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1.发明授权公开(公告)号：US08450449B2
公开(公告)日：2013-05-28
申请号：US13111350
申请日：2011-05-19
申请人： John R. Reynolds , Pengjie Shi , Jianguo Mei , Chad Martin Amb
发明人： John R. Reynolds , Pengjie Shi , Jianguo Mei , Chad Martin Amb
IPC分类号： C08G75/00
CPC分类号： C08G61/126 , C08G61/122 , C08G2261/122 , C08G2261/1424 , C08G2261/3223 , C08G2261/3246 , C08G2261/414 , C08G2261/54 , C09K9/02 , C09K2211/1458 , C09K2211/1491 , G02F2001/1515
摘要： Embodiments of the invention are directed to random conjugated copolymers comprising a plurality of one or more different donor (D) repeating units and a plurality of at least one acceptor (A) repeating unit. At least one of the D units has a solubilizing substituent, statistically a portion of the A repeating units are separated from each other by only one D units and a plurality of the A unit are adjacent to one the D units having the solubilizing substituents. The random conjugated copolymers are black or colored in the neutral state and highly transmissive in the oxidized state. The random conjugated copolymers have the structure -[(D)xA]n-, where x>1 and n(x+1)≧10 or the structure -[(DA))x-(D′A)y]n-, where D represents one substituted D unit and D′ represents another D units and where x≧1, y≧1 and 2n(x+y)≧10. Other embodiments of the invention are directed to forming the -[(D)xA]n- or -[(DA)x-(D′A)y]n- random conjugated copolymers by condensation polymerizations between monomers containing complementary reactive groups.
摘要翻译： 本发明的实施方案涉及包含多个一个或多个不同施主（D）重复单元和多个至少一个受体（A）重复单元的无规共轭共聚物。 D单元中的至少一个具有增溶取代基，统计上，A重复单元的一部分通过仅一个D单元彼此分离，并且多个A单元与具有增溶取代基的D单元中的一个相邻。 无规共轭共聚物在中性状态下为黑色或着色，在氧化态下具有高透射性。 无规共轭共聚物具有结构 - [（D）xA] n-，其中x> 1和n（x + 1）> = 10或结构 - [（DA）x-（D'A）y] n- 其中D表示一个取代的D单元，D'表示另一D单元，其中x> = 1，y> = 1和2n（x + y）> = 10。 本发明的其它实施方案涉及通过在含有互补反应性基团的单体之间进行缩聚而形成 - [（D）xA] n或 - [（DA）x-（D'A）y] n-无规共轭共聚物。
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2.发明申请公开(公告)号：US20110288253A1
公开(公告)日：2011-11-24
申请号：US13111350
申请日：2011-05-19
申请人： JOHN R. REYNOLDS , Pengjie Shi , Jianguo Mei , Chad Martin Amb
发明人： JOHN R. REYNOLDS , Pengjie Shi , Jianguo Mei , Chad Martin Amb
IPC分类号： C08F230/04 , C08G83/00
CPC分类号： C08G61/126 , C08G61/122 , C08G2261/122 , C08G2261/1424 , C08G2261/3223 , C08G2261/3246 , C08G2261/414 , C08G2261/54 , C09K9/02 , C09K2211/1458 , C09K2211/1491 , G02F2001/1515
摘要： Embodiments of the invention are directed to random conjugated copolymers comprising a plurality of one or more different donor (D) repeating units and a plurality of at least one acceptor (A) repeating unit. At least one of the D units has a solubilizing substituent, statistically a portion of the A repeating units are separated from each other by only one D units and a plurality of the A unit are adjacent to one the D units having the solubilizing substituents. The random conjugated copolymers are black or colored in the neutral state and highly transmissive in the oxidized state. The random conjugated copolymers have the structure -[(D)xA]n-, where x>1 and n(x+1)≧10 or the structure -[(DA))x-(D′Ay]n-, where D represents one substituted D unit and D′ represents another D units and where x≧1, y≧1 and 2n(x+y)≧10. Other embodiments of the invention are directed to forming the -[(D)xA]n- or -[(DA)x-(D′A)y]n- random conjugated copolymers by condensation polymerizations between monomers containing complementary reactive groups.
