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1.发明申请CONVERSION OF A MULTIHYDROXYLATED-ALIPHATIC HYDROCARBON OR ESTER THEREOF TO A CHLOROHYDRIN 审中-公开将多羟基化二烃或其酯转化为氯仿的转化公开(公告)号：US20100152499A1
公开(公告)日：2010-06-17
申请号：US12595396
申请日：2008-04-11
申请人： John R. Briggs , Bruce D. Hook , William J. Kruper, JR. , Anil Mehta , Robert M. Alvarado , Sascha Noormann , Perry S. Basile
发明人： John R. Briggs , Bruce D. Hook , William J. Kruper, JR. , Anil Mehta , Robert M. Alvarado , Sascha Noormann , Perry S. Basile
摘要： The present invention relates to a process for converting at least one multihydroxylated-aliphatic hydrocarbon and/or an ester thereof to at least one chlorohydrin and/or an ester thereof, comprising at least one reaction step in which the multihydroxylated-aliphatic hydrocarbon and/or ester thereof is contacted with hydrogen chloride under reaction conditions to produce the chlorohydrin and/or ester thereof, followed by at least one downstream processing step in which the effluents of the reaction step are processed, wherein the downstream processing step is performed in such conditions that the effluents containing the chlorohydrin and/or ester thereof are kept at a temperature of less than 12O° C. The invention allows to minimize the liberation of hydrogen chloride from the products of the hydrochlorination reaction, hence reducing the corrosion of the downstream equipment and reducing M the need to use costly corrosion resistant materials.
摘要翻译： 本发明涉及将至少一种多羟基化脂族烃和/或其酯转化为至少一种氯代醇和/或其酯的方法，该方法包括至少一个反应步骤，其中多羟基化脂族烃和/或 其酯在反应条件下与氯化氢接触以产生氯醇和/或其酯，随后是至少一个下游处理步骤，其中反应步骤的流出物被处理，其中下游处理步骤在以下条件下进行： 含有氯代醇和/或其酯的流出物保持在低于120℃的温度。本发明允许氯化氢从氢氯化反应的产物中释放最小化，从而减少下游设备的腐蚀并减少 M需要使用昂贵的耐腐蚀材料。
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2.发明申请CONVERSION OF A MULTIHYDROXYLATED-ALIPHATIC HYDROCARBON OR ESTER THEREOF TO A CHLOROHYDRIN 审中-公开将多羟基化二烃或其酯转化为氯仿的转化公开(公告)号：US20110028766A1
公开(公告)日：2011-02-03
申请号：US12935719
申请日：2009-03-18
申请人： John R. Briggs , Bruce D. Hook , William J. Kruper Jr. , Anil Mehta , Robert M. Alvarado , Sascha Noormann , Perry S. Basile
发明人： John R. Briggs , Bruce D. Hook , William J. Kruper Jr. , Anil Mehta , Robert M. Alvarado , Sascha Noormann , Perry S. Basile
摘要： The present invention relates to a process for converting at least one multihydroxylated-aliphatic hydrocarbon and/or an ester thereof to at least one chlorohydrin and/or an ester thereof, comprising at least one reaction step in which the multihydroxylated-aliphatic hydrocarbon and/or ester thereof is contacted with hydrogen chloride under reaction conditions to produce the chlorohydrin and/or ester thereof, followed by at least one downstream processing step in which the effluents of the reaction step are processed, wherein the downstream processing step is performed in such conditions that the effluents containing the chlorohydrin and/or ester thereof are kept at a temperature of less than 120° C. The invention allows to minimize the liberation of hydrogen chloride from the products of the hydrochlorination reaction, hence reducing the corrosion of the downstream equipment and reducing the need to use costly corrosion resistant materials.
