公开(公告)号：US20100331165A1

公开(公告)日：2010-12-30

申请号：US12438608

申请日：2006-12-08

申请人： Jong-Ho Lee ,  Hae-Weon Lee ,  Joo-Sun Kim ,  Hue-Sup Song ,  Ji-Won Son ,  Hae-Ryoung Kim ,  Sung-Moon Kim ,  Hyoung-Chul Kim ,  Hwa-Young Jung

发明人： Jong-Ho Lee ,  Hae-Weon Lee ,  Joo-Sun Kim ,  Hue-Sup Song ,  Ji-Won Son ,  Hae-Ryoung Kim ,  Sung-Moon Kim ,  Hyoung-Chul Kim ,  Hwa-Young Jung

IPC分类号： C03C14/00

CPC分类号： H01M8/0282 ,  C03C8/14 ,  C03C8/18 ,  C03C8/24 ,  H01M8/0286 ,  H01M8/2425 ,  H01M8/2432 ,  H01M2008/1293

摘要： A composite sealant of the present invention increases a fracture toughness of glass which has an excellent gas tightness but has a low fracture resistance, to enhance the thermal cycle stability while maintaining the gas tightness of a stack. For this, alpha-alumina fiber particles, alpha-alumina granular particles, and metallic particles are mixed and added to a glass matrix for remarkably increasing the fracture toughness from 0.5 MPa·m05 to 6 MPa·m°'5 through the multiple effects of crack deflection and crack bridging by the fiber and granular particles, and effects of crack arresting and plastic deformation by the metallic particles. When using the high fracture toughness composite sealant of the present invention, since the gas tightness and the stability of the stack can be maintained even when there is a thermal stress produced by a non-uniform temperature distribution or a thermal cycle condition in the stack, increasing the fracture toughness of the composite sealant works as the most important factor for enhancing the reliability of a large-area stack.

摘要翻译： 本发明的复合密封剂提高了具有优异的气密性但具有低抗断裂性的玻璃的断裂韧性，以提高热循环的稳定性，同时保持了叠层的气密性。 为此，将α-氧化铝纤维颗粒，α-氧化铝颗粒和金属颗粒混合并加入到玻璃基质中，通过多种效应将断裂韧性从0.5MPa·m05显着提高到6MPa·m·5 由纤维和颗粒颗粒引起的裂纹弯曲和裂纹桥接，以及金属颗粒的裂纹阻滞和塑性变形的影响。 当使用本发明的高断裂韧性复合密封剂时，即使当堆叠中存在由不均匀的温度分布或热循环条件产生的热应力时，由于能够保持气密性和堆叠的稳定性， 提高复合密封胶的断裂韧性是提高大面积叠层可靠性的最重要因素。

公开(公告)号：US20100285394A1

公开(公告)日：2010-11-11

申请号：US12438619

申请日：2006-12-08

申请人： Jong-Ho Lee ,  Hae-Weon Lee ,  Joo-Sun Kim ,  Hue-Sup Song ,  Ji-Won Son ,  Hae-Ryoung Kim ,  Sung-Moon Kim ,  Hyoung-Chul Kim ,  Hwa-Young Jung

发明人： Jong-Ho Lee ,  Hae-Weon Lee ,  Joo-Sun Kim ,  Hue-Sup Song ,  Ji-Won Son ,  Hae-Ryoung Kim ,  Sung-Moon Kim ,  Hyoung-Chul Kim ,  Hwa-Young Jung

IPC分类号： H01M2/08

CPC分类号： H01M8/0282

摘要： The present invention provides a hybrid composite sealant, as a sealing material for a planar type solid oxide fuel cell stack, having a matrix of a glass composition, wherein a surface layer reinforced with platelet reinforcement particles is laminated on either one or both surfaces of an inner layer reinforced with fibrous reinforcement particles. Accordingly, by applying the composite sealant of the present invention to the solid oxide fuel cell stack, excellent gas-tightness of the stack can be obtained even under low coupling pressure, thermal cycling durability can be enhanced due to low coupling strength with a contact surface of an object to be sealed, stack disassembly and maintenance can be facilitated when parts within the stack are disabled, and stack stability as well as stack performance can be maintained under a pressurized operation condition where pressure differentials between the inside and outside of the stack reach to 5 atmospheric pressures (0.5 MPa).