摘要翻译： 本发明的实施方案涉及包含多个一个或多个不同施主（D）重复单元和多个至少一个受体（A）重复单元的无规共轭共聚物。 D单元中的至少一个具有增溶取代基，统计上，A重复单元的一部分通过仅一个D单元彼此分离，并且多个A单元与具有增溶取代基的D单元中的一个相邻。 无规共轭共聚物在中性状态下为黑色或着色，在氧化态下具有高透射性。 无规共轭共聚物具有结构 - [（D）xA] n-，其中x> 1和n（x + 1）≥10或结构 - [（DA）x-（D'Ay] n-，其中D 表示一个取代的D单元，D'表示另一个D单元，其中x≥1，y≥1和2n（x + y）≥10。本发明的其它实施方案涉及形成 - [（D）xA] 或 - [（DA）x-（D'A）y] n-无规共轭共聚物，通过在含有互补反应性基团的单体之间进行缩聚。
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公开(公告)号：US09006376B2
公开(公告)日：2015-04-14
申请号：US14001787
申请日：2012-02-27
申请人： Chad Martin Amb , Franky So , John R. Reynolds
发明人： Chad Martin Amb , Franky So , John R. Reynolds
CPC分类号： H01L51/0036 , C07F7/30 , C08G61/123 , C08G61/126 , C08G2261/124 , C08G2261/3243 , C08G2261/344 , C08G2261/414 , C08G2261/91 , H01L51/0043 , H01L51/0071 , Y02E10/52 , Y02E10/542 , Y02E10/549
摘要： Embodiments of the invention are directed to Ge comprising heterocyclic compounds which can be used for the preparation of homopolymers and copolymers. The copolymers can be donor-acceptor (DA) alternating copolymers where the donor unit is a Ge comprising heterocyclic unit. The polymers can be used as materials in solar cells and other photovoltaic devices, transistors, diodes, light emitting devices (LEDs), conductors, supercapacitors, batteries, and electrochromic devices.
摘要翻译： 本发明的实施方案涉及包含可用于制备均聚物和共聚物的杂环化合物的Ge。 共聚物可以是供体 - 受体（DA）交替共聚物，其中供体单元是包含杂环单元的Ge。 聚合物可以用作太阳能电池和其他光伏器件，晶体管，二极管，发光器件（LED），导体，超级电容器，电池和电致变色器件中的材料。
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4.发明授权公开(公告)号：US08394917B2
公开(公告)日：2013-03-12
申请号：US12829903
申请日：2010-07-02
IPC分类号： C08G75/00
CPC分类号： C08G75/02 , C08G61/122 , C08G61/123 , C08G61/126 , C08G2261/3223 , C08G2261/3243 , C08G2261/3246 , C09K9/02 , C09K2211/1458 , C09K2211/1483 , G02F2001/1512 , G02F2001/1515 , H01L51/0043 , H01L51/0558
摘要： Embodiments of the invention are directed to alternating donor-acceptor (DA) polymers that are soluble and display a blue or green neutral state that oxidizes to a transmissive state for use as an electrochromic polymer. The D units have 3,4-dioxythiophene, 3,6-dialkoxythieno[3,2-b]thiophene or 3,5-dialkoxy-dithieno[3,2-b:2′,3′-d]thiophene groups. Embodiments of the invention are directed to a method for preparation of the alternating DA polymeric sequences of the DA polymers by a cross-condensation of a nucleophilic acceptor monomer and an electrophilic donor monomer.
摘要翻译： 本发明的实施方案涉及交替的供体 - 受体（DA）聚合物，其可溶并显示蓝色或绿色中性状态，其氧化成透射状态以用作电致变色聚合物。 D单元具有3,4-二氧噻吩，3,6-二烷氧基噻吩并[3,2-b]噻吩或3,5-二烷氧基 - 二噻吩并[3,2-b：2'，3'-d]噻吩基团。 本发明的实施方案涉及通过亲核受体单体和亲电子供体单体的交叉缩合制备DA聚合物的交替DA聚合物序列的方法。
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公开(公告)号：US20120032104A1
公开(公告)日：2012-02-09
申请号：US13196412
申请日：2011-08-02
CPC分类号： H01B1/122 , C08G2261/3223 , H01G9/022 , Y02E60/13
摘要： Embodiments of the invention are directed to a method of forming a film of an insoluble conjugated polymer (CP) by deposition of an ionic CP from aqueous solution and converting the ionic CP to the insoluble CP. The ionic CP can be the salt of a carboxylic acid, sulfonic acid, phosphonic acid, boronic acid, amine, imine, phosphine, thioether, or complexed bidentate or polydentate ligand. The insoluble CP film can be used with an aqueous electrolyte solution for use as: an electrochromic film; charge injection layer for a solar cell, LED, and FET; conventional paints; supercapacitor; battery; electronic paper; anti-static coating; transparent conductor; sensors; anti-microbial coating; adhesive; RFID; or memory system.
