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公开(公告)号：US20090131630A1
公开(公告)日：2009-05-21
申请号：US11884081
申请日：2006-02-10
申请人： Johannes Adrianus Maria Van Broekhoven , Eit Drent , Rene Ernst , Willem Wabe Jager , Cornelia Alida Krom
发明人： Johannes Adrianus Maria Van Broekhoven , Eit Drent , Rene Ernst , Willem Wabe Jager , Cornelia Alida Krom
摘要： A process for the preparation of a dicarboxylic acid, comprising the steps of (a) contacting a conjugated diene with carbon monoxide and water in the presence of a catalyst system including a source of palladium, a source of an anion and a bidentate phosphine ligand, to obtain a mixture containing an ethylenically unsaturated acid and one or more reversible adduct of the conjugated diene and the ethylenically unsaturated acid; and (b) removing unreacted conjugated diene, and the reversible adducts of the conjugated diene from the reaction mixture; and (c) reacting the mixture obtained in step (b) containing the ethylenically unsaturated acid further with carbon monoxide and water to obtain the dicarboxylic acid.
摘要翻译： 一种制备二羧酸的方法，包括以下步骤：（a）在包括钯源，阴离子源和二齿膦配体的催化剂体系的存在下，使共轭二烯与一氧化碳和水接触， 以获得含有烯属不饱和酸和共轭二烯和烯键式不饱和酸的一种或多种可逆加合物的混合物; 和（b）从反应混合物中除去未反应的共轭二烯和共轭二烯的可逆加合物; 和（c）使含有烯属不饱和酸的步骤（b）中获得的混合物与一氧化碳和水进一步反应，得到二羧酸。
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公开(公告)号：US20080269459A1
公开(公告)日：2008-10-30
申请号：US11884113
申请日：2006-02-10
申请人： Eit Drent , Rene Ernst , Willem Wabe Jager , Cornelia Alida Krom
发明人： Eit Drent , Rene Ernst , Willem Wabe Jager , Cornelia Alida Krom
CPC分类号： C07C51/14 , B01J31/24 , B01J2531/824 , C07C57/03 , C07C55/14
摘要： A process for the preparation of a saturated dicarboxylic acid, comprising the steps of (a) contacting a conjugated diene with carbon monoxide and water to obtain a mixture containing an ethylenically unsaturated acid product and one or more reversible adducts of the conjugated diene and the ethylenically unsaturated acid; and (b) reacting the ethylenically unsaturated acid product further with carbon monoxide and water to obtain the dicarboxylic acid, wherein step (a) and (b) are performed in the presence of a catalyst system including a source of palladium, a source of an anion and a bidentate phosphine ligand, and wherein in step (a) the water concentration is maintained at a range of from 0.001 to less than 3% by weight of water, calculated on the overall weight of the liquid reaction medium, and wherein in step (b) the water concentration is maintained at a range of from 3% to 50% by weight of water, calculated on the overall weight of the liquid reaction medium.
摘要翻译： 一种制备饱和二羧酸的方法，包括以下步骤：（a）使共轭二烯与一氧化碳和水接触，以获得含有烯属不饱和酸产物和一种或多种可共轭二烯的可逆加合物和烯键式 不饱和酸 和（b）使烯属不饱和酸产物进一步与一氧化碳和水反应以获得二羧酸，其中步骤（a）和（b）在催化剂体系存在下进行，所述催化剂体系包括钯源， 阴离子和二齿膦配体，并且其中在步骤（a）中，水浓度保持在0.001至小于3重量％的水的范围内，以液体反应介质的总重计算，并且其中在步骤 （b）根据液体反应介质的总重量，水浓度保持在3重量％至50重量％的水的范围内。
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公开(公告)号：US20080269433A1
公开(公告)日：2008-10-30
申请号：US11884107
申请日：2006-02-10
IPC分类号： C08F2/60
摘要： A process for the carbonylation of a conjugated diene to an ethylenically unsaturated acid, comprising the steps of (a) contacting a conjugated diene with carbon monoxide and water in the presence of a catalyst system including a source of palladium, a source of an anion and a bidentate phosphine ligand, to obtain a mixture comprising an ethylenically unsaturated acid and a reversible diene adduct comprising alkenyl ester of the conjugated diene with the ethylenically unsaturated acid; (b) separating the obtained reaction mixture into a gaseous stream comprising unreacted conjugated diene and carbon monoxide, a first liquid product stream comprising at least part of the ethylenically unsaturated acid and the reversible diene adducts, and a second liquid stream comprising the catalyst system in admixture with the ethylenically unsaturated acid; (c) separating the first liquid product stream obtained in step (b) into a stream comprising the ethylenically unsaturated acid and a stream comprising the reversible diene adducts; and (d) recycling the stream comprising the reversible diene adducts to step (a), or converting the reversible diene adducts back to the conjugated diene and the ethylenically unsaturated acid and recycling the thus obtained conjugated diene to step (a).
