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    Insecticidal compounds
    3.
    发明授权
    Insecticidal compounds 有权
    杀虫化合物

    公开(公告)号：US09545106B2

    公开(公告)日：2017-01-17

    申请号：US14118573

    申请日：2012-05-30

    申请人： Jerome Yves Cassayre ,  Peter Renold ,  Myriem El Qacemi ,  Thomas Pitterna ,  Julie Clementine Toueg

    发明人： Jerome Yves Cassayre ,  Peter Renold ,  Myriem El Qacemi ,  Thomas Pitterna ,  Julie Clementine Toueg

    IPC分类号： C07D413/00 ,  A01N43/80 ,  C07D261/02 ,  C07D327/02 ,  C07D413/14 ,  C07D411/12 ,  C07D413/12

    CPC分类号： A01N43/80 ,  C07D261/02 ,  C07D327/02 ,  C07D411/12 ,  C07D413/12 ,  C07D413/14

    摘要： The present invention provides compounds of formula (I): wherein A1, A2, A3 and A4 are independently of one another C—H, C—R5, or nitrogen; B1—B2—B3—B4 is —CH2—C═N—CH2—, —CH2—N—CH2—CH2—, —CH2—C═CH-0- or —CH═C—CH2-0-; G1 is oxygen or sulfur; L is a single bond or C1-C8alkylene; R1 is hydrogen, C1-C8alkyl, C1-C8alkylcarbonyl-, C1-C8alkoxy, C2-C8alkenyl, C2-C8alkynyl, C1-C8alkoxy-C1-C8alkyl, aryl or aryl substituted by one to three R6, or R1 is heterocyclyl or heterocyclyl substituted by one to three R6 or C1-C8alkoxycarbonyl-; R2 is hydrogen, C1-C8haloalkyl or C1-C8alkyl; R3 is C1-C8haloalkyl; R4 is aryl or aryl substituted by one to three R6, or R4 is heterocyclyl or heterocyclyl substituted by one to three R6; Y1 is CR7R8, C═O or C═S; Y2, Y3 and Y4 are independently CR7R8, C=0, C═S, N—R9, O, S, SO or SO2; wherein at least two adjacent ring atoms in the ring formed by Y1, Y2, Y3 and Y4 are heteroatoms; each R7 and R8 is independently hydrogen, halogen, C1-C8alkyl, or C1-C8haloalkyl; and R5, R6, R7, R8 and R9 are as defined in the claims. The invention also relates to processes and intermediates for preparing these compounds, to insecticidal, acaricidal, nematicidal and molluscicidal compositions comprising these compounds and to methods of using these compounds to control insect, acarine, nematode and mollusc pests.

    摘要翻译： 本发明提供式（I）化合物：其中A1，A2，A3和A4彼此独立地为C-H，C-R5或氮; B1-B2-B3-B4是-CH2-C≡N-CH2-，-CH2-N-CH2-CH2-，-CH2-C≡CH-O-或-CH = C-CH2-O-; G1是氧或硫; L是单键或C1-C8亚烷基; R 1是氢，C 1 -C 8烷基，C 1 -C 8烷基羰基 - ，C 1 -C 8烷氧基，C 2 -C 8烯基，C 2 -C 8炔基，C 1 -C 8烷氧基-C 1 -C 8烷基，被1至3个R 6取代的芳基或芳基，或R 1是杂环基或杂环基取代 一至三个R6或C1-C8烷氧基羰基 - ; R2是氢，C1-C8卤代烷基或C1-C8烷基; R3是C1-C8卤代烷基; R4是被一至三个R6取代的芳基或芳基，或R4是被一至三个R6取代的杂环基或杂环基; Y1是CR7R8，C = O或C = S; Y2，Y3和Y4独立地为CR7R8，C = 0，C = S，N-R9，O，S，SO或SO2; 其中由Y1，Y2，Y3和Y4形成的环中至少两个相邻的环原子是杂原子; 每个R 7和R 8独立地是氢，卤素，C 1 -C 8烷基或C 1 -C 8卤代烷基; 且R 5，R 6，R 7，R 8和R 9如权利要求中所定义。 本发明还涉及制备这些化合物的方法和中间体，包含这些化合物的杀虫，杀螨，杀线虫和杀软体动物的组合物，以及使用这些化合物来控制昆虫，螨虫，线虫和软体动物害虫的方法。

    INSECTICIDAL COMPOUNDS
    5.
    发明申请
    INSECTICIDAL COMPOUNDS 有权
    杀虫剂化合物

    公开(公告)号：US20140107056A1

    公开(公告)日：2014-04-17

    申请号：US14118573

    申请日：2012-05-30

    申请人： Jerome Yves Cassayre ,  Peter Renold ,  Myriem El Qacemi ,  Thomas Pitterna ,  Julie Clementine Toueg

    发明人： Jerome Yves Cassayre ,  Peter Renold ,  Myriem El Qacemi ,  Thomas Pitterna ,  Julie Clementine Toueg

