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公开(公告)号：US5656395A
公开(公告)日：1997-08-12
申请号：US479360
申请日：1995-06-07
CPC分类号： H01M4/669 , H01M12/06 , H01M4/661 , H01M4/74 , H01M4/86 , H01M2004/8689 , Y10S428/929 , Y10T29/49108
摘要： A metal current collecting substrate for an air cathode in an electrochemical metal air cell is provided for, wherein the substrate is hardened by one of the steps of sandblasting, shotblasting, plastic deformation of the substrate below the recrystallization temperature range of the metal thereof, and heating the substrate to above the transformation temperature of the metal thereof followed by quenching the substrate below the transformation temperature of the metal thereof. Catalytically active materials, most preferably a mixture of carbon and manganese dioxide, are pressed or otherwise disposed upon the hardened substrate. The substrate is capable of being connected to electrical circuitry. Most preferably, the substrate is a metal screen that has been hardened, roughened and pitted by sandblasting before the catalytically active materials are disposed thereupon, and before the substrate is incorporated into an electrochemical metal air cell.
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2.发明授权
公开(公告)号：US5650246A
公开(公告)日：1997-07-22
申请号：US542809
申请日：1995-10-13
CPC分类号： H01M4/669 , H01M12/06 , H01M4/661 , H01M4/74 , H01M4/86 , H01M2004/8689 , Y10S428/929 , Y10T29/49108
摘要： A metal current collecting substrate for an air cathode in an electrochemical metal air cell is provided for, wherein the substrate is hardened by one of the steps of sandblasting, shotblasting, plastic deformation of the substrate below the recrystallization temperature range of the metal thereof, and heating the substrate to above the transformation temperature of the metal thereof followed by quenching the substrate below the transformation temperature of the metal thereof. Catalytically active materials, most preferably a mixture of carbon and manganese dioxide, are pressed or otherwise disposed upon the hardened substrate. The substrate is capable of being connected to electrical circuitry. Most preferably, the substrate is a metal screen that has been hardened, roughened and pitted by sandblasting before the catalytically active materials are disposed thereupon, and before the substrate is incorporated into an electrochemical metal air cell.
摘要翻译： 提供了一种用于电化学金属空气电池中的空气阴极的金属集流基板，其中通过喷砂，喷丸，低于其金属的再结晶温度范围的基板的塑性变形中的一个步骤来硬化基板，以及 将基板加热至其金属的转变温度以上，然后使基板在其金属的相变温度以下淬火。 催化活性材料，最优选碳和二氧化锰的混合物被压制或以其它方式设置在硬化的基底上。 基板能够连接到电路。 最优选地，基材是金属筛，其在将催化活性材料置于其之前以及在将基底结合到电化学金属空气电池中之前已通过喷砂而被硬化，粗糙化和凹陷。
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3.发明授权
公开(公告)号：US5587259A
公开(公告)日：1996-12-24
申请号：US208450
申请日：1994-03-09
CPC分类号： H01M4/669 , H01M12/06 , H01M4/661 , H01M4/74 , H01M4/86 , H01M2004/8689 , Y10S428/929 , Y10T29/49108
摘要： A metal current collecting substrate for an air cathode in an electrochemical metal air cell is provided for, wherein the substrate is hardened by one of the steps of sandblasting, shotblasting, plastic deformation of the substrate below the recrystallization temperature range of the metal thereof, and heating the substrate to above the transformation temperature of the metal thereof followed by quenching the substrate below the transformation temperature of the metal thereof. Catalytically active materials, most preferably a mixture of carbon and manganese dioxide, are pressed or otherwise disposed upon the hardened substrate. The substrate is capable of being connected to electrical circuitry. Most preferably, the substrate is a metal screen that has been hardened, roughened and pitted by sandblasting before the catalytically active materials are disposed thereupon, and before the substrate is incorporated into an electrochemical metal air cell.
