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    High contrast photographic element containing a novel nucleator
    1.
    发明授权
    High contrast photographic element containing a novel nucleator 失效
    含有新型成核剂的高对比度照相元件

    公开(公告)号：US06228566B1

    公开(公告)日：2001-05-08

    申请号：US09618357

    申请日：2000-07-18

    申请人： John D. Goddard ,  Philip J. Coldrick ,  Rebecca Glen ,  Dawn J. Jenkins

    发明人： John D. Goddard ,  Philip J. Coldrick ,  Rebecca Glen ,  Dawn J. Jenkins

    IPC分类号： G03C529

    CPC分类号： G03C1/061 ,  G03C2001/108

    摘要： The invention relates to an ultrahigh contrast photographic material comprising a support bearing a silver halide emulsion layer, containing a hydrazide nucleating agent in the emulsion layer or a hydrophilic colloid layer, characterized in that the nucleating agent is a dimeric molecule comprising two monomers linked by a linking group, each monomer of which (a) may be the same or different and (b) comprises an acylhydrazide moiety and a nicotinamide moiety in combination, the material providing unexpectedly good nucleation in the absence of, or with reduced amounts of, booster and in a developer whose pH is variable, and further with lower chemical spread and pepper fog.

    摘要翻译： 本发明涉及一种超高对比度照相材料，其包括载体，该载体含有在乳剂层中的酰肼成核剂或亲水胶体层的卤化银乳剂层，其特征在于，所述成核剂是包含两个单体的二聚体分子 连接基团，其中每个单体（a）可以相同或不同，并且（b）组合包含酰肼部分和烟酰胺部分，该材料在不存在或具有减少量的助催化剂和减少的量的情况下提供意想不到的良好成核 在pH可变的显影剂中，进一步具有较低的化学传播和胡椒雾。

    High contrast photographic element containing a novel nucleator
    2.
    发明授权
    High contrast photographic element containing a novel nucleator 失效
    含有新型成核剂的高对比度照相元件

    公开(公告)号：US6143462A

    公开(公告)日：2000-11-07

    申请号：US444777

    申请日：1999-11-22

    申请人： John D. Goddard ,  Philip J. Coldrick ,  Rebecca Glen ,  Dawn J. Jenkins

    发明人： John D. Goddard ,  Philip J. Coldrick ,  Rebecca Glen ,  Dawn J. Jenkins

    IPC分类号： G03C1/06 ,  G03C1/08

    CPC分类号： G03C1/061

    摘要： The invention relates to an ultrahigh contrast photographic material comprising a support bearing a silver halide emulsion layer, containing a hydrazide nucleating agent in the emulsion layer or a hydrophilic colloid layer, characterised in that the nucleating agent is a dimeric molecule comprising two monomers linked by a linking group, each monomer of which (a) may be the same or different and (b) comprises an acylhydrazide moiety and a nicotinamide moiety in combination, the material providing unexpectedly good nucleation in the absence of, or with reduced amounts of, booster and in a developer whose pH is variable, and further with lower chemical spread and pepper fog.

    摘要翻译： 本发明涉及一种超高对比度照相材料，其包括载体，该载体含有在乳剂层中的酰肼成核剂或亲水胶体层的卤化银乳剂层，其特征在于，所述成核剂是包含两个单体的二聚体分子 连接基团，其中每个单体（a）可以相同或不同，并且（b）组合包含酰肼部分和烟酰胺部分，该材料在不存在或具有减少量的助催化剂和减少的量的情况下提供意想不到的良好成核 在pH可变的显影剂中，进一步具有较低的化学传播和胡椒雾。

    High contrast photographic element containing a novel nucleator
    3.
    发明授权
    High contrast photographic element containing a novel nucleator 失效
    含有新型成核剂的高对比度照相元件

    公开(公告)号：US06245480B1

    公开(公告)日：2001-06-12

    申请号：US09591774

    申请日：2000-06-12

    申请人： Judith A. Bogie ,  Philip J. Coldrick ,  John D. Goddard ,  Llewellyn J. Leyshon

    发明人： Judith A. Bogie ,  Philip J. Coldrick ,  John D. Goddard ,  Llewellyn J. Leyshon