摘要翻译： 一种将共轭二烯羰基化成烯属不饱和酸的方法，包括以下步骤：（a）在包括钯源，阴离子源和/或其盐的催化剂体系存在下使共轭二烯与一氧化碳和水接触， 二次膦配体，以获得包含烯键式不饱和酸和包含共轭二烯烯基酯与烯键式不饱和酸的可逆二烯加合物的混合物; （b）将获得的反应混合物分离成包含未反应的共轭二烯和一氧化碳的气流，包含至少部分烯键式不饱和酸和可逆二烯加合物的第一液体产物流和包含催化剂体系的第二液体流 与烯属不饱和酸的混合物; （c）将步骤（b）中获得的第一液体产物流分离成包含烯属不饱和酸的物流和包含可逆二烯加成物的物流; 和（d）将包含可逆二烯加合物的料流再循环到步骤（a）中，或将可逆二烯加合物转化回共轭二烯和烯属不饱和酸，并将由此得到的共轭二烯再循环到步骤（a）。
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4.发明申请公开(公告)号：US20080269520A1
公开(公告)日：2008-10-30
申请号：US11884103
申请日：2006-02-10
IPC分类号： C07C51/14
摘要： A process for the carbonylation of a conjugated diene to a dicarboxylic acid, comprising the steps of (a) contacting a conjugated diene with carbon monoxide and water in the presence of a catalyst system including a source of palladium, a source of an anion and a bidentate phosphine ligand, to obtain a mixture comprising an ethylenically unsaturated acid and reversible diene adducts; (b) separating the obtained reaction mixture into a gaseous stream comprising unreacted conjugated diene and carbon monoxide, a first normally liquid stream comprising at least part of the ethylenically unsaturated acid and the reversible diene adducts, and a second normally liquid stream comprising the catalyst system in admixture with the ethylenically unsaturated acid; (c) recycling the second liquid stream obtained in step (b) to step (a); (d) separating the first liquid product stream obtained in step (b) into a stream comprising the ethylenically unsaturated acid and a stream comprising the reversible diene adducts; and (e) contacting the stream comprising the ethylenically unsaturated acid obtained in step (d) with carbon monoxide and water in the presence of a second catalyst system including a source of palladium, a source of an anion and a bidentate phosphine ligand.
摘要翻译： 一种将共轭二烯羰基化成二羧酸的方法，包括以下步骤：（a）在包括钯源，阴离子源和阴离子的催化剂体系的存在下使共轭二烯与一氧化碳和水接触 二次膦配体，以获得包含烯属不饱和酸和可逆二烯加成物的混合物; （b）将获得的反应混合物分离成包含未反应的共轭二烯和一氧化碳的气流，包含至少部分烯属不饱和酸和可逆二烯加合物的第一常规液体流，以及包含催化剂体系的第二常规液流 与烯属不饱和酸的混合物; （c）将步骤（b）中获得的第二液体流循环到步骤（a）; （d）将步骤（b）中获得的第一液体产物流分离成包含烯属不饱和酸的物流和包含可逆二烯加成物的物流; 和（e）在包含钯源，阴离子源和二齿膦配体的第二催化剂体系的存在下，将包含步骤（d）中获得的烯属不饱和酸的物流与一氧化碳和水接触。
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公开(公告)号：US20080194870A1
公开(公告)日：2008-08-14
申请号：US11884079
申请日：2006-02-10
申请人： Eit Drent , Rene Ernst , Willem Wade Jager , Cornelia Alida Krom
发明人： Eit Drent , Rene Ernst , Willem Wade Jager , Cornelia Alida Krom
IPC分类号： C07C51/14
CPC分类号： C08G69/28 , C07C51/14 , C07C51/43 , Y02P20/584 , C07C55/14
摘要： A process for the preparation of a dicarboxylic acid, comprising the steps of (a) contacting a conjugated diene with carbon monoxide and water in the presence of a catalyst system including a source of palladium, a source of an anion and a bidentate phosphine ligand, to obtain a mixture comprising an ethylenically unsaturated acid product; (b) reacting the mixture obtained in step (a) further with carbon monoxide and water to obtain the dicarboxylic acid in admixture with the ethylenically unsaturated acid; (c) separating the dicarboxylic acid from a liquid filtrate comprising the catalyst system; and (d) recycling at least part of the obtained liquid filtrate to step (a).
