公开(公告)号：US20100116639A1

公开(公告)日：2010-05-13

申请号：US12593252

申请日：2008-04-11

申请人： Jong-Ho Park ,  Jong-Nam Kim ,  Seong-Jun Lee ,  Min-Su Ko ,  Hee Tae Beum ,  Jongkee Park ,  Chang Hyun Ko ,  Sang Sup Han ,  Soon-Haeng Cho

发明人： Jong-Ho Park ,  Jong-Nam Kim ,  Seong-Jun Lee ,  Min-Su Ko ,  Hee Tae Beum ,  Jongkee Park ,  Chang Hyun Ko ,  Sang Sup Han ,  Soon-Haeng Cho

IPC分类号： B01D3/00

CPC分类号： C07C7/12 ,  B01D3/143 ,  B01D53/04 ,  B01D2253/108 ,  B01D2256/24 ,  B01D2257/7022 ,  B01D2259/40086 ,  B01D2259/403 ,  C07C7/005 ,  C07C7/04 ,  C07C7/13 ,  C07C11/08

摘要： The present invention relates to a hybrid process comprising an adsorption process and a distillation process for the separation of butene-1 from a C4 hydrocarbon mixture gas including butene-1, trans-2-butene, cis-2-butene, normal butane, isobutane, etc. The above hybrid process comprises introducing a gaseous C4 mixture into the adsorption tower loaded with adsorbents which adsorb olefins selectively to discharge C4 paraffins to the outlet of the tower, desorbing C4 olefins selectively adsorbed in the adsorption tower to produce high purity C4 olefins mixture gas in which isobutane and normal butane was removed, and separating the high C4 olefins mixture gas (a mixture of butene-1, trans-2-butene, cis-2-butene, and a trace amount of C4 paraffins) via distillation to obtain high purity butene-1 including a trace amount of isobutane in the top of the distillation tower and obtain a mixture gas including trans-2-butene, cis-2-butene and a trace amount of normal butane in the bottom of the tower.

摘要翻译： 本发明涉及一种混合方法，其包括吸附过程和用于从包含丁烯-1，反式-2-丁烯，顺式-2-丁烯，正丁烷，异丁烷的C 4烃混合气体中分离丁烯-1的蒸馏方法 等等。上述混合方法包括将气态C 4混合物引入到负载有吸附剂的吸附塔中，所述吸附剂选择性吸附烯烃以将C4链烷烃排出到塔的出口，解吸选择性吸附在吸附塔中的C4烯烃以产生高纯度C4烯烃 除去异丁烷和正丁烷的混合气体，通过蒸馏将高C4烯烃混合气体（丁烯-1，反式-2-丁烯，顺式-2-丁烯和痕量的C4链烷烃的混合物）分离成 在蒸馏塔顶部得到含有痕量异丁烷的高纯度丁烯-1，得到底部的反式-2-丁烯，顺式-2-丁烯和痕量正丁烷的混合气体 他塔。

公开(公告)号：US08436223B2

公开(公告)日：2013-05-07

申请号：US12593249

申请日：2008-03-28

申请人： Jong-Nam Kim ,  Jong-Ho Park ,  Seong-Jun Lee ,  Min-Su Ko ,  Hee Tae Beum ,  Jongkee Park ,  Chang Hyun Ko ,  Sang Sup Han ,  Soon-Haeng Cho

发明人： Jong-Nam Kim ,  Jong-Ho Park ,  Seong-Jun Lee ,  Min-Su Ko ,  Hee Tae Beum ,  Jongkee Park ,  Chang Hyun Ko ,  Sang Sup Han ,  Soon-Haeng Cho

IPC分类号： C07C7/12

CPC分类号： B01D53/047 ,  B01D2256/24 ,  B01D2257/7022 ,  B01D2259/40054 ,  B01D2259/4006 ,  B01D2259/40062 ,  B01D2259/40067 ,  B01D2259/403 ,  C07C7/13 ,  C07C11/08

摘要： The present invention relates to a method for the separation of C4 olefins and C4 paraffins from a C4 hydrocarbon mixed gas including butene-1, trans-2- butene, cis-2-butene, normal butane, isobutane, etc. The method of the present invention produces C4 olefins with high purity by introducing a gaseous C4 mixture into the adsorption tower loaded with adsorbent selectively adsorbing olefins to adsorb C4 olefins and to discharge C4 paraffins to the outlet of the tower, desorbing C4 olefins adsorbed on the adsorption tower with a desorbent C5 hydrocarbon, C6 hydrocarbon, etc.), and then separating the C4 olefin and the desorbent by a distillation process.

