公开(公告)号：US4795847A

公开(公告)日：1989-01-03

申请号：US151697

申请日：1988-02-02

申请人： Jens Weitkamp ,  Marita Neuber ,  Wilhelm Holtmann ,  Gerd Collin ,  Hans Spengler

发明人： Jens Weitkamp ,  Marita Neuber ,  Wilhelm Holtmann ,  Gerd Collin ,  Hans Spengler

IPC分类号： B01J29/06 ,  B01J29/40 ,  C07B61/00 ,  C07C1/00 ,  C07C2/66 ,  C07C2/86 ,  C07C15/24 ,  C07C67/00 ,  C07C2/68

CPC分类号： C07C2/66 ,  B01J29/40 ,  C07C2/864 ,  C07C2529/40

摘要： A process for the preparation of 2,6-dialkyl-naphthalenes comprising selectively alkylating naphthalene or 2-alkyl-naphthalene with alkylating agent in the presence of a zeolite catalyst at 250.degree. to 345.degree. C. which dialkyl-naphthalenes are useful for the preparation of naphthalene 2,6-dicarboxylic acid used to produce high-quality polyesters or polyamides.

摘要翻译： 一种制备2,6-二烷基萘的方法，包括在250至345℃的沸石催化剂存在下，用烷基化剂选择性地烷基化萘或2-烷基萘，该二烷基萘可用于制备 用于生产高品质聚酯或聚酰胺的萘2,6-二羧酸。

公开(公告)号：US5396012A

公开(公告)日：1995-03-07

申请号：US980988

申请日：1992-11-24

申请人： Marita Neuber ,  Udo Dettmeier ,  Ernst I. Leupold

发明人： Marita Neuber ,  Udo Dettmeier ,  Ernst I. Leupold

IPC分类号： B01J29/08 ,  C07B61/00 ,  C07C2/66 ,  C07C2/70 ,  C07C2/86 ,  C07C15/24 ,  C07C2/68

CPC分类号： C07C2/861 ,  C07C2/66 ,  C07C2/864 ,  C07C2529/08

摘要： Process for the preparation of monoisopropylnaphthalene by alkylation of naphthalene with the aid of zeolites of the faujasite type as catalysts, wherein the cations of the zeolites have been replaced by alkaline earth metal ions.

摘要翻译： 借助于八面沸石沸石作为催化剂烷基化萘，制备单异丙基萘的方法，其中沸石的阳离子被碱土金属离子代替。

公开(公告)号：US5227529A

公开(公告)日：1993-07-13

申请号：US944798

申请日：1992-09-14

申请人： Marita Neuber ,  Ernst I. Leupold

发明人： Marita Neuber ,  Ernst I. Leupold

IPC分类号： C07C45/46

CPC分类号： C07C45/46

摘要： A process for the acylation of naphthyl ethers of the formula ##STR1## using acylating agents of the formula R.sup.2 --CO--X to give acylated naphthyl ethers of the formula ##STR2## in which R.sup.1 and R.sup.2 independently of one another are C.sub.1 -- to C.sub.10 -alkyl, C.sub.2 -- to C.sub.10 -alkenyl or C.sub.3 - to C.sub.8 -cycloalkyl and R.sup.2 is additionally C.sub.6 - to C.sub.10 -aryl and X is Cl, Br, --OCOR.sup.2, OH or C.sub.1 - to C.sub.3 -alkoxy, comprises carrying out the reaction presence of zeolite catalysts which have the formula Z.Al.sub.2 O.sub.3.x SiO.sub.2 (III) in the anhydrous and template-free form, in which Z is M.sup.I.sub.2 O, M.sup.II O and/or (M.sup.III).sub.2 O.sub.3, in which M.sup.I is an alkali metal atom, ammonium or a hydrogen atom, M.sup.II is an alkaline earth metal atom and M.sup.III is a rare earth metal of atomic number 57 to 71 in the periodic table of the elements, and x is a number from 4 to 4000, with the proviso that at least 50% of the negative lattice charges are compensated by protons, ammonium and/or the other metal ions mentioned under M.sup.II and M.sup.III, and the pores of which are formed from at least 10 tetrahedral atoms.

摘要翻译： 使用式R2-CO-X的酰化剂酰化式（I）的萘基醚的方法，得到式（II）的酰化萘基醚，其中R 1和R 2独立地为一个 另一个是C 1至C 10 - 烷基，C 2至C 10 - 烯基或C 3 -C 8 - 环烷基，R 2另外为C 6 -C 10 - 芳基，X为Cl，Br，-OCOR 2，OH或C 1至C 3 - 烷氧基 包括以无水和无模板形式存在具有式Z.Al 2 O 3。x SiO 2（III）的沸石催化剂的反应，其中Z为MI2O，MIIO和/或（MIII）2O3，其中MI 是碱金属原子，铵或氢原子，MII是碱土金属原子，MIII是元素周期表中原子序数57〜71的稀土金属，x是4〜4000的数， 条件是至少50％的负晶格电荷由质子，铵和/或MII和MIII下提及的其它金属离子补偿，孔的孔为fo 从至少10个四面体原子。