    IPC分类号： G03C108

    CPC分类号： G03C1/061 ,  G03C2001/108

    摘要： The invention relates to an ultrahigh contrast photographic material comprising a support bearing a silver halide emulsion layer, containing a hydrazide nucleating agent in the emulsion layer or a hydrophilic colloid layer, characterised in that the nucleating agent of formula (I) comprises (a) two nicotinamide moieties, which may be the same or different, which are linked by a linking group, and (b) a hydrazide moiety linked to only one of the nicotinamide moieties. The nucleator of formula (I) may be in combination with a nucleator of formula (II) which comprises a dimeric molecule comprising two monomers linked by a linking group, each monomer of which (a) may be the same or different and (b) comprises a hydrazide moiety and a nicotinamide moiety. The photographic material provides unexpectedly good nucleation in the absence of, or with reduced amounts of, booster and in a developer whose pH is variable, and further with lower chemical spread and pepper fog. When the synthesis provides both a compound of formula (I) and (II), the products can be used directly without a separation step, providing a cost advantage.

    摘要翻译： 本发明涉及一种超高对比度照相材料，其特征在于，式（I）的成核剂包括：（a）两个（II）的成核剂，其特征在于，所述超高对比度照相材料包含载体，所述载体含有在所述乳剂层中的酰肼成核剂或亲水胶体层的卤化银乳剂层， 烟酰胺部分，其可以相同或不同，其通过连接基团连接，和（b）仅与一个烟酰胺部分连接的酰肼部分。 式（I）的成核剂可以与式（II）的成核剂组合，其包含包含通过连接基团连接的两个单体的二聚体分子，其各自的单体（a）可以相同或不同，和（b） 包含酰肼部分和烟酰胺部分。照相材料在不存在或具有减少量的助催化剂和在pH可变的显影剂中进一步具有较低的化学扩散和胡椒雾的情况下提供出人意料的良好成核。 当合成提供式（I）和（II）的化合物时，可以直接使用产物而不进行分离步骤，从而提供成本优势。

    Image dye-forming couplers and photographic elements containing them
    4.
    发明授权
    Image dye-forming couplers and photographic elements containing them 失效
    图像染料形成成色剂和含有它们的摄影元件

    公开(公告)号：US6071683A

    公开(公告)日：2000-06-06

    申请号：US131851

    申请日：1998-08-07

    申请人： John D. Goddard ,  Danuta Gibson ,  Llewellyn J. Leyshon ,  Brian Thomas

    发明人： John D. Goddard ,  Danuta Gibson ,  Llewellyn J. Leyshon ,  Brian Thomas

    IPC分类号： C07C235/80 ,  C07C311/08 ,  C07D263/44 ,  G03C7/30 ,  G03C7/305 ,  G03C7/36 ,  G03C7/392 ,  G03C1/08

    CPC分类号： C07D263/44 ,  C07C235/80 ,  C07C311/08 ,  G03C7/3013 ,  G03C7/30535 ,  G03C7/36 ,  G03C7/39216

    摘要： The present invention relates to a silver halide photographic element comprising a dye-forming coupler of formula (I) ##STR1## wherein R.sup.1 is selected from an alkyl group, an aryl group, a 5-10 membered heterocyclic group containing one or more O, N or S atoms, each of which groups is unsubstituted or substituted, or a substituted amino group;R.sup.2 is an unsubstituted alkyl group having a secondary or tertiary carbon atom attached to the oxygen atom;X is hydrogen or a coupling-off group; andR.sup.3 is a substituent and n is 0 to 4; orwherein R.sup.2, as defined above, and an R.sup.3 substituent may together with the O atom form a 5-10 membered heterocyclic group which may contain one or more further heteroatoms selected from O, N and S, said group being unsubstituted or substituted; andwherein at least one of R.sup.1, R.sup.2 and R.sup.3 separately or in combination constitutes a ballast group,the couplers providing enhanced light stability together with acceptable dye hue in images produced from photographic materials containing them.

    摘要翻译： 本发明涉及一种卤化银照相元件，其包含式（I）的染料形成成色剂，其中R 1选自烷基，芳基，含有一个或多个O，N或S的5-10元杂环基 原子，其各自为未取代或取代的基团，或取代的氨基; R2是与氧原子连接的具有仲或叔碳原子的未取代的烷基; X是氢或偶合离去基团; R3为取代基，n为0〜4; 或其中如上定义的R 2和R 3取代基可以与O原子一起形成5-10元杂环基团，其可以含有一个或多个另外的选自O，N和S的杂原子，所述基团是未取代的或取代的; 并且其中R 1，R 2和R 3中的至少一个分别或组合构成镇流器基团，所述成色剂提供增强的光稳定性以及由含有它们的照相材料产生的图像中可接受的染料色调。

