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公开(公告)号：US06927270B2
公开(公告)日：2005-08-09
申请号：US10186318
申请日：2002-06-27
IPC分类号： C07F7/07 , C08G20060101 , C08G77/00 , C08G77/06
摘要： Efficient processes have been developed for the cost effective functionalization of polyhedral oligomeric silsesquioxane-silanols (POSS-Silanols) and for the manufacture of polyfunctional polyhedral oligomeric silsesquioxanes. The processes utilize the action of bases or acids on silane coupling agents. The preferred process utilizes base to promote the silylation of POSS-Silanols of the formula [(RSiO1.5)n(R(HO)SiO1.0)m]Σ# with silane coupling agents to form POSS species with functionalized incompletely condensed nanostructures [(RSiO1.5)n(R(YSiR2O)SiO1.0)m]Σ# or functionalized completely condensed nanostructures [(RSiO1.5)n(YSiO1.5)1]Σ#. The process can alternately be conducted with acids. A second process utilizes base to alkylate POSS-Silanols with functionalized alkyl halides. A third related process utilizes base to react with silane coupling agents to form polyfunctional, fully condensed POSS species of formula [(YSiO1.5)n]Σ#. This process can also alternately be conducted under acidic conditions. Each of the processes result in new POSS compositions that can undergo additional desirable chemical reactions or which are directly suitable for polymerization or grafting into polymeric materials. POSS frameworks containing silanol and other reactive functionalities suitable for polymerizations have previously been described as valuable co-monomers in polymerizations and as feed-stocks for the preparation of a diverse number of chemical agents that are useful in polymeric materials in biological applications, and for the modification of surfaces.
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公开(公告)号：US07572872B2
公开(公告)日：2009-08-11
申请号：US11379993
申请日：2006-04-24
申请人： Jason T. Flodin , Joseph D. Lichtenhan , Joseph J. Schwab , Yi-Zhong An , Xuan Fu , Zachary Kemp
发明人： Jason T. Flodin , Joseph D. Lichtenhan , Joseph J. Schwab , Yi-Zhong An , Xuan Fu , Zachary Kemp
IPC分类号： C08F30/08
CPC分类号： A61L27/18 , A61L2400/12 , C08L83/04
摘要： Nanostructured chemicals such as polyhedral oligomeric silsesquioxanes, polyhedral oligomeric silicates, and polyhedral oligomeric metallasesquioxanes are attached to living and nonliving systems as biomaterials to provide a nanoscopic topology that favors biomimetic function and cellular modulation. The resulting surface is nanoscopically thin, nanoscopically dispersed, provides systematic chemistry, surface area, surface volume, surface topology, and is essentially free of impurities, and has controllable properties through selection of composition, R groups, nanostructure size and topology. Highly shape specific and chemically tailorable nanostructured molecules are sized to biological material dimensions and are compatible with all sterilization methods.
摘要翻译： 纳米结构化学物质如多面体低聚倍半硅氧烷，多面体低聚硅酸盐和多面体低聚金属氧化物倍半硅氧烷作为生物材料连接到生物和非活性体系上，以提供有利于仿生功能和细胞调节的纳米视觉拓扑结构。 所得表面纳米级薄，纳米级分散，提供系统化学，表面积，表面体积，表面拓扑，基本上不含杂质，通过选择组成，R基团，纳米结构尺寸和拓扑结构具有可控性。 高度形状的特定和化学可裁剪的纳米结构分子的大小适合生物材料尺寸，并与所有灭菌方法兼容。
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3.发明授权公开(公告)号：US07638195B2
公开(公告)日：2009-12-29
申请号：US11342240
申请日：2006-01-27
IPC分类号： B32B17/02
CPC分类号： C09D5/028 , B82Y30/00 , Y10T428/2938 , Y10T428/2962 , Y10T428/2982 , Y10T428/2995 , Y10T428/31663
摘要： Nanoreinforced coatings with improved hydrophobicity, thermal stability, hardness, and durability have been developed from polyhedral oligomeric silsesquioxane (POSS) reagents and resins. The nanoscopic dimensions and hybrid (organic/inorganic) composition of POSS reagents are particularly useful for coating fillers derived from minerals, metals, glasses, and polymeric materials.
