Process for making curable amide gellant compounds

    公开(公告)号:US20070123663A1

    公开(公告)日:2007-05-31

    申请号:US11289882

    申请日:2005-11-30

    IPC分类号: C08F20/00

    摘要: Disclosed is a process for preparing a compound of the formula wherein R1 is an alkyl group having at least one ethylenic unsaturation, an arylalkyl group having at least one ethylenic unsaturation, or an alkylaryl group having at least one ethylenic unsaturation, R2 and R3 each, independently of the others, are alkylene groups, arylene groups, arylalkylene groups, or alkylarylene groups, R4 and R5 each, independently of the other, is a hydrogen atom or an alkyl group, and n is an integer representing the number of repeat amide units and is at least 1, said process comprising: (a) reacting a diacid of the formula HOOC—R2—COOH with a diamine of the formula in the presence of a catalyst, a solvent, and a coupling agent to form an oligoamide intermediate; and (b) reacting the oligoamide intermediate with an alcohol of the formula R1—OHto form the product.

    Method for preparing curable amide gellant compounds
    3.
    发明申请
    Method for preparing curable amide gellant compounds 有权
    制备可固化酰胺胶凝剂化合物的方法

    公开(公告)号:US20070123724A1

    公开(公告)日:2007-05-31

    申请号:US11290328

    申请日:2005-11-30

    IPC分类号: C07C237/02

    摘要: Disclosed is a process for preparing a compound of the formula wherein R1 is an alkyl group having at least one ethylenic unsaturation, an arylalkyl group having at least one ethylenic unsaturation, or an alkylaryl group having at least one ethylenic unsaturation, R2 and R3 each, independently of the others, are alkylene groups, arylene groups, arylalkylene groups, or alkylarylene groups, and n is an integer representing the number of repeat amide units and is at least 1, said process comprising: (a) reacting a diacid of the formula HOOC—R2—COOH with a diamine of the formula in the absence of a solvent while removing water from the reaction mixture to form an acid-terminated oligoamide intermediate; and (b) reacting the acid-terminated oligoamide intermediate with a monoalcohol of the formula R1—OH in the presence of a coupling agent and a catalyst to form the product.

    摘要翻译: 公开了一种制备下式化合物的方法,其中R 1是具有至少一个烯属不饱和键的烷基,具有至少一个烯属不饱和键的芳基烷基或具有至少一个烯属不饱和键的烷基芳基 烯键式不饱和键,R 2和R 3各自独立地为亚烷基,亚芳基,芳基亚烷基或烷基亚芳基,n为代表 重复酰胺单元的数目并且至少为1,所述方法包括:(a)使式Ⅳ的二酸与-in-line-formula description =“In-Line Formulas”end =“lead”→> HOOC-R' 在不存在溶剂的情况下,在从反应混合物中除去水的情况下,使用下式所示的二胺,在线式描述=“In-line Formula”中, 以形成酸封端的低聚酰胺中间体; 和(b)使酸封端的低聚酰胺中间体与下式的一元醇反应:式中:=“引入”→R 1 -OH 在偶联剂和催化剂的存在下,<?in-line-formula description =“In-line formula”end =“tail”?>以形成产物。

    Phase change inks containing curable amide gellant compounds
    4.
    发明申请
    Phase change inks containing curable amide gellant compounds 有权
    含有可固化酰胺胶凝剂化合物的相变油墨

    公开(公告)号:US20070123606A1

    公开(公告)日:2007-05-31

    申请号:US11290121

    申请日:2005-11-30

    IPC分类号: C09D11/00

    CPC分类号: C09D11/101 C09D11/34

    摘要: Disclosed is a phase change ink comprising a colorant, an initiator, and a phase change ink carrier, said carrier comprising at least one radically curable monomer compound and a compound of the formula wherein R1 and R1′ each, independently of the other, is an alkyl group having at least one ethylenic unsaturation, an arylalkyl group having at least one ethylenic unsaturation, or an alkylaryl group having at least one ethylenic unsaturation, R2, R2′, and R3 each, independently of the others, are alkylene groups, arylene groups, arylalkylene groups, or alkylarylene groups, and n is an integer representing the number of repeat amide units and is at least 1. Also disclosed herein is a method of printing with the phase change ink.

