公开(公告)号：US20090101522A1

公开(公告)日：2009-04-23

申请号：US12128954

申请日：2008-05-29

Applicant: Jing Xu ,  Xingbo Liu ,  Yinglu Jiang ,  Frank Goodwin

Inventor： Jing Xu ,  Xingbo Liu ,  Yinglu Jiang ,  Frank Goodwin

IPC: G01N27/26 ,  G01N27/28

CPC classification number: G01N27/411

Abstract: A system and method for the high temperature in-situ determination of corrosion characteristics of a molten metal on an alloy under study is provided which takes place within an insulated furnace. A graphite crucible provided in the furnace contains an electrolyte formed from a molten salt of a metal halide. A reference electrode formed from the same metal as the electrolyte is immersed in the electrolyte solution in the graphite crucible. A beta-alumina crucible containing a molten metal is also provided within the furnace and preferably within the graphite crucible. A measuring electrode formed from the alloy under study is immersed in the molten metal. Standard electrochemical techniques are used to measure and analyze the electrochemical effects of corrosion of the molten metal on the alloy.

Abstract translation: 提供了一种在绝缘炉内进行高温原位测定熔融金属在正在研究的合金上的腐蚀特性的系统和方法。 设置在炉中的石墨坩埚含有由金属卤化物的熔融盐形成的电解质。 由与电解质相同的金属形成的参比电极浸入石墨坩埚中的电解液中。 在炉内还优选在石墨坩埚内设置含有熔融金属的β-氧化铝坩埚。 将由研究的合金形成的测量电极浸入熔融金属中。 使用标准电化学技术来测量和分析熔融金属对合金的腐蚀的电化学效应。

公开(公告)号：US08173007B2

公开(公告)日：2012-05-08

申请号：US12128954

申请日：2008-05-29

Applicant: Jing Xu ,  Xingbo Liu ,  Yinglu Jiang ,  Frank Goodwin

Inventor： Jing Xu ,  Xingbo Liu ,  Yinglu Jiang ,  Frank Goodwin

IPC: G01N17/02 ,  G01N27/06

CPC classification number: G01N27/411

Abstract: A system and method for the high temperature in-situ determination of corrosion characteristics of a molten metal on an alloy under study is provided which takes place within an insulated furnace. A graphite crucible provided in the furnace contains an electrolyte formed from a molten salt of a metal halide. A reference electrode formed from the same metal as the electrolyte is immersed in the electrolyte solution in the graphite crucible. A beta-alumina crucible containing a molten metal is also provided within the furnace and preferably within the graphite crucible. A measuring electrode formed from the alloy under study is immersed in the molten metal. Standard electrochemical techniques are used to measure and analyze the electrochemical effects of corrosion of the molten metal on the alloy.

Abstract translation: 提供了一种在绝缘炉内进行高温原位测定熔融金属在正在研究的合金上的腐蚀特性的系统和方法。 设置在炉中的石墨坩埚含有由金属卤化物的熔融盐形成的电解质。 由与电解质相同的金属形成的参比电极浸入石墨坩埚中的电解液中。 在炉内还优选在石墨坩埚内提供含有熔融金属的β-氧化铝坩埚。 将由研究的合金形成的测量电极浸入熔融金属中。 使用标准电化学技术来测量和分析熔融金属对合金的腐蚀的电化学效应。

公开(公告)号：US08865354B2

公开(公告)日：2014-10-21

申请号：US13074335

申请日：2011-03-29

Applicant: Hui Zhang ,  Yinglu Jiang ,  Xingbo Liu

Inventor： Hui Zhang ,  Yinglu Jiang ,  Xingbo Liu

IPC: H01M10/0562

CPC classification number: H01M10/0562 ,  H01M10/0525 ,  H01M2300/0068 ,  H01M2300/0071 ,  Y02E60/12