摘要翻译： 本发明的实施方案涉及通过从水溶液中沉积离子CP并将离子CP转化为不溶性CP来形成不溶性共轭聚合物（CP）的膜的方法。 离子CP可以是羧酸，磺酸，膦酸，硼酸，胺，亚胺，膦，硫醚或络合的二齿或多齿配体的盐。 不溶性CP膜可以与电解质溶液一起使用，用作电致变色膜; 用于太阳能电池，LED和FET的电荷注入层; 常规油漆; 超级电容器 电池; 电子纸; 防静电涂料; 透明导体 传感器; 抗微生物涂层; 胶粘剂; RFID; 或内存系统。
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6.发明授权Cathodically coloring yellow soluble electrochromic and light emitting polymers 有权阴极染色黄色可溶性电致变色和发光聚合物公开(公告)号：US08399603B2
公开(公告)日：2013-03-19
申请号：US13282999
申请日：2011-10-27
IPC分类号： C08G75/00
CPC分类号： C09K9/02 , C07D495/04 , C09K2211/1458 , C09K2211/1466
摘要： Embodiments of the invention are directed to yellow-to-transmissive conjugated polymers, a method to prepare the yellow conjugated polymers, the use of the yellow conjugated polymers in an electrochromic and/or electroluminescent device comprising neutral state primary subtractive colored conjugated polymers, and a method to prepare the device comprising the yellow conjugated polymer. The yellow conjugated polymers comprise a sequence of dioxythiophene units alternating with aromatic units, thiophene units, furan units, and/or pyrrole units. The yellow conjugated polymers are prepared by cross-condensation reactions. The yellow conjugated polymers can be soluble and preparation of the device involves deposition of the yellow conjugated polymer from solution onto a surface.
摘要翻译： 本发明的实施方案涉及黄色至透射的共轭聚合物，制备黄色共轭聚合物的方法，在含有中性状态的主要减色共轭聚合物的电致变色和/或电致发光装置中使用黄色共轭聚合物，以及 制备包含黄色共轭聚合物的装置的方法。 黄色共轭聚合物包含与芳族单元，噻吩单元，呋喃单元和/或吡咯单元交替的二氧噻吩单元的序列。 通过交联缩合反应制备黄色共轭聚合物。 黄色共轭聚合物可以是可溶的，并且该装置的制备涉及将黄色共轭聚合物从溶液沉积到表面上。
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公开(公告)号：US20120216870A1
公开(公告)日：2012-08-30
申请号：US13505562
申请日：2010-11-02
IPC分类号： H01L51/46
CPC分类号： H01L51/4273 , H01L51/0036 , H01L51/0037 , H01L51/0038 , H01L51/0039 , H01L51/0043 , H01L51/441 , H01L2251/308 , Y02E10/549
摘要： An organic PV solar cell that has an anode double interlayer situated between an electrode and an organic photoactive layer displays superior power conversion efficiency over that of equivalent devices with an anode single interlayer. The anode double layer can comprise a hole extraction layer adjacent to the anode and an organic hole accepting electron blocking material layer that comprises an aromatic amine compound with a plurality of N atoms. The hole extraction layer can be a metal oxide or an n-type organic semiconductor.