摘要翻译： 已经从多面体低聚倍半硅氧烷（POSS）试剂和树脂开发出具有改进的疏水性，热稳定性，硬度和耐久性的纳米增强涂层。 POSS试剂的纳米尺寸和杂化（有机/无机）组合物特别适用于涂覆源自矿物，金属，玻璃和聚合材料的填料。
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公开(公告)号：US20090176006A1
公开(公告)日：2009-07-09
申请号：US11379993
申请日：2006-04-24
申请人： Jason T. Flodin , Joseph D. Lichtenhan , Joseph J. Schwab , Yi-Zhong An , Xuan Fu , Zachary Kemp
发明人： Jason T. Flodin , Joseph D. Lichtenhan , Joseph J. Schwab , Yi-Zhong An , Xuan Fu , Zachary Kemp
IPC分类号： B05D3/00
CPC分类号： A61L27/18 , A61L2400/12 , C08L83/04
摘要： Nanostructured chemicals such as polyhedral oligomeric silsesquioxanes, polyhedral oligomeric silicates, and polyhedral oligomeric metallasesquioxanes are attached to living and nonliving systems as biomaterials to provide a nanoscopic topology that favors biomimetic function and cellular modulation. The resulting surface is nanoscopically thin, nanoscopically dispersed, provides systematic chemistry, surface area, surface volume, surface topology, and is essentially free of impurities, and has controllable properties through selection of composition, R groups, nanostructure size and topology. Highly shape specific and chemically tailorable nanostructured molecules are sized to biological material dimensions and are compatible with all sterilization methods.
摘要翻译： 纳米结构化学物质如多面体低聚倍半硅氧烷，多面体低聚硅酸盐和多面体低聚金属氧化物倍半硅氧烷作为生物材料连接到生物和非活性体系上，以提供有利于仿生功能和细胞调节的纳米视觉拓扑结构。 所得表面纳米级薄，纳米级分散，提供系统化学，表面积，表面体积，表面拓扑，基本上不含杂质，通过选择组成，R基团，纳米结构尺寸和拓扑结构具有可控性。 高度形状的特定和化学可裁剪的纳米结构分子的大小适合生物材料尺寸，并与所有灭菌方法兼容。
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公开(公告)号：US20100137464A1
公开(公告)日：2010-06-03
申请号：US12698931
申请日：2010-02-02
IPC分类号： C08J9/40
CPC分类号： C08J3/203 , B82Y30/00 , C08J5/005 , C08J2201/038 , C08K5/549 , Y10T428/2995 , Y10T428/31663
摘要： The use of nanostructured chemicals based on polyhedral oligomeric silsesquioxanes (POSS) and polyhedral oligomeric silicates (POS) are used to control porosity in organic and inorganic media. The precisely defined nanoscopic dimensions of this class of chemicals enables porosity to be both created (increased) or reduced (decreased) as desired. The thermal and chemical stability of the POSS/POS nanostructures and the ability of these nano-building blocks to be selectively placed or rationally assembled with both inorganic and organic material mediums allow tailoring of porosity.