摘要翻译： 本发明提供一种作为平面型固体氧化物燃料电池堆的密封材料的混合复合密封剂，其具有玻璃组合物的基体，其中用片状增强颗粒增强的表面层层叠在一个或两个表面上 内层用纤维增强颗粒增强。 因此，通过将本发明的复合密封剂应用于固体氧化物型燃料电池组，即使在低耦合压力下也能获得优异的气密性，因为与接触面的低耦合强度可以提高热循环耐久性 当堆中的部件被禁用时，可以方便地进行堆封拆卸和维护，堆叠的稳定性以及堆叠性能可以在叠层内外的压差达到的加压运行状态下保持 至5个大气压（0.5MPa）。

公开(公告)号：US20070077476A1

公开(公告)日：2007-04-05

申请号：US11529212

申请日：2006-09-29

申请人： Hae-Weon Lee ,  Jong-Ho Lee ,  Joo-Sun Kim ,  Ji-Won Son ,  Hue-Sup Song ,  Hyoung-Chul Kim ,  Hwa-Young Jung

发明人： Hae-Weon Lee ,  Jong-Ho Lee ,  Joo-Sun Kim ,  Ji-Won Son ,  Hue-Sup Song ,  Hyoung-Chul Kim ,  Hwa-Young Jung

IPC分类号： H01M8/12 ,  C04B35/64

CPC分类号： H01M4/9066 ,  H01M4/8621 ,  H01M4/8885 ,  H01M8/1213 ,  H01M8/1226 ,  H01M8/124 ,  Y02P70/56

摘要： The present invention discloses a paste for screen printing which is used in a process of fabricating an anode functional layer, an electrolyte layer and a cathode layer of an anode-supported solid oxide fuel cell. The paste for the solid oxide fuel cell contains raw material powder of each layer, ethyl cellulose which is a binder, alpha terpineol which is a solvent, and an alcoholic solvent which has solubility to a thermosetting binder contained in an anode support and which is added by 0.5 to 20 wt % of alpha terpineol as an additional solvent. The present invention also discloses a fabricating method of an anode-supported solid oxide fuel cell which forms each layer of the fuel cell by screen printing by using the paste. According to the present invention, in the highly efficient pore structure anode support fabricated by thermosetting molding, the composition of the paste for screen printing is controlled to improve weftability, and the movement of the elements is restricted by curing, thereby reducing surface defects of the layers and interfacial defects between the layers in fabrication and improving the interface strength. As a result, the high performance large area solid oxide fuel cell can be economically and efficiently fabricated, and reliability of the product can be remarkably improved.

摘要翻译： 本发明公开了一种丝网印刷用糊剂，其用于制造阳极支撑固体氧化物型燃料电池的阳极功能层，电解质层和阴极层的工序。 固体氧化物型燃料电池用糊剂含有各层的原料粉末，作为粘合剂的乙基纤维素，作为溶剂的α-萜品醇和对阳极载体中含有的热固性粘合剂具有溶解性的醇溶剂， 作为另外的溶剂使用0.5〜20重量％的萜品醇。 本发明还公开了一种阳极支撑的固体氧化物燃料电池的制造方法，其通过使用该糊状物的丝网印刷形成燃料电池的各层。 根据本发明，在通过热固性成型制造的高效率孔结构阳极支撑体中，控制用于丝网印刷的糊剂的组成以改善纬向性，并且元件的移动受到固化的限制，从而减少了 层和界面缺陷在制造和提高界面强度。 结果，可以经济高效地制造高性能大面积固体氧化物燃料电池，可以显着提高产品的可靠性。

公开(公告)号：US08802324B2

公开(公告)日：2014-08-12

申请号：US12438619

申请日：2006-12-08

申请人： Jong-Ho Lee ,  Hae-Weon Lee ,  Joo-Sun Kim ,  Hue-Sup Song ,  Ji-Won Son ,  Hae-Ryoung Kim ,  Sung-Moon Kim ,  Hyoung-Chul Kim ,  Hwa-Young Jung

发明人： Jong-Ho Lee ,  Hae-Weon Lee ,  Joo-Sun Kim ,  Hue-Sup Song ,  Ji-Won Son ,  Hae-Ryoung Kim ,  Sung-Moon Kim ,  Hyoung-Chul Kim ,  Hwa-Young Jung

IPC分类号： H01M2/08

CPC分类号： H01M8/0282

摘要： The present invention provides a hybrid composite sealant, as a sealing material for a planar type solid oxide fuel cell stack, having a matrix of a glass composition, wherein a surface layer reinforced with platelet reinforcement particles is laminated on either one or both surfaces of an inner layer reinforced with fibrous reinforcement particles. Accordingly, by applying the composite sealant of the present invention to the solid oxide fuel cell stack, excellent gas-tightness of the stack can be obtained even under low coupling pressure, thermal cycling durability can be enhanced due to low coupling strength with a contact surface of an object to be sealed, stack disassembly and maintenance can be facilitated when parts within the stack are disabled, and stack stability as well as stack performance can be maintained under a pressurized operation condition where pressure differentials between the inside and outside of the stack reach to 5 atmospheric pressures (0.5 MPa).

