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    POLYMERIZING AND ANCHORING A WATER-SOLUBLE POLYMER TO AN IN-PLACE MINERAL SURFACE OF A WELL
    1.
    发明申请
    POLYMERIZING AND ANCHORING A WATER-SOLUBLE POLYMER TO AN IN-PLACE MINERAL SURFACE OF A WELL 有权
    将水溶性聚合物聚合并固定在一个良好的矿物矿物表面

    公开(公告)号：US20120012320A1

    公开(公告)日：2012-01-19

    申请号：US12835579

    申请日：2010-07-13

    申请人： Jimmie D. Weaver ,  Larry S. Eoff

    发明人： Jimmie D. Weaver ,  Larry S. Eoff

    IPC分类号： E21B43/16

    CPC分类号： C09K8/80 ,  C09K8/508

    摘要： Methods are provided using an anchoring agent for a water-soluble polymer that is in-place polymerized in a subterranean formation. The anchoring agent comprises a hydrolyzable silyl group that reacts with one or more dangling hydroxyl groups of a mineral surface in the subterranean formation to form “hard” bonds, “anchoring” to the mineral surface. The anchoring agent is selected to have another functional group for covalent attachment to the water-soluble polymer. This can help a water-soluble polymer be anchored to a mineral surface in a subterranean formation. Accordingly, it is believed that monomolecular layers of water-soluble polymer will be formed and anchored to the mineral surface, which will provide excellent elastic properties to the matrix. The monomolecular layers are not expected to interfere with the permeability of the matrix.

    摘要翻译： 使用在地层中原位聚合的水溶性聚合物的锚固剂提供方法。 锚固剂包括与地下地层中的矿物表面的一个或多个悬挂的羟基反应的可水解甲硅烷基，以形成“固定”到矿物表面的“硬”键。 选择锚定剂具有用于与水溶性聚合物共价连接的另一官能团。 这可以帮助水溶性聚合物锚定在地层中的矿物表面。 因此，认为水溶性聚合物的单分子层将形成并锚定到矿物表面，这将为基质提供优异的弹性。 预计单分子层不会干扰基质的渗透性。

    Methods of consolidating formations or forming chemical casing or both while drilling
    6.
    发明授权
    Methods of consolidating formations or forming chemical casing or both while drilling 失效
    在钻孔时整合地层或形成化学套管或两者的方法

    公开(公告)号：US06702044B2

    公开(公告)日：2004-03-09

    申请号：US10170400

    申请日：2002-06-13

    申请人： B. Raghava Reddy ,  Larry S. Eoff ,  Donald L. Whitfill ,  J. Michael Wilson ,  Denise Berryhill ,  Russel M. Fitzgerald ,  Thomas E. Becker ,  Jimmie D. Weaver

    发明人： B. Raghava Reddy ,  Larry S. Eoff ,  Donald L. Whitfill ,  J. Michael Wilson ,  Denise Berryhill ,  Russel M. Fitzgerald ,  Thomas E. Becker ,  Jimmie D. Weaver

    IPC分类号： E21B2100

    CPC分类号： C09K8/12 ,  C09K8/24 ,  C09K8/508 ,  C09K8/512 ,  C09K8/5751 ,  Y10S507/903

    摘要： Methods of consolidating formations or forming chemical casing or both while drilling are provided. One method of the invention comprises drilling a well bore with a drilling fluid comprised of water, a polymeric cationic catalyst which is adsorbed on weak zones or formations formed of unconsolidated clays, shale, sand stone and the like, a water soluble or dispersible polymer which is cross-linked by a thermoset resin and causes the resin to be hard and tough when cured, a particulate curable solid thermoset resin, a water soluble thermoset resin, and a delayed dispersible acid catalyst for curing the solid and water soluble resins. The drilling fluid forms a filter cake on the walls of the well bore that cures and consolidates the unconsolidated weak zones and formations penetrated by the well bore so that sloughing is prevented and forms a hard and tough cross-linked chemical casing on the walls of the well bore.

    摘要翻译： 提供了在钻孔时固结地层或形成化学套管或两者的方法。 本发明的一种方法包括用包括水的钻井液钻井井，吸附在由非固结粘土，页岩，砂石等形成的弱区或地层上的聚合阳离子催化剂，水溶性或分散性聚合物， 通过热固性树脂交联并使树脂在固化时硬而坚韧，颗粒固化固体热固性树脂，水溶性热固性树脂和用于固化和水溶性树脂的延迟分散酸催化剂。 钻井液在井眼的壁上形成滤饼，其固化和固结由井眼穿透的未固结的弱区和结构，从而防止脱落并形成硬的和坚韧的交联化学壳体 井眼。

    Polymerizing and anchoring a water-soluble polymer to an in-place mineral surface of a well
    8.
    发明授权
    Polymerizing and anchoring a water-soluble polymer to an in-place mineral surface of a well 有权
    将水溶性聚合物聚合并固定在孔的原位矿物表面

    公开(公告)号：US08950488B2

    公开(公告)日：2015-02-10

    申请号：US12835579

    申请日：2010-07-13

    申请人： Jimmie D. Weaver ,  Larry S. Eoff

    发明人： Jimmie D. Weaver ,  Larry S. Eoff

    IPC分类号： E21B43/25 ,  C09K8/82 ,  C09K8/80 ,  C09K8/508

    CPC分类号： C09K8/80 ,  C09K8/508

    摘要： Methods using an anchoring agent for a water-soluble polymer that is in-place polymerized in a subterranean formation. The anchoring agent comprises a hydrolyzable silyl group that reacts with one or more dangling hydroxyl groups of a mineral surface in the subterranean formation to form “hard” bonds, “anchoring” to the mineral surface. The anchoring agent is selected to have another functional group for covalent attachment to the water-soluble polymer. This can help a water-soluble polymer be anchored to a mineral surface in a subterranean formation. Accordingly, it is believed that monomolecular layers of water-soluble polymer will be formed and anchored to the mineral surface, which will provide excellent elastic properties to the matrix. The monomolecular layers are not expected to interfere with the permeability of the matrix.

    摘要翻译： 用于在地下地层聚合的水溶性聚合物的锚固剂的方法。 锚固剂包括与地下地层中的矿物表面的一个或多个悬挂的羟基反应的可水解甲硅烷基，以形成“固定”到矿物表面的“硬”键。 选择锚定剂具有用于与水溶性聚合物共价连接的另一官能团。 这可以帮助水溶性聚合物锚定在地层中的矿物表面。 因此，认为水溶性聚合物的单分子层将形成并锚定到矿物表面，这将为基质提供优异的弹性。 预计单分子层不会干扰基质的渗透性。