摘要翻译： 提供了一种用于电化学金属空气电池中的空气阴极的金属集流基板，其中通过喷砂，喷丸，低于其金属的再结晶温度范围的基板的塑性变形中的一个步骤来硬化基板，以及 将基板加热至其金属的转变温度以上，然后使基板在其金属的相变温度以下淬火。 催化活性材料，最优选碳和二氧化锰的混合物被压制或以其它方式设置在硬化的基底上。 基板能够连接到电路。 最优选地，基材是金属筛，其在将催化活性材料置于其之前以及在将基底结合到电化学金属空气电池中之前已通过喷砂而被硬化，粗糙化和凹陷。
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4.发明授权Metal-air cathode and cell having catalytically active manganese compounds of valence state +2 失效金属空气阴极和具有催化活性的锰化合物价态的电池+2
公开(公告)号：US5308711A
公开(公告)日：1994-05-03
申请号：US15641
申请日：1993-02-09
CPC分类号： H01M4/9016 , H01M12/06 , H01M4/96
摘要： An air cathode for a metal-air cell and methods for making it are provided. In the air cathode of the present invention, manganese compounds of valence state +2 act as catalysts for the reduction of oxygen, and are distributed substantially evenly throughout a carbon matrix. Manganese compounds of valence state +2 form between carbon particles after the carbon particles are added to an aqueous solution of potassium permanganate.
摘要翻译： 提供一种用于金属 - 空气电池的空气阴极及其制造方法。 在本发明的空气阴极中，价态为+2的锰化合物作为还原氧的催化剂，并且基本均匀地分布在整个碳基质中。 在将碳粒子加入到高锰酸钾水溶液中之后，碳粒子之间形成的价态化合物为+2的锰化合物。
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5.发明授权Method of hardening a metal current collecting strip of an air cathode and a method of making a button type battery 失效硬化空气阴极的金属集流条的方法和制造纽扣式电池的方法
公开(公告)号：US5637117A
公开(公告)日：1997-06-10
申请号：US479361
申请日：1995-06-07
CPC分类号： H01M4/669 , H01M12/06 , H01M4/661 , H01M4/74 , H01M4/86 , H01M2004/8689 , Y10S428/929 , Y10T29/49108
摘要： A metal current collecting substrate for an air cathode in an electrochemical metal air cell is provided for, wherein the substrate is hardened by one of the steps of sandblasting, shotblasting, plastic deformation of the substrate below the recrystallization temperature range of the metal thereof, and heating the substrate to above the transformation temperature of the metal thereof followed by quenching the substrate below the transformation temperature of the metal thereof. Catalytically active materials, most preferably a mixture of carbon and manganese dioxide, are pressed or otherwise disposed upon the hardened substrate. The substrate is capable of being connected to electrical circuitry. Most preferably, the substrate is a metal screen that has been hardened, roughened and pitted by sandblasting before the catalytically active materials are disposed thereupon, and before the substrate is incorporated into an electrochemical metal air cell.
摘要翻译： 提供了一种用于电化学金属空气电池中的空气阴极的金属集流基板，其中通过喷砂，喷丸，低于其金属的再结晶温度范围的基板的塑性变形中的一个步骤来硬化基板，以及 将基板加热至其金属的转变温度以上，然后使基板在其金属的相变温度以下淬火。 催化活性材料，最优选碳和二氧化锰的混合物被压制或以其它方式设置在硬化的基底上。 基板能够连接到电路。 最优选地，基材是金属筛，其在将催化活性材料置于其之前以及在将基底结合到电化学金属空气电池中之前已通过喷砂而被硬化，粗糙化和凹陷。
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6.发明授权Method of making air cathode material having catalytically active manganese compounds of valance state +2 失效制备具有催化活性的价态锰化合物的空气阴极材料的方法+2
公开(公告)号：US5378562A
公开(公告)日：1995-01-03
申请号：US190781
申请日：1994-02-01
CPC分类号： H01M4/9016 , H01M12/06 , H01M4/96
摘要： A method of making an air cathode material for a metal-air cell is provided. In the air cathode material of the present invention, manganese compounds of valence state +2 act as catalysts for the reduction of oxygen, and are distributed substantially evenly throughout a carbon matrix. Manganese compounds of valence state +2 form between carbon particles after the carbon particles are added to an aqueous solution of potassium permanganate.