摘要翻译： 本发明涉及一种从包括丁烯-1，反式-2-丁烯，顺式-2-丁烯，正丁烷，异丁烷等的C4烃混合气体中分离C4烯烃和C4链烷烃的方法。 本发明通过将气态C 4混合物引入负载有选择性吸附烯烃以吸附C4烯烃并将C4链烷烃排出到塔的出口的吸附塔中，通过引入吸附塔上的C4烯烃来解吸附在吸附塔上的C4烯烃来生产高纯度的C4烯烃 解吸C5烃，C6烃等），然后通过蒸馏方法分离C4烯烃和解吸剂。

公开(公告)号：US08431762B2

公开(公告)日：2013-04-30

申请号：US12593252

申请日：2008-04-11

申请人： Jong-Ho Park ,  Jong-Nam Kim ,  Seong-Jun Lee ,  Min-Su Ko ,  Hee Tae Beum ,  Jongkee Park ,  Chang Hyun Ko ,  Sang Sup Han ,  Soon-Haeng Cho

发明人： Jong-Ho Park ,  Jong-Nam Kim ,  Seong-Jun Lee ,  Min-Su Ko ,  Hee Tae Beum ,  Jongkee Park ,  Chang Hyun Ko ,  Sang Sup Han ,  Soon-Haeng Cho

IPC分类号： C07C7/12

CPC分类号： C07C7/12 ,  B01D3/143 ,  B01D53/04 ,  B01D2253/108 ,  B01D2256/24 ,  B01D2257/7022 ,  B01D2259/40086 ,  B01D2259/403 ,  C07C7/005 ,  C07C7/04 ,  C07C7/13 ,  C07C11/08

摘要： The present invention relates to a hybrid process comprising an adsorption process and a distillation process for the separation of butene-1 from a C4 hydrocarbon mixture gas including butene-1, trans-2-butene, cis-2-butene, normal butane, isobutane, etc. The above hybrid process comprises introducing a gaseous C4 mixture into the adsorption tower loaded with adsorbents which adsorb olefins selectively to discharge C4 paraffins to the outlet of the tower, desorbing C4 olefins selectively adsorbed in the adsorption tower to produce high purity C4 olefins mixture gas in which isobutane and normal butane was removed, and separating the high C4 olefins mixture gas (a mixture of butene-1, trans-2-butene, cis-2-butene, and a trace amount of C4 paraffins) via distillation to obtain high purity butene-1 including a trace amount of isobutane in the top of the distillation tower and obtain a mixture gas including trans-2-butene, cis-2-butene and a trace amount of normal butane in the bottom of the tower.

摘要翻译： 本发明涉及一种混合方法，其包括吸附过程和用于从包含丁烯-1，反式-2-丁烯，顺式-2-丁烯，正丁烷，异丁烷的C 4烃混合气体中分离丁烯-1的蒸馏方法 等等。上述混合方法包括将气态C 4混合物引入到负载有吸附剂的吸附塔中，所述吸附剂选择性吸附烯烃以将C4链烷烃排出到塔的出口，解吸选择性吸附在吸附塔中的C4烯烃以产生高纯度C4烯烃 除去异丁烷和正丁烷的混合气体，通过蒸馏将高C4烯烃混合气体（丁烯-1，反式-2-丁烯，顺式-2-丁烯和痕量的C4链烷烃的混合物）分离成 在蒸馏塔顶部得到含有痕量异丁烷的高纯度丁烯-1，得到底部的反式-2-丁烯，顺式-2-丁烯和痕量正丁烷的混合气体 他塔。

