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公开(公告)号：US09293767B2
公开(公告)日：2016-03-22
申请号：US13124723
申请日：2009-10-23
申请人： Jean-Marie Tarascon , Nadir Recham , Michel Armand
发明人： Jean-Marie Tarascon , Nadir Recham , Michel Armand
IPC分类号： H01M4/48 , H01M4/58 , C01B25/26 , C01B25/37 , C01B25/45 , C01B25/455 , C01B33/20 , C01G1/10 , C01G49/00 , C01G51/00 , C01G53/00 , H01M10/052
CPC分类号： H01M4/5825 , C01B25/26 , C01B25/37 , C01B25/45 , C01B25/455 , C01B33/20 , C01G1/10 , C01G49/009 , C01G51/006 , C01G53/006 , C01P2002/54 , C01P2002/72 , C01P2002/77 , C01P2002/88 , C01P2004/04 , C01P2006/40 , H01M4/582 , H01M10/052 , Y10T428/2982
摘要： A material is made up of particles of an optionally-doped fluorosulphate. The fluorosulphate has a distorted Tavorite type structure of formula (A1−aA′a)x(Z1−bZ′b)z(SO4)sFf (I) where A=Li or Na, A′ 0 a hole or at least one doping element, Z=at least one element selected from Fe, Co and Ni, Z′=a hole or at least one doping element, the indices a, b, x, z, s, and f are selected to assure the electroneutrality of the compound and a≧0, b≧0, x≧0, z>0, s>0, f>0, the respective quantities a and b of dopant A and Z′ being such that the Tavorite type structure is preserved. The material is obtained from the precursors thereof by an ionothermal route or ceramic route in a closed reactor. The material is of particular use as an active electrode material.
摘要翻译： 材料由任选掺杂的氟代硫酸盐的颗粒组成。 氟代硫酸盐具有式（A1-aA'a）x（Z1-bZ'b）z（SO4）sFf（I）变形的Tavorite型结构，其中A = Li或Na，A'0为空穴或至少一种掺杂 元素Z =选自Fe，Co和Ni中的至少一种元素，Z'=空穴或至少一种掺杂元素，选择指数a，b，x，z，s和f以确保电中性 化合物和a≥0，b≥0，x≥0，z> 0，s> 0，f> 0，掺杂剂A和Z'的各自的量a和b使得保留了Tavorite型结构。 该材料通过在封闭反应器中的离子热路径或陶瓷路线从其前体获得。 该材料特别用作活性电极材料。
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2.发明申请METHOD FOR PREPARING A SOLID-STATE BATTERY BY SINTERING UNDER PULSATING CURRENT 有权通过在脉冲电流下烧结制备固态电池的方法公开(公告)号：US20130189562A1
公开(公告)日：2013-07-25
申请号：US13578415
申请日：2011-02-17
申请人： Michael Dolle , Patrick Rozier , Gaelle Delaizir , Jean-Marie Tarascon , Virginie Viallet , Mathieu Morcrette , Vincent Seznec , Renaud Bouchet , Abdelmaula Aboulaich , Laurence Tortet
发明人： Michael Dolle , Patrick Rozier , Gaelle Delaizir , Jean-Marie Tarascon , Virginie Viallet , Mathieu Morcrette , Vincent Seznec , Renaud Bouchet , Abdelmaula Aboulaich , Laurence Tortet
CPC分类号： H01M2/0207 , H01M2/204 , H01M4/02 , H01M4/0471 , H01M4/139 , H01M4/5825 , H01M10/0525 , H01M10/0562 , H01M10/058 , H01M2004/021 , H01M2300/0071 , Y02E60/122 , Y10T29/49115
摘要： The present invention relates to a method for preparing a completely solid Li-ion battery having a solid state body wherein the battery is assembled in a single step by stacking at least one layer of a powder mix including a positive electrode active material and a solid electrolyte, at least one intermediate layer of a solid electrolyte and at least one layer of a powder mix including a negative electrode active material and a solid electrolyte, and simultaneous sintering of the three layers at a pressure of at least 20 MPa, under pulsating current. The invention also relates to the Li-ion battery obtained by such a method.