    摘要翻译: 公开了一种相变油墨,其包含着色剂,引发剂和相变油墨载体,所述载体包含至少一种可自由基固化的单体化合物和下式化合物其中R 1和R 2 各自独立地是具有至少一个烯属不饱和度的烷基,具有至少一个烯属不饱和键的芳基烷基或具有至少一个烯属不饱和键的烷基芳基,R“ R 2,R 2,R 3和R 3各自独立地为亚烷基,亚芳基,芳基亚烷基或烷基亚芳基,n 是表示重复酰胺单元数的整数,并且至少为1.本文还公开了用相变油墨印刷的方法。

    Phase change inks
    5.
    发明申请
    Phase change inks 有权
    相变油墨

    公开(公告)号:US20070120908A1

    公开(公告)日:2007-05-31

    申请号:US11289620

    申请日:2005-11-30

    IPC分类号: B41J2/175 C09D11/00 C09D11/02

    CPC分类号: C09D11/101 C09D11/34

    摘要: The phase change ink a viscosity of from about 4 mPa-s to about 50 mPa-s at a first temperature and has a viscosity of from 104 mPa-s to about 109 mPa-s at a second lower temperature. The second temperature may be below the first temperature by at least 10° C. but by no more than 50° C. The first temperature may be from about 60° C. to about 110° C. and the second temperature may be from about 20° C. to about 70 ° C. A curve of log10 viscosity of the phase change ink plotted against temperature in degrees Celsius may have a slope having an absolute value less than 0.02 at the first temperature and have a slope having an absolute value greater than 0.08 for at least a region second temperatures.

    摘要翻译: 相变墨在第一温度下的粘度为约4mPa·s至约50mPa·s,并且具有10-4mPa·s至约10°/ 在第二较低温度下,SUP> mPa-s。 第二温度可以低于第一温度至少10℃,但不超过50℃。第一温度可以为约60℃至约110℃,第二温度可以为约 20℃至约70℃。相变墨水的对数粘度曲线相对于摄氏温度的曲线可以具有在第一温度下具有小于0.02的绝对值的斜率,以及 在至少一个区域第二温度下具有绝对值大于0.08的斜率。

    Phase change inks containing photoinitiator with phase change properties and gellant affinity
    6.
    发明申请
    Phase change inks containing photoinitiator with phase change properties and gellant affinity 失效
    含有相变性能和胶凝剂亲和力的光引发剂的相变油墨

    公开(公告)号:US20070120910A1

    公开(公告)日:2007-05-31

    申请号:US11290202

    申请日:2005-11-30

    IPC分类号: B41J2/175

    摘要: Disclosed is a phase change ink comprising a colorant, an initiator, and an ink vehicle, said ink vehicle comprising (a) at least one radically curable monomer compound, and (b) a compound of the formula wherein R1 is an alkylene, arylalkylene, or alkylarylene group, R2 and R2′ each, independently of the other, are alkylene, arylene, arylalkylene, or alkylarylene groups, R3 and R3′ each, independently of the other, are either (a) photoinitiating groups, or (b) groups which are alkyl, aryl, arylalkyl, or alkylaryl groups, provided that at least one of R3 and R3′ is a photoinitiating group, and X and X′ each, independently of the other, is an oxygen atom or a group of the formula —NR4—, wherein R4 is a hydrogen atom, an alkyl group, an aryl group, an arylalkyl group, or an alkylaryl group.