    IPC分类号： A01N43/80

    CPC分类号： A01N43/80 ,  C07D261/02 ,  C07D327/02 ,  C07D411/12 ,  C07D413/12 ,  C07D413/14

    摘要： The present invention provides compounds of formula (I): wherein A1, A2, A3 and A4 are independently of one another C—H, C—R5, or nitrogen; B1—B2—B3—B4 is —CH2—C═N—CH2—, —CH2—N—CH2—CH2—, —CH2—C═CH-0- or —CH═C—CH2-0-; G1 is oxygen or sulfur; L is a single bond or C1-C8alkylene; R1 is hydrogen, C1-C8alkyl, C1-C8alkylcarbonyl-, C1-C8alkoxy, C2-C8alkenyl, C2-C8alkynyl, C1-C8alkoxy-C1-C8alkyl, aryl or aryl substituted by one to three R6, or R1 is heterocyclyl or heterocyclyl substituted by one to three R6 or C1-C8alkoxycarbonyl-; R2 is hydrogen, C1-C8haloalkyl or C1-C8alkyl; R3 is C1-C8haloalkyl; R4 is aryl or aryl substituted by one to three R6, or R4 is heterocyclyl or heterocyclyl substituted by one to three R6; Y1 is CR7R8, C═O or C═S; Y2, Y3 and Y4 are independently CR7R8, C=0, C═S, N—R9, O, S, SO or SO2; wherein at least two adjacent ring atoms in the ring formed by Y1, Y2, Y3 and Y4 are heteroatoms; each R7 and R8 is independently hydrogen, halogen, C1-C8alkyl, or C1-C8haloalkyl; and R5, R6, R7, R8 and R9 are as defined in the claims. The invention also relates to processes and intermediates for preparing these compounds, to insecticidal, acaricidal, nematicidal and molluscicidal compositions comprising these compounds and to methods of using these compounds to control insect, acarine, nematode and mollusc pests.

    摘要翻译： 本发明提供式（I）化合物：其中A1，A2，A3和A4彼此独立地为C-H，C-R5或氮; B1-B2-B3-B4是-CH2-C≡N-CH2-，-CH2-N-CH2-CH2-，-CH2-C≡CH-O-或-CH = C-CH2-O-; G1是氧或硫; L是单键或C1-C8亚烷基; R 1是氢，C 1 -C 8烷基，C 1 -C 8烷基羰基 - ，C 1 -C 8烷氧基，C 2 -C 8烯基，C 2 -C 8炔基，C 1 -C 8烷氧基-C 1 -C 8烷基，被1至3个R 6取代的芳基或芳基，或R 1是杂环基或杂环基取代 一至三个R6或C1-C8烷氧基羰基 - ; R2是氢，C1-C8卤代烷基或C1-C8烷基; R3是C1-C8卤代烷基; R4是被一至三个R6取代的芳基或芳基，或R4是被一至三个R6取代的杂环基或杂环基; Y1是CR7R8，C = O或C = S; Y2，Y3和Y4独立地为CR7R8，C = 0，C = S，N-R9，O，S，SO或SO2; 其中由Y1，Y2，Y3和Y4形成的环中至少两个相邻的环原子是杂原子; 每个R 7和R 8独立地是氢，卤素，C 1 -C 8烷基或C 1 -C 8卤代烷基; 且R 5，R 6，R 7，R 8和R 9如权利要求中所定义。 本发明还涉及制备这些化合物的方法和中间体，包含这些化合物的杀虫，杀螨，杀线虫和杀软体动物的组合物，以及使用这些化合物来控制昆虫，螨虫，线虫和软体动物害虫的方法。

    Isoxazoline derivatives as insecticidal compounds
    7.
    发明授权
    Isoxazoline derivatives as insecticidal compounds 有权
    异恶唑啉衍生物作为杀虫剂

    公开(公告)号：US09247740B2

    公开(公告)日：2016-02-02

    申请号：US14240428

    申请日：2012-08-24

    申请人： Jerome Yves Cassayre ,  Peter Renold ,  Thomas Pitterna ,  Myriem El Qacemi

    发明人： Jerome Yves Cassayre ,  Peter Renold ,  Thomas Pitterna ,  Myriem El Qacemi

    IPC分类号： C07D413/12 ,  C07D331/04 ,  A01N43/20 ,  A01N43/80 ,  A01N43/40 ,  A01N43/54

    CPC分类号： A01N43/20 ,  A01N43/40 ,  A01N43/54 ,  A01N43/80 ,  C07D331/04 ,  C07D413/12

    摘要： The present invention provides compounds of formula (I), wherein G1 is oxygen; R1 is hydrogen; R2 is group P (P) L is a bond, methylene or ethylene; one of A1 and A2 is S, SO or SO2 and the other is —C(R4)R4—R3 is hydrogen or methyl; each R4 is independently hydrogen or methyl; Y1 is C—R6, CH or nitrogen; Y2 and Y3 are independently CH or nitrogen; wherein no more than two of Y1, Y2 and Y3 are nitrogen and wherein Y2 and Y3 are not both nitrogen; R5 is hydrogen, halogen, cyano, nitro, NH2, C1-C2alkyl, C1-C2haloalkyl, C3-C5cycloalkyl, C3-C5halocycloalkyl, C1-C2alkoxy, C1-C2haloalkoxy; R6 together with R5 forms a —CH═CH—CH═CH— bridge; X2 is C—X6 or nitrogen; X1, X3 and X6 are independently hydrogen, halogen or trihalomethyl, wherein at least two of X1, X3 and X6 are not hydrogen; X4 is trifluoromethyl, difluoromethyl or chlorodifluoromethyl. The invention also provides intermediates useful for the preparation of compounds of formula (I), as well as methods of controlling insects, acarines, nematodes or molluscs using the compounds of formula (I).

