公开(公告)号：US4339620A

公开(公告)日：1982-07-13

申请号：US239806

申请日：1981-03-02

申请人： Joseph A. Cowfer ,  Jamal S. Eden ,  Angelo J. Magistro

发明人： Joseph A. Cowfer ,  Jamal S. Eden ,  Angelo J. Magistro

IPC分类号： B01J23/72 ,  C07C17/156 ,  C07C17/15

CPC分类号： B01J23/72 ,  C07C17/156

摘要： There is disclosed a method and composition for improving the fluidization characteristics and alleviating or inhibiting stickiness in a supported cupric chloride catalyst used as fluid bed catalyst in oxyhydrochlorinations reactions. The method involves the in situ preparation of the supported cupric chloride catalyst by addition of bare support on which no cupric chloride is deposited to the supported cupric chloride catalyst in the fluidized bed, or the use in the bed as the initial charge or as addition to the bed as makeup, of a composition which is a mixture of supported cupric chloride catalyst and bare support. In either event, as the oxyhydrochlorination proceeds, a portion of the cupric chloride on the supported catalyst becomes released therefrom and deposited in situ on the bare support, and stickiness of the cupric chloride containing catalyst particles to one another in the fluid bed is alleviated or inhibited.

摘要翻译： 公开了一种改善流化特性并减轻或抑制用于羟基氢氯化反应中作为流化床催化剂的负载型氯化铜催化剂中的粘性的方法和组合物。 该方法包括通过添加裸式载体来原位制备负载的氯化铜催化剂，其上没有将氯化铜沉积在流化床中的负载的氯化铜催化剂上，或者在床中用作初始电荷或作为添加 作为化妆品的床，作为负载的氯化铜催化剂和裸支撑物的混合物的组合物。 在任一情况下，随着氧化氢氯化的进行，载体催化剂上的一部分氯化铜被释放出来，并在裸露的载体上原位沉积，并且在流化床中彼此含有氯化铜的催化剂颗粒的粘性得到缓解或 抑制。

公开(公告)号：US4849393A

公开(公告)日：1989-07-18

申请号：US140272

申请日：1987-12-31

申请人： Jamal S. Eden ,  Joseph A. Cowfer

发明人： Jamal S. Eden ,  Joseph A. Cowfer

IPC分类号： B01J23/78 ,  B01J27/10 ,  C07C17/156

CPC分类号： B01J27/10 ,  B01J23/78 ,  C07C17/156

摘要： A fluidizable catalyst composition is provided containing about 2% to about 8% by weight of copper (about 4% to about 17% by weight of copper salt), from about 1.0% to about 10% by weight of a rare earth metal salt(s), preferably the chloride salt(s), and from about 0.25% to about 2.3% by weight of an alkali metal salt(s), preferably the chloride salt(s), all weight percents based upon the total weight of the catalyst composition. The metals are codeposited on a fluidizable, high surface area alumina support. The weight of the alkali metal employed is not over 2.5% by weight (as the chloride) and the weight ratio of the rare earth metal salt(s) to the alkali metal salt(s) must be at least 1:1. Such catalyst compositions are extremely useful as fluid bed catalysts in the vapor phase oxychlorination reaction of ethylene, oxygen and hydrogen chloride to produce 1,2-dichloroethane (EDC). The use of the catalysts results in improved, high percent ethylene efficiencies and high percent HCl conversions, and avoids operating problems caused by stickiness of the catalyst in the fluid bed. A combination of copper chloride, potassium chloride and one or more of the rare earth chlorides on a fluidizable gamma alumina support, produces an excellent catalyst for a fluid bed ethylene oxychlorination process.

摘要翻译： 提供了一种可流化催化剂组合物，其含有约2％至约8％重量的铜（约4％至约17％重量的铜盐），约1.0％至约10％重量的稀土金属盐（ s），优选氯化物盐，和约0.25重量％至约2.3重量％的碱金属盐，优选氯化物盐，基于催化剂的总重量，所有重量百分比 组成。 金属共沉积在可流化的高表面积氧化铝载体上。 所用碱金属的重量不超过2.5重量％（作为氯化物），稀土金属盐与碱金属盐的重量比必须至少为1:1。 这种催化剂组合物在乙烯，氧气和氯化氢的气相氧氯化反应中作为流化床催化剂非常有用，以产生1,2-二氯乙烷（EDC）。 催化剂的使用导致乙烯效率提高，乙烯转化率高，HCl转化率高，避免了催化剂在流化床中的粘性引起的操作问题。 在可流化的γ氧化铝载体上，氯化铜，氯化钾和一种或多种稀土氯化物的组合产生用于流化床乙烯氧氯化方法的优异催化剂。

公开(公告)号：US4740642A

公开(公告)日：1988-04-26

申请号：US898566

申请日：1986-08-21

申请人： Jamal S. Eden ,  Joseph A. Cowfer

发明人： Jamal S. Eden ,  Joseph A. Cowfer

IPC分类号： B01J23/78 ,  B01J27/10 ,  B01J27/122 ,  C07B61/00 ,  C07C17/00 ,  C07C17/156 ,  C07C19/045 ,  C07C67/00 ,  C07C17/02

