Method of preparing high capacity nickel electrode powder
    3.
    发明授权
    Method of preparing high capacity nickel electrode powder 失效
    制备高容量镍电极粉末的方法

    公开(公告)号:US3941614A

    公开(公告)日:1976-03-02

    申请号:US558110

    申请日:1975-03-13

    IPC分类号: H01M4/32 H01M4/52 H01M4/16

    CPC分类号: H01M4/32 H01M4/52

    摘要: An electrode plate is made by loading a supporting porous metallic plaque with active battery material made by: (1) hydrolyzing the reaction product of a starting material comprising an admixture of Ni oxide and effective amounts of sodium peroxide fused at temperatures between about 800.degree.C-1150.degree.C, the hydrolyzed solid reaction product containing electrochemically active Ni hydrated oxides and hydroxide forms, (2) if desirable, drying the product below about 65.degree.C, and (3) adding, at some step in the method, an amount of cobalt containing additive effective to provide about 2-12 wt% total Co in the active battery material based on Ni oxide plus Co content.

    摘要翻译: 电极板通过用活性电池材料装载支撑多孔金属板制成,该活性电池材料通过以下步骤制备:(1)水解包含Ni氧化物和有效量的过氧化钠的起始材料的反应产物,其在约800℃ -1150℃,含有电化学活性的Ni水合氧化物和氢氧化物形式的水解固体反应产物,(2)如果需要,将产物干燥在约65℃以下,和(3)在该方法的某个步骤中加入量 的含钴添加剂有效地提供基于Ni氧化物和Co含量的活性电池材料中的总共Co的约2-12重量%。

    High capacity nickel battery material doped with alkali metal cations
    4.
    发明授权
    High capacity nickel battery material doped with alkali metal cations 失效
    高容量镍电池材料掺杂碱金属阳离子

    公开(公告)号:US4330603A

    公开(公告)日:1982-05-18

    申请号:US229360

    申请日:1981-01-29

    IPC分类号: H01M4/32 H01M4/52

    CPC分类号: H01M4/32 H01M4/52

    摘要: A high capacity battery material is made, consisting essentially of hydrated Ni(II) hydroxide, and about 5 wt. % to about 40 wt. % of Ni(IV) hydrated oxide interlayer doped with alkali metal cations selected from potassium, sodium and lithium cations.

    摘要翻译: 制造高容量电池材料,其基本上由氢氧化镍(II)和约5wt。 %至约40wt。 含有选自钾,钠和锂阳离子的碱金属阳离子的Ni(IV)水合氧化物中间体的%。

    Iron EDTA chelate catalyzed oxidation of uranium
    5.
    发明授权
    Iron EDTA chelate catalyzed oxidation of uranium 失效
    铁EDTA螯合催化氧化铀

    公开(公告)号:US4243638A

    公开(公告)日:1981-01-06

    申请号:US915648

    申请日:1978-06-15

    摘要: Uranium ore deposits which contain uranium in the relatively insoluble tetravalent state are readily selectively leached in situ to recover relatively pure uranium compounds, by: (a) passing through the ore deposit a relatively dilute aqueous leach solution of ammonium bicarbonate, ferric ammonium ethylenediaminetetraacetic acid (EDTA), and a source of oxygen, the leach solution converting the tetravalent uranium to hexavalent uranium which readily dissolves in the leach solution; (b) withdrawing the reacted leach solution enriched in dissolved uranium from the ore deposit; and (c) stripping the uranium from the withdrawn leach solution. The stripping of the uranium from the leach solution is preferably accomplished by countercurrent flow of the enriched leach solution to a column of base anion exchange material which preferentially extracts the uranium. Base anion exchange material loaded with uranium is separated from the leach solution and is treated with an aqueous alkaline eluant to extract the uranium and to regenerate the base anion exchange material. The stripped leach solution is adjusted by adding ammonium bicarbonate, peroxide, and ferric ammonium EDTA, and its pH corrected if necessary, and the leach solution is recycled through the ore deposit. The uranium bearing eluant is then acidified and treated with ammonia to precipitate relatively pure ammonium diuranate (ADU).

    摘要翻译: 含有相对不溶性四价态的铀的铀矿床可以通过以下方式容易地选择性地浸出以回收相对纯的铀化合物:(a)通过矿石沉积相对稀的碳酸氢铵浸出溶液,乙二胺四乙酸亚铁铵 EDTA)和氧源,将四价铀转化为六价铀的浸出溶液,其容易溶解在浸出溶液中; (b)从矿床中取出富含溶解铀的反应浸出液; 和(c)从撤回的浸出溶液中汽提铀。 从浸出溶液中汽提铀优选通过将富集浸出溶液逆流流向优先萃取铀的碱阴离子交换材料塔来完成。 将负载有铀的碱性阴离子交换材料与浸出溶液分离,并用碱性水溶液处理以提取铀并再生碱阴离子交换材料。 通过加入碳酸氢铵,过氧化物和EDTA铁铵来调节剥离的浸出溶液,如果需要,其pH值被校正,并且浸出溶液通过矿床再循环。 然后将含铀的洗脱液酸化并用氨处理以沉淀相对纯的氢氧化二铵(ADU)。