Abstract: An inorganic solid electrolyte glass phase composite is provided comprising a substance of the general formula La2/3-xLi3xTiO3 wherein x ranges from about 0.04 to about 0.17, and a glass material. The glass material is one or more compounds selected from Li2O, Li2S, Li2SO4, Li3PO4, B2O3, P2O5, P2O3, Al2O3, SiO2, CaO, MgO, BaO, TiO2, GeO2, SiS2, Sb2O3, SnS, TaS2, P2S5, B2S3, and a combination of two or more thereof. A lithium-ion conducting solid electrolyte composite is disclosed comprising a lithium-ion conductive substance of the general formula La2/3-xLi3xTiO3—Z wherein x ranges form about 0.04 to 0.17, and wherein “Z” is the glass material identified above. A battery is disclosed having at least one cathode and anode and an inorganic solid electrolyte glass phase composite as described above disposed on or between at least one of the cathode and the anode.

Abstract translation: 提供了一种无机固体电解质玻璃相复合材料，其包含通式La2 / 3-xLi3xTiO3的物质，其中x为约0.04至约0.17的范围，以及玻璃材料。 玻璃材料是选自Li 2 O，Li 2 S，Li 2 SO 4，Li 3 PO 4，B 2 O 3，P 2 O 5，P 2 O 3，Al 2 O 3，SiO 2，CaO，MgO，BaO，TiO 2，GeO 2，SiS 2，Sb 2 O 3，SnS，TaS 2，P 2 S 5， 以及其两个以上的组合。 公开了一种锂离子传导性固体电解质复合体，其包含通式为La2 / 3-xLi3xTiO3-Z的锂离子导电物质，其中x范围形成约0.04至0.17，并且其中“Z”是上述玻璃材料。 公开了具有如上所述的至少一个阴极和阳极以及设置在阴极和阳极中的至少一个之间或之中的无机固体电解质玻璃相复合材料的电池。

公开(公告)号：US20110318650A1

公开(公告)日：2011-12-29

申请号：US13074335

申请日：2011-03-29

Applicant: Hui Zhang ,  Yinglu Jiang ,  Xingbo Liu

Inventor： Hui Zhang ,  Yinglu Jiang ,  Xingbo Liu

IPC: H01M10/0562 ,  H01G9/032

CPC classification number: H01M10/0562 ,  H01M10/0525 ,  H01M2300/0068 ,  H01M2300/0071 ,  Y02E60/12

Abstract: An inorganic solid electrolyte glass phase composite is provided comprising a substance of the general formula La2/3-xLi3xTiO3 wherein x ranges from about 0.04 to about 0.17, and a glass material. The glass material is one or more compounds selected from Li2O, Li2S, Li2SO4, Li3PO4, B2O3, P2O5, P2O3, Al2O3, SiO2, CaO, MgO, BaO, TiO2, GeO2, SiS2, Sb2O3, SnS, TaS2, P2S5, B2S3, and a combination of two or more thereof. A lithium-ion conducting solid electrolyte composite is disclosed comprising a lithium-ion conductive substance of the general formula La2/3-xLi3xTiO3—Z wherein x ranges form about 0.04 to 0.17, and wherein “Z” is the glass material identified above. A battery is disclosed having at least one cathode and anode and an inorganic solid electrolyte glass phase composite as described above disposed on or between at least one of the cathode and the anode.

Abstract translation: 提供了一种无机固体电解质玻璃相复合材料，其包含通式La2 / 3-xLi3xTiO3的物质，其中x为约0.04至约0.17的范围，以及玻璃材料。 玻璃材料是选自Li 2 O，Li 2 S，Li 2 SO 4，Li 3 PO 4，B 2 O 3，P 2 O 5，P 2 O 3，Al 2 O 3，SiO 2，CaO，MgO，BaO，TiO 2，GeO 2，SiS 2，Sb 2 O 3，SnS，TaS 2，P 2 S 5， 以及其两个以上的组合。 公开了一种锂离子传导性固体电解质复合体，其包含通式为La2 / 3-xLi3xTiO3-Z的锂离子导电物质，其中x范围形成约0.04至0.17，并且其中“Z”是上述的玻璃材料。 公开了具有如上所述的至少一个阴极和阳极以及设置在阴极和阳极中的至少一个之间或之中的无机固体电解质玻璃相复合材料的电池。