摘要翻译： 本发明提供一种作为平面型固体氧化物燃料电池堆的密封材料的混合复合密封剂，其具有玻璃组合物的基体，其中用片状增强颗粒增强的表面层层叠在一个或两个表面上 内层用纤维增强颗粒增强。 因此，通过将本发明的复合密封剂应用于固体氧化物型燃料电池组，即使在低耦合压力下也能获得优异的气密性，因为与接触面的低耦合强度可以提高热循环耐久性 当堆中的部件被禁用时，可以方便地进行堆封拆卸和维护，堆叠的稳定性以及堆叠性能可以在叠层内外的压差达到的加压运行状态下保持 至5个大气压（0.5MPa）。

公开(公告)号：US07887976B2

公开(公告)日：2011-02-15

申请号：US11529212

申请日：2006-09-29

申请人： Hae-Weon Lee ,  Jong-Ho Lee ,  Joo-Sun Kim ,  Ji-Won Son ,  Hue-Sup Song ,  Hyoung-Chul Kim ,  Hwa-Young Jung

发明人： Hae-Weon Lee ,  Jong-Ho Lee ,  Joo-Sun Kim ,  Ji-Won Son ,  Hue-Sup Song ,  Hyoung-Chul Kim ,  Hwa-Young Jung

IPC分类号： H01M4/02 ,  H01M4/64 ,  H01M8/10

CPC分类号： H01M4/9066 ,  H01M4/8621 ,  H01M4/8885 ,  H01M8/1213 ,  H01M8/1226 ,  H01M8/124 ,  Y02P70/56

摘要： Disclosed is a paste for screen printing which is used in the fabrication of an anode functional layer, an electrolyte layer, or a cathode layer of an anode-supported solid oxide fuel cell. The paste contains a raw material powder, ethyl cellulose alpha terpineol, and an alcoholic solvent in which a thermosetting binder is soluble. Also provided is a method of fabricating an anode-supported solid oxide fuel cell using the paste. Thus, a reliable high-performance, large area solid oxide fuel cell that can be economically and efficiently fabricated is provided.

摘要翻译： 公开了一种丝网印刷用糊剂，其用于阳极支撑固体氧化物燃料电池的阳极功能层，电解质层或阴极层的制造。 该糊状物含有原料粉末，乙基纤维素萜品醇和可溶于热固性粘合剂的醇溶剂。 还提供了使用该糊料制造负极固体氧化物燃料电池的方法。 因此，提供了可以经济有效地制造的可靠的高性能，大面积的固体氧化物燃料电池。

公开(公告)号：US20070015045A1

公开(公告)日：2007-01-18

申请号：US11521478

申请日：2006-09-15

申请人： Jong-Ho Lee ,  Hae-Weon Lee ,  Joo-Sun Kim ,  Ji-Won Son ,  Hue-Sup Song ,  Hyoung-Chul Kim ,  Hwa-Young Jung

发明人： Jong-Ho Lee ,  Hae-Weon Lee ,  Joo-Sun Kim ,  Ji-Won Son ,  Hue-Sup Song ,  Hyoung-Chul Kim ,  Hwa-Young Jung

IPC分类号： H01M4/86

CPC分类号： H01M8/1226 ,  H01M4/0471 ,  H01M4/8605 ,  H01M4/8621 ,  H01M4/8652 ,  H01M4/8885 ,  H01M4/9016 ,  H01M4/9033 ,  H01M4/9066 ,  H01M8/1213 ,  H01M8/1246 ,  H01M8/1253 ,  H01M8/126 ,  Y02E60/525 ,  Y02P70/56

摘要： Disclosed is an anode supporter for a solid oxide fuel cell (SOFC). The SOFC comprises an anode supporter having a high gas permeability, a high electrical conductivity, a high electrochemical activity, a high mechanical strength, and a large area; an anode functional layer for attenuating a surface defect of the anode supporter and maximizing an electrochemical activity of the anode; an electrolyte having a ultra-thin film; a cathode functional layer for removing an interface reaction between the electrolyte and the cathode and enhancing an electrochemical reaction at the cathode; a cathode having an excellent interface bonding characteristic with the cathode functional layer and a high electrical conductivity; and a current collect layer for maximizing an electrical connection between the cathode and a separator or interconnector. Accordingly, a performance of the single cell of a large area is enhanced.

摘要翻译： 公开了一种固体氧化物燃料电池（SOFC）的阳极支撑体。 SOFC包括具有高透气性，高导电性，高电化学活性，高机械强度和大面积的阳极支撑体; 阳极功能层，用于衰减阳极支撑体的表面缺陷并使阳极的电化学活性最大化; 具有超薄膜的电解质; 阴极功能层，用于去除电解质和阴极之间的界面反应并增强阴极处的电化学反应; 与阴极功能层具有优异的界面结合特性和高导电性的阴极; 以及用于最大化阴极和分离器或互连器之间的电连接的电流收集层。 因此，提高了大面积的单电池的性能。