摘要翻译： 一种制备二羧酸的方法，包括以下步骤：（a）在包括钯源，阴离子源和二齿膦配体的催化剂体系的存在下，使共轭二烯与一氧化碳和水接触， 以获得包含烯属不饱和酸产物的混合物; （b）使步骤（a）中得到的混合物进一步与一氧化碳和水反应，得到与烯属不饱和酸混合的二羧酸; （c）从包含催化剂体系的液体滤液中分离二羧酸; 和（d）将至少部分获得的液体滤液再循环到步骤（a）。
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公开(公告)号：US20060235241A1
公开(公告)日：2006-10-19
申请号：US10557309
申请日：2004-05-13
申请人： Eit Drent , Rene Ernst , Willem Wabe Jager
发明人： Eit Drent , Rene Ernst , Willem Wabe Jager
CPC分类号： B01J31/04 , B01J31/24 , B01J2231/321 , B01J2531/824 , C07C67/38 , C07C231/12 , C07F9/5027 , C07F9/657163 , C07C69/24 , C07C233/09
摘要： A process for the carbonylation of a conjugated diene, which involves reacting the conjugated diene with carbon monoxide and a co-reactant having a mobile hydrogen atom in the presence of a catalyst system including: (a) a source of palladium; and (b) a bidentate diphosphine ligand of formula II, R1R2>P1—R3m—R—R4n—P2
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7.发明授权
公开(公告)号：US5670440A
公开(公告)日：1997-09-23
申请号：US731906
申请日：1996-10-22
申请人： Simona Bronco , Giambattista Consiglio , Silvia Di Benedetto , Eit Drent , Hero Jan Heeres , Johannes Adrianus Maria Van Broekhoven , Marinus Johannes Reynhout
发明人： Simona Bronco , Giambattista Consiglio , Silvia Di Benedetto , Eit Drent , Hero Jan Heeres , Johannes Adrianus Maria Van Broekhoven , Marinus Johannes Reynhout
CPC分类号： B01J31/2295 , B01J31/24 , B01J31/2409 , C08G67/02 , B01J2231/10 , B01J2531/0205 , B01J2531/824 , B01J2531/842
摘要： A catalyst composition comprising a) a palladium compound, b) an anion, and c) an asymmetric phosphorus bidentate ligand of the general formula R.sup.5 R.sup.6 P-Q-CHR.sup.9 -PR+7R.sup.8, wherein Q is a 1,2-ferrocenyl bridging group, R.sup.5, R.sup.6, R.sup.7 and R.sup.8 are identical or different optionally polar substituted hydrocarbyl groups and R.sup.9 is hydrogen or an optionally polar substituted hydrocarbyl group; a process for the preparation of linear alternating copolymers of carbon monoxide with an aliphatic -olefin having at least 3 and at most 10 carbon atoms, which process comprises contacting a mixture of the monomers with a said catalyst composition; and a linear alternating copolymer of carbon monoxide with an aliphatic -olefin having at least 3 and at most 10 carbon atoms which copolymer has an isotacticity of 95% or more.
摘要翻译： 一种催化剂组合物，其包含a）钯化合物，b）阴离子，和c）通式为R 5 R 6 P-Q-CHR 9 -PR + 7 R 8的不对称磷二齿配位体，其中Q为1,2-二茂铁基桥接基团，R 5 R 6，R 7和R 8是相同或不同的任选极性取代的烃基，R 9是氢或任选的极性取代的烃基; 一种制备一氧化碳与具有至少3个和至多10个碳原子的脂族α-烯烃的线性交替共聚物的方法，该方法包括使单体与所述催化剂组合物的混合物接触; 和一氧化碳与具有至少3个且至多10个碳原子的脂肪族α-烯烃的直链交替共聚物，共聚物的全同立构规整度为95％以上。
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公开(公告)号：US07858787B2
公开(公告)日：2010-12-28
申请号：US11857011
申请日：2007-09-18
申请人： Eit Drent , Roelof Van Ginkel , Willem Wabe Jager
发明人： Eit Drent , Roelof Van Ginkel , Willem Wabe Jager
IPC分类号： C07F9/02 , C07C233/00 , C07C45/00 , C07C5/00
CPC分类号： C07F9/65683 , B01J31/2419 , B01J2231/321 , B01J2531/845 , C07C1/24 , C07C29/16 , C07C11/02 , C07C31/125
摘要： A process for converting an olefin having x carbon atoms into an olefin having x+1 carbon atoms wherein the process comprises the steps of: (i) reacting an olefin having x carbon atoms with carbon monoxide and hydrogen in the presence of a hydroformylation catalyst to produce an alcohol having x+1 carbon atoms, and (ii) dehydrating the alcohol produced in step (i) in the presence of a dehydration catalyst to produce an olefin having x+1 carbon atoms characterized in that the hydroformylation catalyst used in step (i) is based on: (a) a source of cobalt, and (b) a ligand which contains phosphorus and nitrogen.
