摘要:
Copolysiloxanecarbonates are prepared in the melt by the reaction of a diaryl carbonate such as diphenyl carbonate with a mixture of a dihydroxyaromatic compound and a carbonate-terminated polydiorganosiloxane, the latter typically prepared by reaction of a diaryl carbonate or aryl chloroformate with a hydroxyorgano-terminated polydiorganosiloxane. By this method, incorporation of silicone units in the copolysiloxanecarbonate is maximized.
摘要:
The present invention is directed to a method of making polycarbonates by the melt condensation of diarylcarbonate and dihydric phenol in the presence of a tetraorganophosphonium carboxylate salt, such as tetrabutylphosphonium acetate.
摘要:
The present invention is directed to a method for effecting the redistribution of polycarbonate and polycarbonate blends utilizing a tetraorganophosphonium carboxylate salt.
摘要:
Blow moldable polycarbonate is produced by first producing a polycarbonate preform by a melt transesterification process. The polycarbonate preform comprises 2.1 to 10 mole percent polyfunctional branching agent, based on the total moles of polycarbonate in the polycarbonate preform. The polycarbonate preform is then melt equilibrated with a second polycarbonate to produce a blow moldable grade.
摘要:
UV stabilized polycarbonates are provided having chemically combined polyhydric phenol benzotriazole carbonate units, such as 1,1-bis(4-hydroxyphenyl)-1-[4-hydroxy-3-(N-2-benzotriazole)phenyl]ethane carbonate units and methods for making. Incorporation of the polyhydric phenol benzotriazole functional units into the polycarbonate backbone can be achieved by redistribution or transesterification under melt polymerization conditions.
摘要:
The present invention provides a composition comprising polycarbonate wherein the polycarbonate has a very low Fries content (e.g., above 5 ppm and below 360 ppm). The present invention also provides a polycarbonate having a very low Fries content which is made by the melt process. This polycarbonate has high ductility and high impact strength. The invention also provides a method for making these compositions. Another aspect of the invention is an optical disk comprising polycarbonate having a very low Fries content which is made by the melt process. Such optical disks resist breakage due to bending.
摘要:
Disclosed herein is a polycarbonate copolymer comprising A) a structure derived from a dihydroxy alkylene oxide compound selected from the group consisting of formula (1a) and formula (1b): H-(E-X)l—OH (1a) H-(E-X-E)l-OH (1b) wherein E and X are different and each and independently are selected from the group consisting of formula (2a) and formula (2b): —(OCH2CH2)m— (2a) —(OCHRCH2)n— (2b) wherein R is a C1-8 alkyl group; l, m, and n are integers greater than or equal to 1; and wherein the weight average molecular weight of the total amount of the structures corresponding to formula (2b) in the copolymer is between 100 and 2,000 g/mol; and B) a structure derived from a dihydroxy aromatic compound, wherein the weight percentages are based on the total weight of the structures of A) and B).
摘要:
Disclosed herein is a polycarbonate copolymer comprising A) a structure derived from a dihydroxy alkylene oxide compound selected from the group consisting of formula (1a) and formula (1b): H-(E-X)l—OH (1a) H-(E-X-E)l-OH (1b) wherein E and X are different and each and independently are selected from the group consisting of formula (2a) and formula (2b): —(OCH2CH2)m— (2a) —(OCHRCH2)n— (2b) wherein R is a C1-8 alkyl group; l, m, and n are integers greater than or equal to 1; and wherein the weight average molecular weight of the total amount of the structures corresponding to formula (2b) in the copolymer is between 100 and 2,000 g/mol; and B) a structure derived from a dihydroxy aromatic compound, wherein the weight percentages are based on the total weight of the structures of A) and B).
摘要:
Disclosed herein is a polycarbonate copolymer comprising A) a structure derived from a dihydroxy alkylene oxide compound selected from the group consisting of formula (1a) and formula (1b): H-(E-X)l—OH (1a) H-(E-X-E)l-OH (1b) wherein E and X are different and each and independently are selected from the group consisting of formula (2a) and formula (2b): —(OCH2CH2)m— (2a) —(OCHRCH2)n— (2b) wherein R is a C1-8 alkyl group; l, m, and n are integers greater than or equal to 1; and wherein the weight average molecular weight of the total amount of the structures corresponding to formula (2b) in the copolymer is between 100 and 2,000 g/mol; and B) a structure derived from a dihydroxy aromatic compound, wherein the weight percentages are based on the total weight of the structures of A) and B).
摘要:
Disclosed herein is a polycarbonate copolymer comprising A) a structure derived from a dihydroxy alkylene oxide compound selected from the group consisting of formula (1a) and formula (1b): H-(E-X)l—OH (1a) H-(E-X-E)l-OH (1b) wherein E and X are different and each and independently are selected from the group consisting of formula (2a) and formula (2b): —(OCH2CH2)m— (2a) —(OCHRCH2)n— (2b) wherein R is a C1-8 alkyl group; l, m, and n are integers greater than or equal to 1; and wherein the weight average molecular weight of the total amount of the structures corresponding to formula (2b) in the copolymer is between 100 and 2,000 g/mol; and B) a structure derived from a dihydroxy aromatic compound, wherein the weight percentages are based on the total weight of the structures of A) and B).