摘要翻译： 本发明涉及将至少一种多羟基化脂族烃和/或其酯转化为至少一种氯代醇和/或其酯的方法，该方法包括至少一个反应步骤，其中多羟基化脂族烃和/或 其酯在反应条件下与氯化氢接触以产生氯醇和/或其酯，随后是至少一个下游处理步骤，其中反应步骤的流出物被处理，其中下游处理步骤在以下条件下进行： 含有氯代醇和/或其酯的流出物保持在小于120℃的温度。本发明允许氯化氢从氢氯化反应的产物中释放最小化，从而减少下游设备的腐蚀并减少 需要使用昂贵的耐腐蚀材料。
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公开(公告)号：US20100331555A1
公开(公告)日：2010-12-30
申请号：US12866370
申请日：2009-01-22
IPC分类号： C07D301/24 , B01D3/14 , C07D301/32
CPC分类号： C07D301/12 , C07D301/32
摘要： A process and apparatus are disclosed for the purification of epichlorohydrin. The process includes distilling and/or fractionating a feed stream containing epichlorohydrin, dichlorohydrin(s), and one or more other substances, subjecting at least a portion of the liquid phase effluent to a dichlorohydrin dehydrochlorination process for converting residual dichlorohydrin(s) in the liquid phase effluent to epichlorohydrin, and recovering purified epichlorohydrin from the vapor phase effluent in which the distillation/fractionation pressure and/or temperature of step (1) is adjusted to retain at least 5 weight-percent epichlorohydrin in the liquid phase effluent. The apparatus for making purified epichlorohydrin includes a dehydrochlorination apparatus, a first liquid-vapor contacting apparatus, and a second liquid-vapor contacting apparatus connected to the dehydrochlorination apparatus for recycling a distillate to the dehydrochlorination apparatus. Advantages include more efficient recovery of epichlorohydrins and reduced capital investment in recovery equipment.
摘要翻译： 公开了用于纯化表氯醇的方法和装置。 该方法包括蒸馏和/或分馏含有表氯醇，二氯丙醇和一种或多种其它物质的进料流，将至少一部分液相流出物进行二氯丙醇脱氯化氢处理，以将残留的二氯丙醇 液相流出物至表氯醇，并从蒸气相流出物中回收纯化的表氯醇，其中调节步骤（1）的蒸馏/分馏压力和/或温度以在液相流出物中保留至少5重量％的表氯醇。 用于制备纯化的表氯醇的装置包括脱氯化氢装置，第一液 - 蒸气接触装置和连接到脱氯化氢装置的第二液 - 蒸气接触装置，用于将馏出物再循环到脱氯化氢装置。 优点包括更有效地回收表氯醇，减少回收设备的资金投入。
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公开(公告)号：US08298500B2
公开(公告)日：2012-10-30
申请号：US12866370
申请日：2009-01-22
IPC分类号： B01J8/00 , C07D301/26
CPC分类号： C07D301/12 , C07D301/32
摘要： A process and apparatus are disclosed for the purification of epichlorohydrin. The process includes distilling and/or fractionating a feed stream containing epichlorohydrin, dichlorohydrin(s), and one or more other substances, subjecting at least a portion of the liquid phase effluent to a dichlorohydrin dehydrochlorination process for converting residual dichlorohydrin(s) in the liquid phase effluent to epichlorohydrin, and recovering purified epichlorohydrin from the vapor phase effluent in which the distillation/fractionation pressure and/or temperature of step (1) is adjusted to retain at least 5 weight-percent epichlorohydrin in the liquid phase effluent. The apparatus for making purified epichlorohydrin includes a dehydrochlorination apparatus, a first liquid-vapor contacting apparatus, and a second liquid-vapor contacting apparatus connected to the dehydrochlorination apparatus for recycling a distillate to the dehydrochlorination apparatus. Advantages include more efficient recovery of epichlorohydrins and reduced capital investment in recovery equipment.