CPC分类号： B01J27/10 ,  B01J23/78 ,  C07C17/156

摘要： A fluidizable catalyst composition is provided containing about 2% to about 8% by weight of copper (about 4% to about 17% by weight of copper salt), from about 0.2% to about 10% by weight of a rare earth metal salt(s), preferably the chloride salt(s), and from about 0.25% to about 2.3% by weight of an alkali metal salt(s), preferably the chloride salt(s), all weight percents based upon the total weight of the catalyst composition. The metals are codeposited on a fluidizable, high surface area alumina support. The weight of the alkali metal employed is not over 2.5% by weight (as the chloride) and the weight ratio of the rare earth metal salt(s) to the alkali metal salt(s) must be at least 0.8:1. Such catalyst compositions are extremely useful as fluid bed catalysts in the vapor phase oxychlorination reaction of ethylene, oxygen and hydrogen chloride to produce 1,2-dichloroethane (EDC). The use of the catalysts results in improved, high percent ethylene efficiencies and high percent HCl conversions, and avoids operating problems caused by stickiness of the catalyst in the fluid bed. A combination of copper chloride, potassium chloride and one or more of the rare earth chlorides on a fluidizable gamma alumina support, produces an excellent catalyst for a fluid bed ethylene oxychlorination process.

摘要翻译： 提供了一种可流化的催化剂组合物，其含有约2％至约8％重量的铜（约4％至约17％重量的铜盐），约0.2％至约10％重量的稀土金属盐（ s），优选氯化物盐，和约0.25重量％至约2.3重量％的碱金属盐，优选氯化物盐，基于催化剂的总重量，所有重量百分比 组成。 金属共沉积在可流化的高表面积氧化铝载体上。 所使用的碱金属的重量不超过2.5重量％（作为氯化物），稀土金属盐与碱金属盐的重量比必须至少为0.8:1。 这种催化剂组合物在乙烯，氧气和氯化氢的气相氧氯化反应中作为流化床催化剂非常有用，以产生1,2-二氯乙烷（EDC）。 催化剂的使用导致乙烯效率提高，乙烯转化率高，HCl转化率高，避免了催化剂在流化床中的粘性引起的操作问题。 在可流化的γ氧化铝载体上，氯化铜，氯化钾和一种或多种稀土氯化物的组合产生用于流化床乙烯氧氯化方法的优异催化剂。

公开(公告)号：US4031149A

公开(公告)日：1977-06-21

申请号：US490513

申请日：1974-07-22

申请人： Jamal S. Eden

发明人： Jamal S. Eden

IPC分类号： B01D53/86 ,  B01J23/12 ,  B01J27/00 ,  C01B7/01 ,  C07C17/00 ,  C07C17/156 ,  C07C17/158 ,  C07C21/04 ,  C07C67/00 ,  C07C21/00

CPC分类号： C01B7/01 ,  B01J23/12 ,  C07C17/156

摘要： There is disclosed an improved method of making chlorinated derivatives of ethylene wherein chlorine-containing by-products are burned in a catalytic combustion reactor to produce primarily a hydrogen halide which is recycled to the chlorinated derivative reaction and the heat of combustion from said reactor is utilized to preheat the materials used in said chlorinated derivative reaction. The catalyst employed is one containing 5% to 20% of UO.sub.3 (uranium trioxide) on 80% to 95% Al.sub.2 O.sub.3, SiO.sub.2 or a combination of Al.sub.2 O.sub.3 and SiO.sub.2 as a support and having a surface area of at least 50 square meters per gram. The catalytic combustion reaction is carried out at temperatures in the range of about 350.degree. C. to about 450.degree. C. to produce a mixture of gases containing essentially hydrogen chloride and being substantially free of elemental chlorine and chlorohydrocarbon compounds, said gases being then mixed with ethylene and reacted to form ethylene dichloride (EDC).

摘要翻译： 公开了一种制备乙烯氯化衍生物的改进方法，其中含氯副产物在催化燃烧反应器中燃烧以产生主要的卤化氢，其被再循环至氯化衍生物反应，并利用来自所述反应器的燃烧热 以预热所述氯化衍生物反应中使用的材料。 所使用的催化剂是在80％至95％的Al 2 O 3，SiO 2或Al 2 O 3和SiO 2的组合作为载体并且具有至少50平方米/克的表面积的含有5％至20％的UO 3（三氧化铀）的催化剂。 催化燃烧反应在约350℃至约450℃的温度下进行，以产生基本上含有氯化氢并基本上不含元素氯和氯代烃化合物的气体混合物，然后将所述气体混合 与乙烯反应形成二氯乙烷（EDC）。