摘要翻译： 具有位于电极和有机光活性层之间的阳极双层间隔的有机PV太阳能电池相对于具有阳极单中间层的等效器件的功率转换效率显示出优异的功率转换效率。 阳极双层可以包括邻近阳极的空穴提取层和包含具有多个N原子的芳族胺化合物的有机孔接受电子阻挡材料层。 空穴提取层可以是金属氧化物或n型有机半导体。
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公开(公告)号：US20110003967A1
公开(公告)日：2011-01-06
申请号：US12829903
申请日：2010-07-02
IPC分类号： C08G75/06
CPC分类号： C08G75/02 , C08G61/122 , C08G61/123 , C08G61/126 , C08G2261/3223 , C08G2261/3243 , C08G2261/3246 , C09K9/02 , C09K2211/1458 , C09K2211/1483 , G02F2001/1512 , G02F2001/1515 , H01L51/0043 , H01L51/0558
摘要： Embodiments of the invention are directed to alternating donor-acceptor (DA) polymers that are soluble and display a blue or green neutral state that oxidizes to a transmissive state for use as an electrochromic polymer. The D units have 3,4-dioxythiophene, 3,6-dialkoxythieno[3,2-b]thiophene or 3,5-dialkoxy-dithieno[3,2-b:2′,3′-d]thiophene groups. Embodiments of the invention are directed to a method for preparation of the alternating DA polymeric sequences of the DA polymers by a cross-condensation of a nucleophilic acceptor monomer and an electrophilic donor monomer.
摘要翻译： 本发明的实施方案涉及交替的供体 - 受体（DA）聚合物，其可溶并显示蓝色或绿色中性状态，其氧化成透射状态以用作电致变色聚合物。 D单元具有3,4-二氧噻吩，3,6-二烷氧基噻吩并[3,2-b]噻吩或3,5-二烷氧基 - 二噻吩并[3,2-b：2'，3'-d]噻吩基团。 本发明的实施方案涉及通过亲核受体单体和亲电子供体单体的交叉缩合制备DA聚合物的交替DA聚合物序列的方法。
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公开(公告)号：US09093193B2
公开(公告)日：2015-07-28
申请号：US13196412
申请日：2011-08-02
CPC分类号： H01B1/122 , C08G2261/3223 , H01G9/022 , Y02E60/13
摘要： Embodiments of the invention are directed to a method of forming a film of an insoluble conjugated polymer (CP) by deposition of an ionic CP from aqueous solution and converting the ionic CP to the insoluble CP. The ionic CP can be the salt of a carboxylic acid, sulfonic acid, phosphonic acid, boronic acid, amine, imine, phosphine, thioether, or complexed bidentate or polydentate ligand. The insoluble CP film can be used with an aqueous electrolyte solution for use as: an electrochromic film; charge injection layer for a solar cell, LED, and FET; conventional paints; supercapacitor; battery; electronic paper; anti-static coating; transparent conductor; sensors; anti-microbial coating; adhesive; RFID; or memory system.
摘要翻译： 本发明的实施方案涉及通过从水溶液中沉积离子CP并将离子CP转化为不溶性CP来形成不溶性共轭聚合物（CP）的膜的方法。 离子CP可以是羧酸，磺酸，膦酸，硼酸，胺，亚胺，膦，硫醚或络合的二齿或多齿配体的盐。 不溶性CP膜可以与电解质溶液一起使用，用作电致变色膜; 用于太阳能电池，LED和FET的电荷注入层; 常规油漆; 超级电容器 电池; 电子纸; 防静电涂料; 透明导体 传感器; 抗微生物涂层; 胶粘剂; RFID; 或内存系统。
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公开(公告)号：US20130334520A1
公开(公告)日：2013-12-19
申请号：US14001787
申请日：2012-02-27
申请人： Chad Martin Amb , Franky So , John R. Reynolds
发明人： Chad Martin Amb , Franky So , John R. Reynolds
IPC分类号： H01L51/00
CPC分类号： H01L51/0036 , C07F7/30 , C08G61/123 , C08G61/126 , C08G2261/124 , C08G2261/3243 , C08G2261/344 , C08G2261/414 , C08G2261/91 , H01L51/0043 , H01L51/0071 , Y02E10/52 , Y02E10/542 , Y02E10/549
摘要： Embodiments of the invention are directed to Ge comprising heterocyclic compounds which can be used for the preparation of homopolymers and copolymers. The copolymers can be donor-acceptor (DA) alternating copolymers where the donor unit is a Ge comprising heterocyclic unit. The polymers can be used as materials in solar cells and other photovoltaic devices, transistors, diodes, light emitting devices (LEDs), conductors, supercapacitors, batteries, and electrochromic devices.
摘要翻译： 本发明的实施方案涉及包含可用于制备均聚物和共聚物的杂环化合物的Ge。 共聚物可以是供体 - 受体（DA）交替共聚物，其中供体单元是包含杂环单元的Ge。 聚合物可以用作太阳能电池和其他光伏器件，晶体管，二极管，发光器件（LED），导体，超级电容器，电池和电致变色器件中的材料。
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