摘要翻译： 公开了用于纯化表氯醇的方法和装置。 该方法包括蒸馏和/或分馏含有表氯醇，二氯丙醇和一种或多种其它物质的进料流，将至少一部分液相流出物进行二氯丙醇脱氯化氢处理，以将残留的二氯丙醇 液相流出物至表氯醇，并从蒸气相流出物中回收纯化的表氯醇，其中调节步骤（1）的蒸馏/分馏压力和/或温度以在液相流出物中保留至少5重量％的表氯醇。 用于制备纯化的表氯醇的装置包括脱氯化氢装置，第一液 - 蒸气接触装置和连接到脱氯化氢装置的第二液 - 蒸气接触装置，用于将馏出物再循环到脱氯化氢装置。 优点包括更有效地回收表氯醇，减少回收设备的资金投入。
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公开(公告)号：US08338627B2
公开(公告)日：2012-12-25
申请号：US12512227
申请日：2009-07-30
申请人： William W. Fan , Christian D. Kneupper , Sascha Noormann , Ranate Patrascu , Bruce D. Hook , Charles W. Lipp , Michael D. Cloeter , Heinz Groenewald
发明人： William W. Fan , Christian D. Kneupper , Sascha Noormann , Ranate Patrascu , Bruce D. Hook , Charles W. Lipp , Michael D. Cloeter , Heinz Groenewald
IPC分类号： C07D301/24
CPC分类号： C07D301/26 , C07D303/04 , C07D303/08 , Y02P20/127
摘要： A process for producing epoxide, the process including contacting an organic phase including at least one halohydrin(s) with at least one aqueous phase including a base in a plug-flow mixer/reactor system to disperse the organic phase in the aqueous phase via a mixing device imparting a power-to-mass ratio of at least 0.2 W/kg to convert at least a portion of the at least one halohydrin to an epoxide.
摘要翻译： 一种生产环氧化物的方法，该方法包括使包含至少一种卤代醇的有机相与至少一种包含碱的水相在活塞流混合器/反应器系统中接触，以通过经由 混合装置赋予至少0.2W / kg的功率质量比以将至少一部分卤代醇转化为环氧化物。
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公开(公告)号：US20100029958A1
公开(公告)日：2010-02-04
申请号：US12508435
申请日：2009-07-23
IPC分类号： C07D301/24
CPC分类号： C07D301/26 , B01D3/009 , Y02P20/127
摘要： A process for producing epoxides, the process including: (a) feeding at least one aqueous alkali and at least one halohydrin to a reactive distillation column; (b) concurrently in the reactive distillation column: (i) reacting at least a portion of the halohydrin with the alkali to form an epoxide; and (ii) stripping water and the epoxide from a basic aqueous residue; (c) recovering the water and the epoxide from the reactive distillation column as an overheads fraction; and, (d) condensing and phase separating the overheads fraction at a temperature of 50° C. or less to form an organic overheads fraction including the epoxide and an aqueous overheads fraction including water.
摘要翻译： 一种制备环氧化物的方法，该方法包括：（a）将至少一种碱金属和至少一种卤代醇进料至反应性蒸馏塔; （b）在反应蒸馏塔中同时进行：（i）使至少一部分卤代醇与碱反应形成环氧化物; 和（ii）从碱性含水残余物中除去水和环氧化物; （c）从反应蒸馏塔中回收水和环氧化物作为塔顶馏分; 和（d）在50℃或更低的温度下冷凝和相分离塔顶馏分以形成包括环氧化物的有机塔顶馏分和包含水的塔顶馏分馏分。
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公开(公告)号：US07982061B2
公开(公告)日：2011-07-19
申请号：US12508435
申请日：2009-07-23
IPC分类号： C07D301/24
CPC分类号： C07D301/26 , B01D3/009 , Y02P20/127
摘要： A process for producing epoxides, the process including: (a) feeding at least one aqueous alkali and at least one halohydrin to a reactive distillation column; (b) concurrently in the reactive distillation column: (i) reacting at least a portion of the halohydrin with the alkali to form an epoxide; and (ii) stripping water and the epoxide from a basic aqueous residue; (c) recovering the water and the epoxide from the reactive distillation column as an overheads fraction; and, (d) condensing and phase separating the overheads fraction at a temperature of 50° C. or less to form an organic overheads fraction including the epoxide and an aqueous overheads fraction including water.