公开(公告)号：US4169862A

公开(公告)日：1979-10-02

申请号：US490391

申请日：1974-07-22

申请人： Jamal S. Eden

发明人： Jamal S. Eden

IPC分类号： B01D53/86 ,  B01D53/70 ,  B01J23/00 ,  C01B7/01 ,  C07C17/00 ,  C07C17/156 ,  C07C17/158 ,  C07C17/38 ,  C07C17/395 ,  C07C21/04 ,  C07C67/00 ,  C07C21/00

CPC分类号： C07C17/156 ,  C01B7/01 ,  C07C17/395

摘要： There is disclosed an improved method of making chlorinated derivatives of ethylene wherein chlorine-containing by-products are burned in a catalytic combustion reactor to produce primarily a hydrogen halide which is recycled to the chlorinated derivative reaction and the heat of combustion from said reactor is utilized to preheat the materials used in said chlorinated derivative reaction. The catalyst employed is one containing 0.01% to 0.50% of platinum or palladium on 99.99% to 99.50% Al.sub.2 O.sub.3, SiO.sub.2 or a combination of Al.sub.2 O.sub.3 and SiO.sub.2 as a support and having a surface area of at least 50 square meters per gram. The catalytic combustion reaction is carried out at temperatures in the range of about 300.degree. C. to about 450.degree. C. to produce a mixture of gases containing essentially hydrogen chloride and being substantially free of elemental chlorine and chlorohydrocarbon compounds, said gases being then mixed with ethylene and reacted to form ethylene dichloride (EDC).

公开(公告)号：US4185039A

公开(公告)日：1980-01-22

申请号：US972770

申请日：1978-12-26

申请人： Jamal S. Eden

发明人： Jamal S. Eden

IPC分类号： C01B32/50 ,  C07C17/00 ,  C07C17/156 ,  C07C19/045 ,  C07C67/00 ,  C07C21/00 ,  C07C11/00

CPC分类号： C07C17/156

摘要： Process for the selective catalytic oxidation of carbon monoxide in the presence of olefin monomers without appreciable oxidation of such monomers. According to this process, a gaseous waste stream containing carbon monoxide, olefin monomers, and a variety of other agents, is contacted with a catalytically effective amount of copper chromite, preferably in an oxygen enriched environment, at temperatures in the range from about 200.degree. C. to about 325.degree. C. The contact time of the stream with the catalyst bed can vary within broad limits, and the duration of which will vary inversely with the temperature of the catalyst bed.

摘要翻译： 在烯烃单体的存在下选择性催化氧化一氧化碳的方法，而不明显地氧化这些单体。 根据该方法，将含有一氧化碳，烯烃单体和各种其它试剂的气态废物流与催化有效量的亚铬酸铜接触，优选在富氧环境中，温度范围为约200℃ 流与催化剂床的接触时​​间可以在宽范围内变化，其持续时间将与催化剂床的温度反向变化。

公开(公告)号：US4446249A

公开(公告)日：1984-05-01

申请号：US378928

申请日：1982-05-17

申请人： Jamal S. Eden

发明人： Jamal S. Eden

IPC分类号： B01J23/78 ,  B01J23/83 ,  B01J27/10 ,  C07C17/156

CPC分类号： B01J27/10 ,  B01J23/78 ,  B01J23/83 ,  C07C17/156

摘要： A fluidizable catalyst composition is provided having cupric chloride deposited on a fluidizable, modified gamma alumina support in which the support has incorporated, prior to the deposit of copper, from 0.5% to 3.0% by weight based on the weight of the support of at least one metal selected from the group consisting of potassium, lithium, rubidium, cesium, alkaline earth metals, rare earth metals, or combinations thereof. Such catalyst compositions are extremely useful as the fluid bed catalyst in the vapor phase oxyhydrochlorination reaction of ethylene, oxygen and hydrogen chloride to produce 1,2-dichloroethane. The use of the catalysts results in improved EDC efficiency based on ethylene and avoids operating problems caused by stickiness of the catalyst in the fluid bed. Incorporation of a combination of potassium and barium in the fluidizable gamma alumina support, prior to deposit of the copper, produces an excellent catalyst for a fluid bed ethylene oxyhydrochlorination process in which the vent gases from the process are recycled.

摘要翻译： 提供了一种可流化催化剂组合物，其具有沉积在可流化的，改性的γ氧化铝载体上的氯化铜，其中载体在沉积铜之前已经加入至少0.5重量％至3.0重量％，基于载体的重量至少 选自由钾，锂，铷，铯，碱土金属，稀土金属或其组合组成的组中的一种金属。 这种催化剂组合物在乙烯，氧气和氯化氢的气相氧氯化反应中作为流化床催化剂是非常有用的，以产生1,2-二氯乙烷。 催化剂的使用导致基于乙烯的改进的EDC效率，并避免了由催化剂在流化床中的粘性引起的操作问题。 在可沉积的铜之前，在可流化的γ氧化铝载体中并入钾和钡的组合，为流化床乙烯氧化氢氯化方法产生优异的催化剂，其中来自该方法的排放气体被再循环。