公开(公告)号：US5910381A

公开(公告)日：1999-06-08

申请号：US843910

申请日：1997-04-17

申请人： Jeremy Barker ,  Feng Gao ,  Arnie Stux

发明人： Jeremy Barker ,  Feng Gao ,  Arnie Stux

IPC分类号： H01M4/66 ,  H01M10/0525 ,  H01M10/0569 ,  H01M6/14

CPC分类号： H01M10/0525 ,  H01M10/0569 ,  H01M4/66 ,  Y10T29/49108 ,  Y10T29/49112

摘要： The subject invention discloses a novel electrolyte for a solid battery system. Specifically, an electrolyte solvent of chlorinated diethyl carbonates demonstrate good electrochemical stability in conjunction with specific anode and cathode materials. When used with a propylene carbonate co-solvent, it reduces or eliminates the decomposition of propylene carbonate during the first cycle. It is appropriate with a variety of electrolyte salts, and especially with LiBF.sub.4. Chloro-substituted diethyl carbonates also show good high and low temperature performance in electrochemical cells.

摘要翻译： 本发明公开了一种用于固体电池系统的新型电解质。 具体来说，氯化二乙基碳酸酯的电解质溶剂与特定的阳极和阴极材料结合显示出良好的电化学稳定性。 当与碳酸丙烯酯共溶剂一起使用时，其可以在第一个循环中减少或消除碳酸亚丙酯的分解。 适用于各种电解质盐，尤其适用于LiBF4。 氯取代的碳酸二乙酯在电化学电池中也表现出良好的高低温性能。

公开(公告)号：US5972055A

公开(公告)日：1999-10-26

申请号：US680421

申请日：1996-07-15

申请人： Feng Gao ,  Jeremy Barker ,  Porter H. Mitchell ,  Jeffrey Swoyer ,  Arnie Stux

发明人： Feng Gao ,  Jeremy Barker ,  Porter H. Mitchell ,  Jeffrey Swoyer ,  Arnie Stux

IPC分类号： H01M6/16 ,  H01M6/18 ,  H01M10/052 ,  H01M10/0565 ,  H01M10/38

CPC分类号： H01M10/052 ,  H01M10/0565 ,  H01M6/164 ,  H01M6/188 ,  Y10T29/49115

摘要： The subject invention discloses a novel method of providing a binary electrolyte-solvent solution in a solid battery system. A first component of this binary electrolyte solvent system is provided by a material which acts as a plasticizer in the formation of a solid polymeric matrix (separator), composite cathode and/or composite anode, and which also acts as an electrolyte solvent in the completed electrochemical cell. The second component of the binary electrolyte solvent system is an electrolyte solvent, which generally carries the electrolyte salt into the electrolytic cell precursor. The first and second components of the binary electrolyte solvent system mix within the electrolytic cell, dispersing the electrolyte salt throughout the binary electrolyte solvent system. The addition of the electrolyte salt to the electrolytic cell precursor acts to activate the cell precursor, and to form a functional electrolytic cell or battery system.

摘要翻译： 本发明公开了一种在固体电池系统中提供二元电解质溶剂溶液的新方法。 这种二元电解质溶剂体系的第一个组分由一种在形成固体聚合物基质（分离器），复合阴极和/或复合阳极中作为增塑剂的材料提供，并且还可以在完成后的电解质溶剂 电化学电池。 二元电解质溶剂系统的第二组分是电解质溶剂，其通常将电解质盐携带到电解槽前体中。 二元电解质溶剂系统的第一和第二组分在电解池内混合，将电解质盐分散在整个二元电解质溶剂系统中。 将电解质盐添加到电解槽前体中起作用以活化细胞前体，并形成功能性电解池或电池系统。