摘要:
The invention provides an improved process for the preparation of double metal cyanide (DMC) catalysts for the preparation of polyether polyols by polyaddition of alkylene oxides on to starter compounds containing active hydrogen atoms, in which aqueous solutions of a metal salt and a metal cyanide salt are first reacted in the presence of an organic complexing ligand and optionally one or more further complex-forming components to form a DMC catalyst dispersion, this dispersion is then filtered, the filter cake is subsequently washed with one or more aqueous or non-aqueous solutions of the organic complexing ligand and optionally one or more further complex-forming components by a filter cake washing and the washed filter cake is finally dried, after an optional pressing out or mechanical removal of moisture.
摘要:
The invention relates to novel zinc/metal hexacyanocobaltate complex compounds corresponding to the formula:Zn.sub.3-v M.sub.v [Co(CN).sub.6 ].sub.2.w(H.sub.2 O).x(L).y[Zn(X).sub.n ].z[M(Y).sub.m)].These complex compounds are suitable catalysts. This invention also relates to a process for the production of the compounds, and to the use of the compounds in a process for the production of polyether polyols.These novel zinc/metal hexacyanocobaltate complex compounds when used as catalysts in a process for the production of polyether polyols substantially reduce the induction period of the polyaddition reaction of alkylene oxides to starter compounds containing hydrogen atoms. Furthermore, the resultant polyether polyols have a significantly narrower molecular weight distribution.
摘要:
The invention relates to a method of welding weld studs to a workpiece, in particular of aluminum in each case, by the stroke ignition method, in which the stroke height(s) of the weld stud (1) is altered as a function of the measured arc voltage and optionally of the arc firing time. In particular, the stroke height(s) of the stud (1) can be increased during the occurrence of short circuits, i.e. during a sudden drop in the arc voltage, preferably in predetermined steps. The weld stud is immersed into a pool of melt after a predetermined period of time of between 5 and 10 ms after the welding current has been switched off. The polarity of the stud or of the workpiece is changed at least once during the welding process. The welding current is interrupted for a predetermined period of time for this purpose. The method leads to an improved, readily reproducible quality of weld.
摘要:
The present invention provides a process for conditioning double metal cyaide (DMC) catalysts, which are employed in the preparation of polyether polyols based on starter compounds having active hydrogen atoms, the preparation of polyether polyols using the conditioned catalysts and the use of the polyether polyols prepared in this way for the preparation of polyurethane materials.
摘要:
The invention is directed to novel poly(ether-ester)polyols, processes for their production from monocarboxylic or polycarboxylic acid esters with one or more bound polyether chain(s). This invention also relates to the production of polyurethane materials in which the isocyanate-reactive component comprises these poly(ether-ester)polyols.
摘要:
An ordering means for document files or the like comprises a base plate which is provided with at least two fixed ordering pins. At least one movable closure bow can be brought into closure contact with the ordering pins. Possibly a holder-down is provided which is adapted to be clamped with respect to the ordering pins. A locking member displaceable with respect to the base plate serves to adjust the closure bow or bows and on the base plate guide means are provided for guiding the locking member. The locking member is provided with guide slots or guide grooves via which the locking member is in engagement with each closure bow so that on displacement of the locking member the respective closure bow can be opened or closed.
摘要:
The present invention provides a process for conditioning double metal cyanide (DMC) catalysts, which are employed in the preparation of polyether polyols based on starter compounds having active hydrogen atoms, the preparation of polyether polyols using the conditioned catalysts and the use of the polyether polyols prepared in this way for the preparation of polyurethane materials.
摘要:
The invention is directed to novel poly(ether-ester)polyols, processes for their production from monocarboxylic or polycarboxylic acid esters with one or more bound polyether chain(s). This invention also relates to the production of polyurethane materials in which the isocyanate-reactive component comprises these poly(ether-ester)polyols.
摘要:
The present invention provides a process for conditioning double metal cyanide (DMC) catalysts, which are employed in the preparation of polyether polyols based on starter compounds having active hydrogen atoms, the preparation of polyether polyols using the conditioned catalysts and the use of the polyether polyols prepared in this way for the preparation of polyurethane materials.
摘要:
The invention relates to a quick set-up system for calibration devices located downstream from an extruder, in particular one for synthetic profiles. With this quick set-up system, a dry gauge and the vacuum tank(s) are mounted on two horizontally positioned tubes that are positively connected to the calibration stage, such that they can be moved and adjusted horizontally and vertically, which enables an exact advance adjustment of the gliding device, and with it, of the vacuum tanks and calibration device, thus eliminating a subsequent alignment. In addition, by installing a central water disposal system, the required replacement of hoses with different lengths when moving the vacuum tanks is avoided.