    摘要翻译： 本发明提供式（I）化合物，其中G1是氧; R1是氢; R2是基团P（P）L是键，亚甲基或亚乙基; A1和A2之一是S，SO或SO2，另一个是-C（R4）R4-R3是氢或甲基; 每个R 4独立地是氢或甲基; Y1是C-R6，CH或氮; Y2和Y3独立地是CH或氮; 其中Y1，Y2和Y3中不超过两个是氮，并且其中Y 2和Y 3不都是氮; R5是氢，卤素，氰基，硝基，NH2，C1-C2烷基，C1-C2卤代烷基，C3-C5环烷基，C3-C5卤代环烷基，C1-C2烷氧基，C1-C2卤代烷氧基; R6与R5一起形成-CH = CH-CH = CH-桥; X2是C-X6或氮; X1，X3和X6独立地为氢，卤素或三卤代甲基，其中X 1，X 3和X 6中的至少两个不是氢; X4是三氟甲基，二氟甲基或氯二氟甲基。 本发明还提供了可用于制备式（I）化合物的中间体，以及使用式（I）化合物控制昆虫，螨虫，线虫或软体动物的方法。

    ISOXAZOLINE DERIVATIVES AS INSECTICIDAL COMPOUNDS
    8.
    发明申请
    ISOXAZOLINE DERIVATIVES AS INSECTICIDAL COMPOUNDS 有权
    异辛唑衍生物作为杀虫剂化合物

    公开(公告)号：US20140206606A1

    公开(公告)日：2014-07-24

    申请号：US14240428

    申请日：2012-08-24

    申请人： Jerome Yves Cassayre ,  Peter Renold ,  Thomas Pitterna ,  Myriem El Qacemi

    发明人： Jerome Yves Cassayre ,  Peter Renold ,  Thomas Pitterna ,  Myriem El Qacemi

    IPC分类号： A01N43/80 ,  A01N43/40 ,  A01N43/54 ,  A01N43/20

    CPC分类号： A01N43/20 ,  A01N43/40 ,  A01N43/54 ,  A01N43/80 ,  C07D331/04 ,  C07D413/12

    摘要： The present invention provides compounds of formula (I), wherein G1 is oxygen; R1 is hydrogen; R2 is group P (P) L is a bond, methylene or ethylene; one of A1 and A2 is S, SO or SO2 and the other is —C(R4)R4—R3 is hydrogen or methyl; each R4 is independently hydrogen or methyl; Y1 is C—R6, CH or nitrogen; Y2 and Y3 are independently CH or nitrogen; wherein no more than two of Y1, Y2 and Y3 are nitrogen and wherein Y2 and Y3 are not both nitrogen; R5 is hydrogen, halogen, cyano, nitro, NH2, C1-C2alkyl, C1-C2haloalkyl, C3-C5cycloalkyl, C3-C5halocycloalkyl, C1-C2alkoxy, C1-C2haloalkoxy; R6 together with R5 forms a —CH═CH—CH═CH— bridge; X2 is C—X6 or nitrogen; X1, X3 and X6 are independently hydrogen, halogen or trihalomethyl, wherein at least two of X1, X3 and X6 are not hydrogen; X4 is trifluoromethyl, difluoromethyl or chlorodifluoromethyl. The invention also provides intermediates useful for the preparation of compounds of formula (I), as well as methods of controlling insects, acarines, nematodes or molluscs using the compounds of formula (I).

    摘要翻译： 本发明提供式（I）化合物，其中G1是氧; R1是氢; R2是基团P（P）L是键，亚甲基或亚乙基; A1和A2之一是S，SO或SO2，另一个是-C（R4）R4-R3是氢或甲基; 每个R 4独立地是氢或甲基; Y1是C-R6，CH或氮; Y2和Y3独立地是CH或氮; 其中Y1，Y2和Y3中不超过两个是氮，并且其中Y 2和Y 3不都是氮; R5是氢，卤素，氰基，硝基，NH2，C1-C2烷基，C1-C2卤代烷基，C3-C5环烷基，C3-C5卤代环烷基，C1-C2烷氧基，C1-C2卤代烷氧基; R6与R5一起形成-CH = CH-CH = CH-桥; X2是C-X6或氮; X1，X3和X6独立地为氢，卤素或三卤代甲基，其中X 1，X 3和X 6中的至少两个不是氢; X4是三氟甲基，二氟甲基或氯二氟甲基。 本发明还提供了可用于制备式（I）化合物的中间体，以及使用式（I）化合物控制昆虫，螨虫，线虫或软体动物的方法。