    Method for rapid photographic processing with maintained color balance using diffusible photochemicals
    6.
    发明授权
    Method for rapid photographic processing with maintained color balance using diffusible photochemicals 失效
    快速摄影处理方法，使用可扩散的光化学物质保持色彩平衡

    公开(公告)号：US5994037A

    公开(公告)日：1999-11-30

    申请号：US176529

    申请日：1998-10-21

    申请人： Peter J. Twist ,  John D. Goddard

    发明人： Peter J. Twist ,  John D. Goddard

    IPC分类号： G03C7/407 ,  G03C7/413

    CPC分类号： G03C7/413 ,  G03C2200/20 ,  G03C2200/52 ,  G03C7/30541 ,  Y10S430/164

    摘要： Color photographic elements, especially color photographic papers, can be more rapidly color developed (up to 25 seconds) in the presence of a color developing solution containing a selectively diffusible color development photochemical such as a development inhibitor. Despite the shortened processing time, color balance within the three color records of such elements is maintained. The selectively diffusible color development photochemical has size and structure that enables it to have sufficient solubility in the color developing composition, and to selectively diffuse into the topmost red-sensitive emulsion layers of the processed color papers only.

    摘要翻译： 在含有选择性扩散显色光化学物质如显影抑制剂的显色溶液的存在下，彩色照相元件，特别是彩色照相纸可以更快速地显色（至多25秒）。 尽管处理时间缩短了，但仍保持了这些元素的三色记录中的色彩平衡。 选择性扩散显色光化学品具有使其能够在显色组合物中具有足够溶解度的尺寸和结构，并且仅选择性地扩散到经处理的彩色纸的最上面的感光乳剂层中。

    Photographic addenda
    9.
    发明授权
    Photographic addenda 失效
    摄影附录

    公开(公告)号：US06200741B1

    公开(公告)日：2001-03-13

    申请号：US09443743

    申请日：1999-11-19

    申请人： Paul L. Stanley ,  John D. Goddard

    发明人： Paul L. Stanley ,  John D. Goddard

    IPC分类号： G03C108

    CPC分类号： G03C7/39236 ,  G03C7/30535

    摘要： The present invention provides a photographic element comprising a support bearing a light-sensitive silver halide emulsion layer in association with an image dye-forming coupler and having associated therewith a compound of general formula wherein R1 is an unsubstituted or substituted alkyl group, aryl group or 5-10 membered heterocyclic ring group containing one or more heteroatoms selected from N, O and S; each R2 is independently selected from hydrogen, halogen, and substituted or unsubstituted alkyl, aryl, alkyl- or aryl-sulfamoyl, alkyl- or aryl-sulfonamido, alkyl- or aryl-carbamoyl, alkyl- or aryl-carbonamido, alkenyloxy or 5-10 membered heterocyclic ring group containing one or more heteroatoms selected from N, O and S; each Y is independently selected from the groups consisting of —NHSO2 and —SO2NH; wherein the hydrogen therein has a pKa value of less than 9; n is an integer from 1 to 20; x is an integer from 1 to 6 and wherein the compound is ballasted. The addenda of formula (I) can significantly increase the image dye yield and improve robustness to process pH variation, without adverse effects on coupler or dye stability, dye hue and/or speed, in a simple, cost effective way.

    摘要翻译： 本发明提供了一种照相元件，其包含支持感光卤化银乳剂层的支持物，其与形成成像剂的成色剂相结合，并且与其相关联的通式化合物R1是未取代或取代的烷基，芳基或5- 含有一个或多个选自N，O和S的杂原子的10元杂环基;每个R 2独立地选自氢，卤素和取代或未取代的烷基，芳基，烷基 - 或芳基 - 氨磺酰基，烷基 - 或芳基 - 亚磺酰氨基， 含有一个或多个选自N，O和S的杂原子的烷基或芳基 - 氨基甲酰基，烷基 - 或芳基 - 碳酰氨基，烯氧基或5-10元杂环基;每个Y独立地选自-NHSO 2和 - SO2NH; 其中其中的氢气的pKa值小于9; n为1至20的整数; x为1至6的整数，并且化合物被镇定。式（I）的添加剂可显着提高图像染料的产率 并且以简单且成本有效的方式提高了稳定性以处理pH变化，而不影响成色剂或染料稳定性，染料色调和/或速度。