    Catalyses of uranium oxidation
    6.
    发明授权
    Catalyses of uranium oxidation 失效
    铀氧化催化剂

    公开(公告)号:US4200337A

    公开(公告)日:1980-04-29

    申请号:US915647

    申请日:1978-06-15

    摘要: The oxidation of uranium is catalyzed with water-soluble copper or zinc chelates. An aqueous solution is prepared containing carbonate or bicarbonate ion, an oxidizer such as hydrogen peroxide or oxygen, and a water-soluble copper or zinc chelate which has at least two amino, carboxylic acid, or thiocarboxylic acid donor groups. The solution is pumped into an underground deposit of uranium. The water-soluble +4 state uranium is oxidized to the water-soluble +6 state which forms a complex with the carbonate ion. The solution is pumped to the surface and is recycled after precipitation of the uranium.

    摘要翻译: 铀的氧化用水溶性铜或锌螯合物催化。 制备含有碳酸盐或碳酸氢根离子的水溶液,氧化剂如过氧化氢或氧气,以及具有至少两个氨基,羧酸或硫代羧酸供体基团的水溶性铜或锌螯合物。 将溶液泵入地下的铀矿床。 水溶性+4态铀被氧化成与碳酸根离子形成络合物的水溶性+6状态。 将溶液泵送到表面,并在铀沉淀后再循环。

    Method of preparing high capacity nickel electrode powder
    7.
    发明授权
    Method of preparing high capacity nickel electrode powder 失效
    制备高容量镍电极粉末的方法

    公开(公告)号:US4029132A

    公开(公告)日:1977-06-14

    申请号:US689624

    申请日:1976-05-24

    IPC分类号: H01M4/32 H01M4/52

    CPC分类号: H01M4/52 H01M4/32

    摘要: A battery electrode plate is made by loading a supporting porous metallic plaque with active battery material made by: (1) hydrolyzing the reaction product of a fuse-melted starting material comprising an admixture of nickel oxide, sodium peroxide and an amount of an oxide containing, alkali metal, non-reactive flux material effective to allow a melt-fusion reaction of the starting material at temperatures of between about 650.degree. C to about 925.degree. C, the hydrolyzed solid reaction product containing electrochemically active nickel hydrated oxides and hydroxide forms, (2) if desirable, drying the product below about 65.degree. C, and (3) preferably adding, at some step in the method, an amount of cobalt containing additive effective to provide about 2 wt.% to about 10 wt.% cobalt in the active battery material based on nickel oxide plus cobalt content.

    摘要翻译: 电池电极板是通过用活性电池材料装载支撑多孔金属板制成的,该活性电池材料是通过以下方法制得的:(1)水解包含氧化镍,过氧化钠和一定量的氧化物的熔融起始材料的反应产物 ,有效地允许原料在约650℃至约925℃的温度下的熔融熔融反应的碱金属,非反应性助熔剂,含有电化学活性的镍水合氧化物和氢氧化物形式的水解固体反应产物, (2)如果需要,将产物干燥在约65℃以下,和(3)优选在该方法的某一步骤中加入一定量的含钴添加剂,其有效提供约2重量%至约10重量%的钴 在基于氧化镍加钴含量的活性电池材料中。

    Method of preparing high capacity nickel electrode powder
    10.
    发明授权
    Method of preparing high capacity nickel electrode powder 失效
    制备高容量镍电极粉末的方法

    公开(公告)号:US4016091A

    公开(公告)日:1977-04-05

    申请号:US627330

    申请日:1975-10-30

    IPC分类号: H01M4/32 H01M4/52 H01M4/88

    CPC分类号: H01M4/32 H01M4/52

    摘要: An electrode plate is made by loading a supporting porous metallic plaque with active battery material made by: (1) hydrolyzing the reaction product of a starting material comprising an admixture of Ni oxide and effective amounts of sodium peroxide fused at temperatures between about 800.degree.-1150.degree. C, the hydrolyzed solid reaction product containing electrochemically active Ni hydrated oxides and hydroxide forms, (2) if desirable, drying the product below about 65.degree. C, and (3) adding, at some step in the method, an amount of cobalt containing additive effective to provide about 2-12 wt% total Co in the active battery material based on Ni oxide plus Co content.

    摘要翻译: 电极板是通过用活性电池材料加载支撑多孔金属板制成的,该活性电池材料通过以下步骤制备:(1)水解包含Ni氧化物混合物和有效量的过氧化钠的起始材料的反应产物,其在约800℃ - 1150℃,含有电化学活性的Ni水合氧化物和氢氧化物的水解固体反应产物形成,(2)如果需要,将产物干燥至约65℃以下,和(3)在该方法的某一步骤中加入一定量的 含钴添加剂有效地提供基于Ni氧化物加Co含量的活性电池材料中的总共Co的约2-12重量%。