摘要翻译： 将具有x个碳原子的烯烃转化为具有x + 1个碳原子的烯烃的方法，其中所述方法包括以下步骤：（i）在加氢甲酰化催化剂存在下使具有x个碳原子的烯烃与一氧化碳和氢气反应， 产生具有x + 1个碳原子的醇，和（ii）在脱水催化剂存在下使步骤（ⅰ）中产生的醇脱水以产生具有x + 1个碳原子的烯烃，其特征在于步骤（a）中使用的加氢甲酰化催化剂 i）基于：（a）钴源，和（b）含有磷和氮的配体。
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公开(公告)号：US5908958A
公开(公告)日：1999-06-01
申请号：US824858
申请日：1997-03-26
申请人： Eit Drent , Willem Wabe Jager
发明人： Eit Drent , Willem Wabe Jager
CPC分类号： C07C67/38
摘要： The invention relates to a process for the carbonylation of acetylenically unsaturated compounds, whereby a feedstock comprising an acetylenically unsaturated compound and a relatively minor amount of an 1,2-alkadiene compound is contacted under carbonylation conditions with carbon monoxide and a co-reactant, in the presence of a catalyst system, based on: a) a source of cations of one or more metals of Group VIII of the Periodic Table; b) a phosphine having an aromatic substituent which contains an imino nitrogen atom separated by at least one bridging carbon atom from the phosphorus atom, and c) a protic acid, characterized in that the catalyst system is further based on d) a monodentate monophosphine or monophosphite.
摘要翻译： 本发明涉及一种炔属不饱和化合物的羰基化方法，其中包含炔属不饱和化合物和相对少量的1,2-二烯化合物的原料在羰基化条件下与一氧化碳和共反应物接触， 催化剂体系的存在，基于：a）周期表第VIII族的一种或多种金属的阳离子源; b）具有芳族取代基的膦，其含有由磷原子至少一个桥连碳原子分离的亚氨基氮原子，和c）质子酸，其特征在于催化剂体系还基于d）单齿单膦或 单亚磷酸酯
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公开(公告)号：US06835850B2
公开(公告)日：2004-12-28
申请号：US10381040
申请日：2003-08-25
申请人： Eit Drent , Willem Wabe Jager , Otto Erik Sielcken , Imre Toth
发明人： Eit Drent , Willem Wabe Jager , Otto Erik Sielcken , Imre Toth
IPC分类号： C07C6736
CPC分类号： B01J31/04 , B01J31/2428 , B01J31/248 , B01J2231/321 , B01J2531/824 , C07C67/38 , C07C69/533
摘要： Process for the carbonylation of a conjugated diene by reacting the conjugated diene with carbon monoxide and an hydroxyl group containing compound in the presence of a catalyst system based on: (a) a source of palladium cations, (b) a diphosphine ligand, and (c) a source of anions, wherein the diphosphine ligand is a ligand having the general formula I wherein x1 and x2 represent a cyclic group with at least 5 ring atoms, of which one is a phosphorus atom, and R represents a bivalent aliphatic bridging group, connecting both phosphorus atoms, containing from 2 to 4 atoms in the bridge, which is substituted with at least one substituent or R represents a phenyl group with both phosphorus groups bound to the 1,2-position.
摘要翻译： 通过在催化剂体系的存在下使共轭二烯与一氧化碳和含羟基的化合物反应来共轭二烯羰基化的方法，其基于：（a）钯阳离子源，（b）二膦配体和（ c）阴离子源，其中二膦配体是具有通式I的配体，其中x 1和x 2表示具有至少5个环原子的环状基团，其中一个是磷原子，R 代表二价脂肪族桥连基团，其连接两个在原子团中含有2至4个原子的磷原子，该原子被至少一个取代基取代，或R表示两个磷键与1,2-位相结合的苯基。
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