    摘要翻译: 公开了包含着色剂,引发剂和油墨载体的相变油墨,所述油墨载体包含(a)至少一种可自由基固化的单体化合物,和(b)下式化合物其中R 1, SUB>是亚烷基,亚芳基亚烷基或烷基亚芳基,R 2和R 2各自独立地是亚烷基,亚芳基,芳基亚烷基或烷基亚芳基, R 3和R 3各自独立地是(a)光引发基团,或(b)烷基,芳基,芳基烷基或烷基芳基的基团 基团,条件是R 3和R 3'中的至少一个是光引发基团,X和X'各自独立地是氧原子或 式-NR 4 - 的基团,其中R 4是氢原子,烷基,芳基,芳基烷基或烷基芳基。

    Ink jet of functionalized waxes
    7.
    发明申请
    Ink jet of functionalized waxes 失效
    功能化蜡的喷墨

    公开(公告)号:US20060158491A1

    公开(公告)日:2006-07-20

    申请号:US11034714

    申请日:2005-01-14

    IPC分类号: B41J2/17

    CPC分类号: C09D11/101

    摘要: An ink jet ink includes an ink vehicle, wherein the ink vehicle includes at least one wax monomer functionalized to include in the chain at least one reactive group curable upon exposure to radiation. The reactive group is preferably curable via cationic or free radical polymerization. In a preferred embodiment, the ink vehicle includes a wax monomer having a structure: wherein C represents a cationically curable group and R represents a radically curable group. The inks may be used to form an image by jetting the ink onto a transfuse member surface, increasing the viscosity of the ink upon the transfuse member surface, subsequently transferring the ink from the transfuse member surface to an image receiving substrate, and exposing the ink to radiation following the transfer to the image receiving substrate to effect reaction of the at least one reactive group.

    摘要翻译: 喷墨油墨包括油墨载体,其中油墨载体包括至少一种蜡官能化的蜡单体,其在链中包含在暴露于辐射时可固化的至少一种反应性基团。 反应性基团优选通过阳离子或自由基聚合可固化。 在优选的实施方案中,油墨载体包括具有以下结构的蜡单体:其中C表示阳离子可固化基团,R表示可自由基固化的基团。 油墨可以用于通过将墨喷射到输入构件表面上来形成图像,增加在输入构件表面上的墨的粘度,随后将墨从输液构件表面转移到图像接收基底,并使墨 在转移到图像接收基板之后进行辐射以实现至少一个反应性基团的反应。

    Photoinitiator with phase change properties and gellant affinity
    10.
    发明申请
    Photoinitiator with phase change properties and gellant affinity 有权
    具有相变性质和胶凝剂亲和力的光引发剂

    公开(公告)号:US20070123723A1

    公开(公告)日:2007-05-31

    申请号:US11290207

    申请日:2005-11-30

    IPC分类号: C07C237/02

    摘要: Disclosed is a compound of the formula wherein R1 is an alkylene, arylene, arylalkylene, or alkylarylene group, R2 and R2′ each independently of the other, are alkylene, arylene, arylalkylene, or alklarylene groups, R3′ each, independently of the other, are either (a) photoinitiating groups, or (b) groups which are alkyl, aryl, arylalkyl, or alkylaryl groups, provide that at least one of R3 and R3′ is a photoinitiating group, and X and X′ each, independently of the other, is an oxygen atom or a group of the formula —NR4—, wherein R4 is a hydrogen atom, an alkyl group, an aryl group, or an alkylaryl group.

    摘要翻译: 公开了下式的化合物其中R 1是亚烷基,亚芳基,芳基亚烷基或烷基亚芳基,R 2和R 2各自 独立于亚烷基,亚芳基,芳基亚烷基或亚烷基,R 3 3各自独立地为(a)光引发基团,或(b)基团,其为烷基, 芳基,芳烷基或烷基芳基,提供R 3和R 3'中的至少一个是光引发基团,X和X'各自独立地为其它 是氧原子或式-NR 4 - - 的基团,其中R 4是氢原子,烷基,芳基或烷基芳基 。