摘要翻译： 本发明涉及一种制备具有固态体的完全固体锂离子电池的方法，其中通过将至少一层包含正极活性材料和固体电解质的粉末混合物堆叠在一个步骤中组装电池 ，固体电解质的至少一个中间层和至少一层包含负极活性材料和固体电解质的粉末混合物，并且在脉动电流下以至少20MPa的压力同时烧结三层。 本发明还涉及通过这种方法获得的锂离子电池。
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公开(公告)号：US08062791B1
公开(公告)日：2011-11-22
申请号：US12157443
申请日：2008-06-10
CPC分类号： H01M4/54 , H01M4/34 , H01M4/485 , H01M10/052 , H01M10/32
摘要： A battery cathode comprises an electrode of silver, molybdenum, oxygen, fluorine and chlorine and having a higher discharge capacity expressed as milliampere hour per gram of material (mAh/g) available from silver reduction at a potential above 3V as compared to that of SVO material versus lithium. The battery cathode compound can be represented by Ag6 Mo2O7F3Cl. The cathode is devoted for primary lithium batteries application and most notably can be used in a medical battery, such as a defibrillator battery [e.g. implantable cardioverter defibrillator (ICD) battery] having a lithium metal anode.
摘要翻译： 电池阴极包括银，钼，氧，氟和氯的电极，并且具有更高的放电容量，表示为每毫升材料（mAh / g）表示的毫安小时，其电位高于3V时的银还原，与SVO相比 材料与锂。 电池阴极化合物可以由Ag6 Mo2O7F3Cl表示。 阴极用于一次锂电池应用，并且最显着地可用于医疗电池，例如除颤器电池[例如， 具有锂金属阳极的植入式心律转复除颤器（ICD）电池]。
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4.发明申请公开(公告)号：US20100308473A1
公开(公告)日：2010-12-09
申请号：US12739848
申请日：2008-10-24
申请人： Patrice Simon , Pierre-Louis Taberna , Thierry Lebey , Jean Pascal Cambronne , Vincent Bley , Quoc Hung Luan , Jean Marie Tarascon
发明人： Patrice Simon , Pierre-Louis Taberna , Thierry Lebey , Jean Pascal Cambronne , Vincent Bley , Quoc Hung Luan , Jean Marie Tarascon
IPC分类号： H01L25/065 , H01L21/60 , H01L23/538 , H01L23/46 , H01L21/768 , H01L21/70 , H01L21/02 , B23P11/00
CPC分类号： H01L21/76 , B82Y10/00 , B82Y40/00 , H01L23/473 , H01L24/64 , H01L24/67 , H01L24/70 , H01L24/72 , H01L25/0657 , H01L29/413 , H01L2221/1094 , H01L2224/16 , H01L2225/06527 , H01L2924/01006 , H01L2924/01013 , H01L2924/01023 , H01L2924/01024 , H01L2924/01029 , H01L2924/01033 , H01L2924/01046 , H01L2924/01047 , H01L2924/01051 , H01L2924/01058 , H01L2924/01061 , H01L2924/01075 , H01L2924/01078 , H01L2924/01079 , H01L2924/01082 , H01L2924/014 , H01L2924/14 , H01L2924/15747 , Y10T29/49833 , H01L2924/00
摘要： A method of fabricating an electrically conductive mechanical interconnection element (12) comprises: a first stage of electrochemically depositing a structure comprising a plurality of metal wires (2a) of sub-micrometric diameter projecting from the likewise metallic surface of a substrate (2); and a second stage of controlled partial dissolution of said wires to reduce their diameter. A method of making a mechanical and/or electrical interconnection, the method comprising the steps consisting in: fabricating two interconnection elements by a method as described above; and placing said interconnection elements face to face and pressing one against the other so as to cause the nanometric wires projecting from the surfaces of said elements to interpenetrate and tangle together. A three-dimensional electronic device comprising a stack of microelectronic chips mechanically and electrically connected to one another by such interconnection elements.
摘要翻译： 制造导电机械互连元件（12）的方法包括：电化学沉积包括从基底（2）的同样金属表面突出的多个亚微米直径金属线（2a）的结构的第一阶段; 以及所述电线的受控部分溶解以减小其直径的第二阶段。 一种制造机械和/或电互连的方法，所述方法包括以下步骤：通过上述方法制造两个互连元件; 并且将所述互连元件面对面地放置并相对于另一个按压，以使得从所述元件的表面突出的纳米线互穿并缠结在一起。 一种三维电子设备，其包括通过这种互连元件彼此机械地和电连接的微电子芯片堆叠。
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5.发明授权公开(公告)号：US07736813B2
公开(公告)日：2010-06-15
申请号：US11793865
申请日：2005-12-19
CPC分类号： G02F1/1533 , G02F1/1506
摘要： The invention concerns an electrochromic cell with emission controlled by electrodeposition under the action of a control voltage. The cell comprises the following flexible elements, superimposed and respectively in intimate contact: a first electrode (11) intended to be connected to a first potential of the control voltage, a first porous layer (12), formed of a mixture of PVDF-HFP, PEO and an activated carbon powder, a porous separator (13), formed of a mixture of PVDF-HFP and PEO, a second electrode (14) formed of a grid and connected to a second potential of the control voltage, a second porous layer (15), formed of a mixture of PVDF-HFP, PEO and carbon powder, an aqueous electrolytic solution containing a copper salt being contained in the first flexible layer (12), in the separator (13) and in the second flexible layer (15).