摘要翻译： 一种制备环氧化物的方法，该方法包括：（a）将至少一种碱金属和至少一种卤代醇进料至反应性蒸馏塔; （b）在反应蒸馏塔中同时进行：（i）使至少一部分卤代醇与碱反应形成环氧化物; 和（ii）从碱性含水残余物中除去水和环氧化物; （c）从反应蒸馏塔中回收水和环氧化物作为塔顶馏分; 和（d）在50℃或更低的温度下冷凝和相分离塔顶馏分以形成包括环氧化物的有机塔顶馏分和包含水的塔顶馏分馏分。
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公开(公告)号：US07985867B2
公开(公告)日：2011-07-26
申请号：US12508465
申请日：2009-07-23
IPC分类号： C07D301/24 , B01D3/34
CPC分类号： C07D301/26 , B01D3/009 , Y02P20/127
摘要： A process for producing epoxides, the process including: (a) feeding at least one aqueous alkali and at least one halohydrin to a reactive distillation column, wherein the reactive distillation column includes a feed zone, a top zone disposed above the feed zone, and a bottom zone disposed below the feed zone; (b) concurrently in the reactive distillation column: (i) reacting at least a portion of the halohydrin with the alkali to form an epoxide; and (ii) stripping water and the epoxide from a basic aqueous residue; (c) recovering the water and the epoxide from the reactive distillation column as an overheads fraction; (d) condensing and phase separating the overheads fraction to form an organic overheads fraction including the epoxide and an aqueous overheads fraction including water; and (e) maintaining a liquid holdup per plate in the feed zone at a residence time of 10 seconds or less.
摘要翻译： 一种制备环氧化物的方法，该方法包括：（a）将至少一种碱金属和至少一种卤代醇进料到反应性蒸馏塔中，其中反应蒸馏塔包括进料区，设置在进料区上方的顶部区，以及 位于进料区下方的底部区域; （b）在反应蒸馏塔中同时进行：（i）使至少一部分卤代醇与碱反应形成环氧化物; 和（ii）从碱性含水残余物中除去水和环氧化物; （c）从反应蒸馏塔中回收水和环氧化物作为塔顶馏分; （d）冷凝和相分离塔顶馏分以形成包括环氧化物和包含水的含水塔顶馏分的有机塔顶馏分; 和（e）在10秒或更短的停留时间内在进料区中保持每个板的液体滞留量。
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公开(公告)号：US20100029959A1
公开(公告)日：2010-02-04
申请号：US12508465
申请日：2009-07-23
IPC分类号： C07D301/24
CPC分类号： C07D301/26 , B01D3/009 , Y02P20/127
摘要： A process for producing epoxides, the process including: (a) feeding at least one aqueous alkali and at least one halohydrin to a reactive distillation column, wherein the reactive distillation column includes a feed zone, a top zone disposed above the feed zone, and a bottom zone disposed below the feed zone; (b) concurrently in the reactive distillation column: (i) reacting at least a portion of the halohydrin with the alkali to form an epoxide; and (ii) stripping water and the epoxide from a basic aqueous residue; (c) recovering the water and the epoxide from the reactive distillation column as an overheads fraction; (d) condensing and phase separating the overheads fraction to form an organic overheads fraction including the epoxide and an aqueous overheads fraction including water; and (e) maintaining a liquid holdup per plate in the feed zone at a residence time of 10 seconds or less.
摘要翻译： 一种制备环氧化物的方法，该方法包括：（a）将至少一种碱金属和至少一种卤代醇进料到反应性蒸馏塔中，其中反应蒸馏塔包括进料区，设置在进料区上方的顶部区，以及 位于进料区下方的底部区域; （b）在反应蒸馏塔中同时进行：（i）使至少一部分卤代醇与碱反应形成环氧化物; 和（ii）从碱性含水残余物中除去水和环氧化物; （c）从反应蒸馏塔中回收水和环氧化物作为塔顶馏分; （d）冷凝和相分离塔顶馏分以形成包括环氧化物和包含水的含水塔顶馏分的有机塔顶馏分; 和（e）在10秒或更短的停留时间内在进料区中保持每个板的液体滞留量。
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