摘要翻译： 使用基于多面体低聚倍半硅氧烷（POSS）和多面体低聚硅酸盐（POS）的纳米结构化学品用于控制有机和无机介质中的孔隙率。 这类化学品的精确定义的纳米尺寸尺寸可以根据需要产生（增加）或减少（减少）孔隙度。 POSS / POS纳米结构的热和化学稳定性以及这些纳米结构单元与无机和有机材料介质选择性地放置或合理组装的能力允许调整孔隙度。
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公开(公告)号：US20080221262A1
公开(公告)日：2008-09-11
申请号：US11725994
申请日：2007-03-19
申请人： Joseph M. Mabry , Timothy S. Haddad , Sarah Anne Mazzella , Sukhendu B. Hait , Joseph J. Schwab , Joseph D. Lichtenhan
发明人： Joseph M. Mabry , Timothy S. Haddad , Sarah Anne Mazzella , Sukhendu B. Hait , Joseph J. Schwab , Joseph D. Lichtenhan
IPC分类号： C08L83/06
CPC分类号： B82Y30/00 , C08F8/42 , C08F120/14
摘要： A method of using fluorinated-nanostructured POSS chemicals as alloying agents for the reinforcement of polymer microstructures, including polymer coils, domains, chains, and segments, at the molecular level. Because of their tailorable compatibility with nonfluorinated polymers, nanostructured chemicals can be readily and selectively incorporated into polymers by direct blending processes. The incorporation of a nanostructured chemical into a polymer favorably impacts a multitude of polymer physical properties. Properties most favorably improved are surface properties, such as lubricity, contact angle, water repellency, deicing, surface tension, and abrasion resistance. Improved surface properties may be useful for applications such as anti-icing surfaces, non-wetting surfaces, low friction surfaces, self cleaning. Other properties improved include time dependent mechanical and thermal properties such as heat distortion, creep, compression set, shrinkage, modulus, hardness and biological compatibility. In addition to mechanical properties, other physical properties are favorably improved, including lower thermal conductivity, dielectric properties, fire resistance, gas permeability and separation. These improved properties may be useful in a number of applications, including space-survivable materials and seals, gaskets, cosmetics, and personal care.
摘要翻译： 使用氟化纳米结构化POSS化学品作为合金剂的方法，用于在分子水平上增强聚合物微结构，包括聚合物线圈，结构域，链和链段。 由于其与非氟化聚合物的可定制的相容性，纳米结构化学物质可以通过直接共混方法容易且有选择地并入聚合物中。 将纳米结构化学物质掺入聚合物有利地影响了许多聚合物的物理性质。 最有利地改善的性能是表面性质，例如润滑性，接触角，防水性，除冰，表面张力和耐磨性。 改进的表面性质可用于诸如防冰表面，非润湿表面，低摩擦表面，自清洁等应用。 改进的其它性能包括时间相关的机械和热性能，如热变形，蠕变，压缩永久变形，收缩，模量，硬度和生物相容性。 除机械性能外，其他物理性能得到有利改善，包括较低的导热性，介电性能，耐火性，透气性和分离性。 这些改进的性质可用于许多应用，包括空间存活材料和密封件，垫圈，化妆品和个人护理。
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公开(公告)号：US07897667B2
公开(公告)日：2011-03-01
申请号：US11725994
申请日：2007-03-19
申请人： Joseph M. Mabry , Timothy S. Haddad , Sarah Anne Mazzella , Sukhendu B. Hait , Joseph J. Schwab , Joseph D. Lichtenhan
发明人： Joseph M. Mabry , Timothy S. Haddad , Sarah Anne Mazzella , Sukhendu B. Hait , Joseph J. Schwab , Joseph D. Lichtenhan
IPC分类号： C08K5/24
CPC分类号： B82Y30/00 , C08F8/42 , C08F120/14
摘要： A method of using fluorinated-nanostructured POSS chemicals as alloying agents for the reinforcement of polymer microstructures, including polymer coils, domains, chains, and segments, at the molecular level. Because of their tailorable compatibility with nonfluorinated polymers, nanostructured chemicals can be readily and selectively incorporated into polymers by direct blending processes. The incorporation of a nanostructured chemical into a polymer favorably impacts a multitude of polymer physical properties. Properties most favorably improved are surface properties, such as lubricity, contact angle, water repellency, deicing, surface tension, and abrasion resistance. Improved surface properties may be useful for applications such as anti-icing surfaces, non-wetting surfaces, low friction surfaces, self cleaning. Other properties improved include time dependent mechanical and thermal properties such as heat distortion, creep, compression set, shrinkage, modulus, hardness and biological compatibility. In addition to mechanical properties, other physical properties are favorably improved, including lower thermal conductivity, dielectric properties, fire resistance, gas permeability and separation. These improved properties may be useful in a number of applications, including space-survivable materials and seals, gaskets, cosmetics, and personal care.