摘要翻译： 本发明涉及在控制电压的作用下通过电沉积控制发射的电致变色电池。 电池包括叠加并分别紧密接触的以下柔性元件：旨在连接到控制电压的第一电位的第一电极（11），由PVDF-HFP的混合物形成的第一多孔层（12） ，PEO和活性炭粉末，由PVDF-HFP和PEO的混合物形成的多孔分离器（13），由栅格形成并连接到控制电压的第二电位的第二电极（14），第二多孔 由PVDF-HFP，PEO和碳粉末的混合物形成的层（15），包含在第一柔性层（12）中的铜盐的水性电解液，隔板（13）和第二柔性层 （15）。
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公开(公告)号：US06187061B1
公开(公告)日：2001-02-13
申请号：US09315434
申请日：1999-05-20
IPC分类号： H01G900
CPC分类号： H01G9/155 , H01G4/30 , H01G11/72 , H01M6/181 , H01M10/4264 , H01M16/00 , Y02E60/13 , Y10T29/417
摘要： Supercapacitor cell electrode and separator elements formulated as membranes of plasticized polymers matrix compositions are laminated with electrically conductive current collector elements to form flexible, unitary supercapacitor structures. The matrix plasticizer component is extracted from the laminate with polymer-inert solvent and replaced with electrolyte solution to activate the supercapacitor. Various arrangements of cell structure elements provide parallel and series cell structures which yield improved specific energy capacity and increased voltage output for utilization demands. The supercapacitor elements may also be laminated with similar polymeric rechargeable battery cell structures to provide hybrid devices capable of delivering both high energy and high power as needed in electronic systems.
摘要翻译： 配制为增塑聚合物基体组合物的膜的超级电容器电极和隔离元件与导电集电器元件层叠以形成柔性的单一超级电容器结构。 用聚合物惰性溶剂从层压体中提取基质增塑剂组分，并用电解质溶液代替以激活超级电容器。 电池结构元件的各种布置提供并联和串联电池结构，其产生改进的比能量容量和增加的电压输出用于利用需求。 超级电容器元件也可以与类似的聚合物可再充电电池单元结构层压，以提供能够在电子系统中根据需要传送高能量和高功率的混合设备。
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公开(公告)号：US5635138A
公开(公告)日：1997-06-03
申请号：US373830
申请日：1995-01-17
CPC分类号： G01N23/20008 , H01M10/48 , H01M6/181
摘要： An apparatus and method for monitoring structural changes of an electrode in a rechargeable battery include an in situ x-ray study electrochemical cell holder (30) comprising top and bottom cell holder members (32, 34) including at least one beryllium window element (36) for transmission of diffractometer x-radiation. A rechargeable battery cell (43) mounted within the x-ray cell holder enclosure comprises an electrolyte/separator element (68) interposed between positive and negative electrodes (64, 66). A current collector element (70) formed of an electrically-conductive open-mesh grid is disposed between the positive electrode and the separator to enable ion-conducting contact of the electrode and separator while maintaining electrical continuity between the electrode and an external x-ray cell holder terminal (54). As a result of this arrangement, the positive electrode need not contact the window element to establish an electrical battery circuit, but may be sufficiently spaced from the window to avoid electrolytic corrosion of the beryllium element. The in situ x-ray electrochemical cell holder and battery cell structure allow for continuous monitoring of the structural changes in electrode materials during charge/discharge cycling.
摘要翻译： 用于监测可再充电电池中的电极的结构变化的装置和方法包括原位x射线研究电化学电池座（30），其包括顶部和底部电池保持器构件（32,34），其包括至少一个铍窗口元件（36） ）用于传播衍射仪x辐射。 安装在x射线电池保持器外壳内的可再充电电池单元（43）包括插在正极和负极（64,66）之间的电解质/分离元件（68）。 由导电开口网格形成的集电器元件（70）设置在正电极和隔板之间，以使电极和隔板之间能够进行离子导电接触，同时保持电极与外部x射线之间的电连续性 电池座端子（54）。 作为这种布置的结果，正极不需要接触窗口元件以建立电池电路，而是可以与窗口充分间隔开以避免铍元件的电解腐蚀。 原位X射线电化学电池座和电池单元结构允许连续监测充电/放电循环期间电极材料的结构变化。
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公开(公告)号：US5478668A
公开(公告)日：1995-12-26
申请号：US241255
申请日：1994-05-11
IPC分类号： C08J9/26 , C08J9/28 , H01M2/02 , H01M2/16 , H01M4/64 , H01M6/18 , H01M6/30 , H01M6/32 , H01M6/42 , H01M6/46 , H01M10/04 , H01M10/05 , H01M10/052 , H01M10/0565 , H01M2/08
CPC分类号： H01M10/05 , C08J9/28 , H01M10/0431 , H01M10/052 , H01M10/0565 , H01M2/1653 , H01M6/181 , H01M6/32 , H01M6/46 , C08J2327/16 , H01M2300/0085 , H01M6/30 , H01M6/42
摘要： A rechargeable lithium ion battery comprises a plurality of interleaved flexible electrolytic cells, each of which is a unitary planar laminated structure comprising polymeric anode, cathode, and intermediate electrolyte layers disposed between electrically conductive anode and cathode collector foil elements. One of the collector foils of a cell has an open grid structure to allow penetration of electrolyte solution into the cell layer while the other is substantially more continuous to provide supporting strength to the cell. At least a pair of cells having respective continuous foil anode and cathode collectors are interleaved in spiral-folded fashion to present those collector foils at the outer surface of the resulting structure to provide terminal contacts for the resulting high-capacity, low-profile battery.
