as well as to the resulting batteries. The method involves assembling together a negative electrode, a positive electrode, and an electrolyte, and then exposing the assembly to a firm charge at the operating temperature of the battery. The electrolyte is a ceramic or a solution of an A+ salt in a polar liquid, a polymer, or the mixture thereof. The active material of the negative electrode is a material which has a redox couple, the potential of which is 0 V to 1.6 V relative to the A+/A+ couple. The active material of the positive electrode is a material which has a redox couple, the potential of which is higher then that of the couple of the negative electrode. The positive electrode used during assembly consists of a current collector having a comprises material which contains the positive active material and at least one sacrificial salt of a cations E+ is selected from among Li+, Na+, K+ and the onium cations, and a redox action selected from azide anions, ketocarboxylate anions, and hydrazide anions, optionally in the form of a polymers.

    摘要翻译: 本发明涉及使用A +(Li +或Na +)作为电化学载体制造电池的方法,以及所得的电池。 该方法包括将负极,正电极和电解质组装在一起,然后在电池的工作温度下将组件暴露于牢固的电荷。 电解质是陶瓷或A +盐在极性液体,聚合物或其混合物中的溶液。 负极的活性材料是具有氧化还原电位的材料,其电位相对于A + / A +电压为0V至1.6V。 正极的活性物质是具有氧化还原电位的材料,其电位高于负电极的电位。 在组装期间使用的正电极由具有包含正极活性材料的材料和至少一种阳离子E +的牺牲盐选自Li +,Na +,K +和鎓阳离子的集电器组成,并且选择氧化还原作用 从叠氮阴离子,酮羧酸根阴离子和酰肼阴离子,任选地以聚合物的形式。

    Boron or aluminum complexes
    3.
    发明授权
    Boron or aluminum complexes 有权
    硼或铝络合物

    公开(公告)号:US08563761B2

    公开(公告)日:2013-10-22

    申请号:US12736195

    申请日:2009-03-19

    IPC分类号: C07F5/06 C07F5/02 C01G49/02

    摘要: The present invention relates to boron and aluminum complexes, to the preparation thereof, and to the use thereof for solubilizing ionic compounds. The complexes have one of the following formulae: in which D represents B or Al; R1 represents R, RF, NO2, CN, C(═O)OR, RSO2, or RFSO2; —X1—, —X2—, —X3— and X4 each represent a divalent group >C═O, >C═NC≡N, >C═C(C≡N)2, >CR2R3 or >SO2; —Y1—, —Y2— and —Y3— each represent a divalent group —O—, >N(C≡N), >N(CORF), >N(SO2R4), >NR4, >N(COR4) or >N(SO2RF); R, R2 and R3 each represent H, an alkyl group, an aryl group, an alkylaryl group, an arylalkyl group, an oxaalkyl group or an alkenyl group; R4 represents an alkyl group, an aryl group, an alkylaryl group, a heteroaryl group, an arylalkyl group, an oxaalkyl group, an alkenyl group or an RFCH2— group; RF is a perfluoroalkyl group, a partially fluorinated alkyl group, or a partially or totally fluorinated phenyl group; each of the R′2 and R′3 groups represents R or F.

    摘要翻译: 本发明涉及硼和铝络合物,其制备方法及其用于增溶离子化合物的用途。 所述络合物具有下式之一:其中D表示B或Al; R1表示R,RF,NO2,CN,C(= O)OR,RSO2或RFSO2; -X1-,-X2-,-X3-和X4各自表示二价基团> C = O,> C = NC = N,> C = C(C = N)2,> CR2R3或> SO2; -Y2-,-Y2-和-Y3-各自表示二价基团-O - ,> N(C = N),> N(CORF),> N(SO 2 R 4),NR 4,N(COR 4) N(SO2RF); R,R 2和R 3各自表示H,烷基,芳基,烷基芳基,芳烷基,氧杂烷基或烯基; R4表示烷基,芳基,烷基芳基,杂芳基,芳基烷基,氧杂烷基,烯基或RFCH2-基团; RF是全氟烷基,部分氟化烷基或部分或全部氟化苯基; R'2和R'3各自表示R或F.

    METHOD FOR PREPARING ALKALI METAL AND TRANSITION METAL FLUOROSULFATES
    8.
    发明申请
    METHOD FOR PREPARING ALKALI METAL AND TRANSITION METAL FLUOROSULFATES 有权
    制备碱金属和过渡金属氟化物的方法

    公开(公告)号:US20140291572A1

    公开(公告)日:2014-10-02

    申请号:US13697573

    申请日:2011-05-11

    IPC分类号: C01D15/06 C01D5/00

    摘要: The invention relates to a method for preparing an alkali metal and transition metal fluorosulfate that is useful as an electrode material in an electrochemical battery that operates by alkali ion exchange. The method includes a first step that involves: preparing a mixture of precursors of elements making up fluorosulfate, placing said mixture in contact with a solid polymer at ambient temperature, subjecting the reaction medium to a heat treatment that aims to melt the polymer, and subsequently reacting the precursors with one another. Said polymer is one that is solid at ambient temperature, has a melting point lower than the reaction temperature of the precursors, is stable at least up to the reaction temperature of the precursors, and is soluble in a nonpolar aprotic organic solvent.

    摘要翻译: 本发明涉及一种制备碱金属和过渡金属氟硫酸盐的方法,其可用作通过碱离子交换操作的电化学电池中的电极材料。 该方法包括第一步骤,其包括:制备构成氟硫酸盐的元素的前体的混合物,将所述混合物与环境温度下的固体聚合物接触,使反应介质经受热处理,其目的是熔化聚合物,随后 使前体彼此反应。 所述聚合物是在环境温度下为固体的聚合物,其熔点低于前体的反应温度,至少稳定至前体的反应温度,并且可溶于非极性非质子有机溶剂。