摘要翻译： 使用氟化纳米结构化POSS化学品作为合金剂的方法，用于在分子水平上增强聚合物微结构，包括聚合物线圈，结构域，链和链段。 由于其与非氟化聚合物的可定制的相容性，纳米结构化学物质可以通过直接共混方法容易且有选择地并入聚合物中。 将纳米结构化学物质掺入聚合物有利地影响了许多聚合物的物理性质。 最有利地改善的性能是表面性质，例如润滑性，接触角，防水性，除冰，表面张力和耐磨性。 改进的表面性质可用于诸如防冰表面，非润湿表面，低摩擦表面，自清洁等应用。 改进的其它性能包括时间相关的机械和热性能，如热变形，蠕变，压缩永久变形，收缩，模量，硬度和生物相容性。 除机械性能外，其他物理性能得到有利改善，包括较低的导热性，介电性能，耐火性，透气性和分离性。 这些改进的性质可用于许多应用，包括空间存活材料和密封件，垫圈，化妆品和个人护理。
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公开(公告)号：US07553904B2
公开(公告)日：2009-06-30
申请号：US11225607
申请日：2005-09-12
申请人： Joseph D. Lichtenhan , Qibo Liu , Yan-Jyh Lee , Xuan Fu , Sukhendu Hait , Joseph J. Schwab , Rusty L. Blanski , Patrick N. Ruth
发明人： Joseph D. Lichtenhan , Qibo Liu , Yan-Jyh Lee , Xuan Fu , Sukhendu Hait , Joseph J. Schwab , Rusty L. Blanski , Patrick N. Ruth
IPC分类号： C08L83/00
CPC分类号： C08K5/549 , Y10T428/31663
摘要： A method of using olefin containing nanostructured chemicals and silanol containing nanostructured chemicals as high temperature resins is described. Vinyl containing nanostructured chemicals are particularity effective in thermosets as they control the motions of polymer chains, and segments, at the molecular level. Silanol containing nanostructured chemicals are particularity effective in thermosets containing polar groups as the silanol can enhance the reactivity of these groups. Because of their tailorable compatibility with fluorinated polymers, nanostructured chemicals can be readily and selectively incorporated into polymers by direct blending and polymerization processes. The incorporation of a nanostructured chemical into a polymer favorably impacts a multitude of polymer physical properties. Properties most favorably improved are heat distortion and flammability characteristics, permeability, optical properties, texture, feel and durability. Other properties improved include time dependent mechanical and thermal properties such as creep, compression set, shrinkage, modulus, and hardness. In addition to mechanical properties, other physical properties are favorably improved, including lower thermal conductivity, and gas oxygen permeability. These improved properties may be useful in a number of applications, including composite materials, foams, cosmetics, and durable coatings.