摘要翻译： 可充电锂离子电池包括多个交错的柔性电解电池，每个电解电容器是包括设置在导电阳极和阴极集电体箔元件之间的聚合物阳极，阴极和中间电解质层的整体平面层叠结构。 电池的集电箔之一具有开放的栅格结构，以允许电解质溶液渗透到电池层中，而另一个基本上更连续以向电池提供支撑强度。 具有相应连续的箔阳极和阴极集电器的至少一对电池以螺旋折叠的方式交错，以在所得结构的外表面处提供这些集电箔，以为所得的大容量，低轮廓的电池提供端子触点。
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9.发明授权
公开(公告)号：US5422203A
公开(公告)日：1995-06-06
申请号：US952392
申请日：1992-09-28
CPC分类号： H01M10/05
摘要： Irreversible loss of lithium during the initial discharge cycle of secondary batteries with carbon intercalation electrodes is substantially reduced by employing as the cell electrolyte a non-aqueous solution of LiPF.sub.6 in a mixture of dimethylcarbonate and ethylene carbonate. By this means, in a secondary battery cell comprising, for example, a Li.sub.1+x Mn.sub.2 O.sub.4 positive electrode and a graphite negative electrode, up to about 90% of the theoretical level of lithium can be reversibly cycled at an exceptionally high rate of about C/1 (complete discharge in one hour).
摘要翻译： 通过在碳酸二甲酯和碳酸亚乙酯的混合物中使用LiPF 6的非水溶液作为电池电解质，可以显着降低在具有碳插层电极的二次电池的初始放电循环期间锂的不可逆损耗。 通过这种方式，在包含例如Li1 + xMn2O4正极和石墨负极的二次电池中，高达约90％的理论水平的锂可以以非常高的约C / 1（1小时内完全放电）。
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公开(公告)号：US5418091A
公开(公告)日：1995-05-23
申请号：US110262
申请日：1993-08-23
IPC分类号： C08J9/26 , C08J9/28 , H01M2/16 , H01M6/18 , H01M6/32 , H01M10/05 , H01M10/052 , H01M10/0565
CPC分类号： C08J9/28 , H01M10/05 , H01M10/052 , H01M10/0565 , H01M2/1653 , H01M6/181 , H01M6/32 , C08J2327/16 , H01M2300/0085 , Y02P70/54 , Y10T29/49115
摘要： A flexible polymeric film useful as an interelectrode separator or electrolyte member in electrolytic devices, such as rechargeable batteries, comprises a copolymer of vinylidene fluoride with 8 to 25% hexafluoropropylene. The film may be cast or formed as a self-supporting layer retaining about 20% to 70% of a high-boiling solvent or solvent mixture comprising such solvents as ethylene carbonate, propylene carbonate, dimethyl carbonate, and dibutyl phthalate. The film may be used in such form or after leaching of the retained solvent with a film-inert low-boiling solvent to provide a separator member into which a solution of electrolytic salt is subsequently imbibed to displace retained solvent or replace solvent previously leached from the polymeric matrix.
摘要翻译： 用作电解装置（例如可再充电电池）中的电极间隔离物或电解质构件的柔性聚合物膜包括偏二氟乙烯与8至25％六氟丙烯的共聚物。 该膜可以被浇铸或形成为保持约20％至70％的包含碳酸亚乙酯，碳酸亚丙酯，碳酸二甲酯和邻苯二甲酸二丁酯等溶剂的高沸点溶剂或溶剂混合物的自支撑层。 该膜可以以这种形式使用，或者在用惰性低温溶剂浸出后使用，以提供隔板构件，随后吸收电解盐溶液以置换保留的溶剂或替代以前从 聚合物基质。
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