公开(公告)号：US20100048971A1

公开(公告)日：2010-02-25

申请号：US12593249

申请日：2008-03-28

申请人： Jong-Nam Kim ,  Jong-Ho Park ,  Seong-Jun Lee ,  Min-Su Ko ,  Hee Tae Beum ,  Jongkee Park ,  Chang Hyun Ko ,  Sang Sup Han ,  Soon-Haeng Cho

发明人： Jong-Nam Kim ,  Jong-Ho Park ,  Seong-Jun Lee ,  Min-Su Ko ,  Hee Tae Beum ,  Jongkee Park ,  Chang Hyun Ko ,  Sang Sup Han ,  Soon-Haeng Cho

IPC分类号： C07C7/04 ,  C07C7/11

CPC分类号： B01D53/047 ,  B01D2256/24 ,  B01D2257/7022 ,  B01D2259/40054 ,  B01D2259/4006 ,  B01D2259/40062 ,  B01D2259/40067 ,  B01D2259/403 ,  C07C7/13 ,  C07C11/08

摘要： The present invention relates to a method and an apparatus for the separation of C4 olefins (butene-1, trans-2-butene, cis-2-butene, etc.) and C4 paraffins (normal butane, isobutane, etc.) from a C4 hydrocarbon mixed gas including butene-1, trans-2-butene, cis-2-butene, normal butane, isobutane, etc. The method of the present invention produces C4 olefins with high purity by introducing a gaseous C4 mixture into the adsorption tower loaded with adsorbent selectively adsorbing olefins to adsorb C4 olefins and to discharge C4 paraffins to the outlet of the tower, desorbing C4 olefins adsorbed on the adsorption tower with a desorbent (C5 hydrocarbon, C6 hydrocarbon, etc.), and then separating the C4 olefin and the desorbent by a distillation process. The apparatus of the present invention is composed of several adsorption towers loaded with an adsorbent which selectively adsorb olefins and two distillation towers for the separation of the mixture gases of olefins/desorbents and paraffins/desorbents respectively, The basic operating process of the adsorption tower comprises a adsorption step of selectively adsorbing C4 olefin from the feeding mixture, a C4 olefin rinse step of removing a small amount of C4 paraffins adsorbed together with C4 olefins, and a desorption step of desorbing C4 olefins by using a desorbent, and further comprises a pressure equalization step, a cocurrent depressurization step, and a accumulation pressure step in order to increase the yield and concentration of olefins depending on the operation pressure of the adsorption tower. The desorbent discharged from the process together with olefins or paraffins is separated in the distillation tower and then recycled.

摘要翻译： 本发明涉及一种用于分离C4烯烃（丁烯-1，反式-2-丁烯，顺-2-丁烯等）和C4链烷烃（正丁烷，异丁烷等）的方法和装置， 包括丁烯-1，反式-2-丁烯，顺式-2-丁烯，正丁烷，异丁烷等的C4烃混合气体。本发明的方法通过将气态C 4混合物引入吸附塔中来生产高纯度的C4烯烃 负载吸附剂选择性吸附烯烃以吸附C4烯烃并将C4链烷烃排出到塔的出口，用解吸剂（C5烃，C6烃等）解吸吸附在吸附塔上的C4烯烃，然后分离C4烯烃 和通过蒸馏方法的解吸剂。 本发明的装置由多个吸附塔组成，吸附塔分别选择性地吸附烯烃和两个蒸馏塔，用于分离烯烃/脱附剂和石蜡/脱附剂的混合气体。吸附塔的基本操作过程包括 从进料混合物中选择性吸附C4烯烃的吸附步骤，除去少量与C4烯烃一起吸附的C4链烷烃的C4烯烃漂洗步骤，以及通过使用脱附剂解吸C4烯烃的解吸步骤，还包括压力 平衡步骤，并流减压步骤和累积压力步骤，以根据吸附塔的操作压力提高烯烃的产率和浓度。 从该方法中排出的解吸剂与烯烃或链烷烃一起在蒸馏塔中分离，然后再循环。