摘要翻译： 描述了使用含烯烃的纳米结构化学品和含硅烷醇的纳米结构化学品作为高温树脂的方法。 含乙烯基纳米结构化学品在热固性材料中特别有效，因为它们在分子水平上控制聚合物链和链段的运动。 含硅烷醇的纳米结构化学品在含极性基团的热固性材料中是特别有效的，因为硅烷醇可增强这些基团的反应性。 由于它们与氟化聚合物的可定制的相容性，纳米结构化学物质可以通过直接共混和聚合过程容易且选择性地引入到聚合物中。 将纳米结构化学物质掺入聚合物有利地影响了许多聚合物的物理性质。 性能最有利地提高了热变形和易燃特性，渗透性，光学性能，质地，手感和耐久性。 改进的其它性能包括时间依赖性机械和热性能，如蠕变，压缩永久变形，收缩率，模量和硬度。 除机械性能外，还有其他物理性能得到改善，包括较低的导热系数和气体透氧性。 这些改进的性质可用于许多应用，包括复合材料，泡沫，化妆品和耐用涂层。
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公开(公告)号：US06972312B1
公开(公告)日：2005-12-06
申请号：US09631892
申请日：2000-08-04
申请人： Joseph D. Lichtenhan , Joseph J. Schwab , Yi-Zong An , William Reinerth , Michael J. Carr , Frank J. Feher , Raquel Terroba , Qibo Liu
发明人： Joseph D. Lichtenhan , Joseph J. Schwab , Yi-Zong An , William Reinerth , Michael J. Carr , Frank J. Feher , Raquel Terroba , Qibo Liu
CPC分类号： C08G77/04 , C08G77/045 , C08G77/06 , C08G77/08
摘要： Three processes for the manufacture of polyhedral oligomeric silsesquioxanes (POSS) which utilize the action of bases that are capable of either attacking silicon or any compound that can react with a protic solvent (e.g. ROH, H2O etc.) and generate hydroxide [OH]−, alkoxide [RO]−′, etc. The first process utilizes such bases to effectively redistribute the silicon-oxygen frameworks in polymeric silsesquioxanes [RSiO1.5]28 where ∞=1-1,000,000 or higher into POSS nanostructures of formulas [(RSiO1.5)nΣ#, homoleptic, [(RXSiO1.5)n]Σ#, functionalized homoleptic, [(RSiO1.5)m(R′SiO1.5)n]Σ#, heteroleptic, and {(RSiO1.5)m(RXSiO1.0)n}Σ#, functionalized heteroleptic nanostructures. The second process utilizes base to aid in the formation of POSS nanostructures of formulas [(RSiO1.5)n]Σ# homoleptic and [(RSiO1.5)m(R′SiO1.5)n]Σ# heteroleptic and [(RSiO1.5)m(RXSiO1.0)n]Σ# functionalized heteroleptic nanostructures from silanes RSiX3 and linear or cyclic silsesquioxanes of the formula RX2Si—(OSiRX)m—OSiRX2 where m=0-10, X=OH, Cl, Br, I, alkoxide OR, acetate OOCR, peroxide OOR, amine NR2, isocyanate NCO, and R. The third process utilizes base to selectively ring-open the silicon-oxygen-silicon (Si—O—Si) bonds in POSS structures to form POSS species with incompletely condensed nanostructures. These processes also afford stereochemical control over X. The three processes result in new POSS species that can undergo additional chemical manipulations to ultimately be converted into POSS-species suitable for polymerization, grafting, or other desirable chemical reactions.
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公开(公告)号：US06770724B1
公开(公告)日：2004-08-03
申请号：US09783719
申请日：2001-02-16
IPC分类号： C08G7706
CPC分类号： C07F7/21 , C07F7/0876 , C08G77/04 , C08G77/045 , C08G77/38
摘要： Method is provided for selectively opening rings of polyhedral oligomeric silsesquioxane (POSS) compounds to from functionalized derivatives thereof or new POSS species. Per the inventive method, the POSS compound is reacted with an acid to selectively cleave bonds in the POSS rings to add functionalities thereto for grafting, polymerization or catalysis, to thus form new familes of POSS derived compounds. Also provided are the new compounds so formed. Method is also provided for expanding rings of POSS compounds. Per the inventive method, a POSS compound is reacted with silane reagents to obtain an expanded POSS framework with added Si ring substituends to form new families of POSS compounds. Also provided are the new compounds so formed.
摘要翻译： 提供了从其官能化衍生物或新的POSS物质选择性地打开多面体低聚倍半硅氧烷（POSS）化合物的环的方法。 按照本发明的方法，POSS化合物与酸反应以选择性地切割POSS环中的键，以便为其接枝，聚合或催化添加官能团，从而形成新的POSS衍生化合物。 还提供了如此形成的新化合物。 还提供了扩展POSS化合物环的方法。 根据本发明的方法，POSS化合物与硅烷试剂反应以获得具有添加的Si环取代基的扩展的POSS框架，以形成新的POSS化合物族。 还提供了如此形成的新化合物。
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