摘要翻译： 提供一种制造用于金属 - 空气池的空气阴极材料的方法。 在本发明的空气阴极材料中，价态为+2的锰化合物作为氧还原的催化剂，并且基本均匀地分布在整个碳基质中。 在将碳粒子加入到高锰酸钾水溶液中之后，碳粒子之间形成的价态化合物为+2的锰化合物。
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公开(公告)号：US20090026077A1
公开(公告)日：2009-01-29
申请号：US11829843
申请日：2007-07-27
申请人： Robert B. Dopp
发明人： Robert B. Dopp
IPC分类号： G01N27/333 , G01N27/28
CPC分类号： G01N27/28
摘要： A system and method are provided for rapidly evaluating electrochemical components such as catalysts, electrodes, electrolyte, and membranes that delivers a high degree of accuracy and requires minimal materials costs. In one embodiment, the system may comprise a detachable electrochemical cell for housing an electrochemical reaction. The cell may comprise an anode chamber and a cathode chamber separated by an ion-diffusion membrane and an electrically conductive current collector in electrochemical communication with the cell. The reaction cell includes an outlet port in the cell to permit the removal of product gasses, and ports to permit the flow of electrolyte through said cell. The system further comprises means, for example, a reciprocating piston, for sealing the reaction cell to the system to prevent exposure of the electrochemical reaction to the ambient environment, where the cell and adjacent components may be sealed by, for example, gaskets, that permit rapid separation.
摘要翻译： 提供了一种用于快速评估电化学组分如催化剂，电极，电解质和膜的系统和方法，其提供高精度并且需要最少的材料成本。 在一个实施例中，系统可以包括用于容纳电化学反应的可拆卸电化学电池。 电池可以包括由离子扩散膜分离的阳极室和阴极室以及与电池电化学连通的导电集电体。 反应池包括在电池中的出口以允许去除产物气体，以及允许电解质通过所述电池的端口。 该系统还包括例如往复式活塞的装置，用于将反应池密封到系统以防止电化学反应暴露于周围环境，其中电池和相邻部件可以通过例如垫圈密封， 允许快速分离。
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公开(公告)号：US06248463B1
公开(公告)日：2001-06-19
申请号：US09313885
申请日：1999-05-18
申请人： Robert B. Dopp , John Edward Oltman
发明人： Robert B. Dopp , John Edward Oltman
IPC分类号： H01M1206
CPC分类号： H01M12/06
摘要： This invention pertains to metal-air electrochemical cells wherein one or more air entry ports is located in the bottom of the cathode can, to provide for entry of oxygen-rich air into the cathode can, where the oxygen partcicpates in the chemical reaction whereby the cell produces electrical energy. In this invention, multiple small air entry ports are provided. Generally, the use of multiple ports distributed over the bottom of the cathode can, opposite the reaction surface of the cathode assembly, while not increasing the overall open area of the ports, results in an increase in the ratio of the cell limiting current to the rate at which moisture is lost from the cell. Accordingly, moisture loss as a function of electrical energy produced, is less.
摘要翻译： 本发明涉及金属 - 空气电化学电池，其中一个或多个空气入口位于阴极罐的底部，以提供富氧空气进入阴极罐，其中氧在化学反应中分解，由此， 电池产生电能。 在本发明中，提供了多个小型进气口。 通常，分布在阴极底部的多个端口的使用可以与阴极组件的反作用表面相反，而不增加端口的总开口面积，导致电池限制电流与 水分从细胞中损失的速率。 因此，作为产生的电能的函数的水分损失较小。
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公开(公告)号：US4369568A
公开(公告)日：1983-01-25
申请号：US232431
申请日：1981-02-09
申请人： Robert B. Dopp
发明人： Robert B. Dopp
CPC分类号： H01M4/12 , H01M12/06 , Y10T29/49108 , Y10T29/4911
摘要： An improved metal-air button cell is provided. The cell is comprised of the following components: a conductive metal can, a cathode assembly in the can, a conductive metal cover, and a separator between the cathode assembly, wherein the metal cover and separator provide borders of a space in which an anode material can be placed. The improvement is that the amount of anode material is not sufficient to fill the space provided for it, and, wherein, the anode material is positioned against the separator and a void exists between the cover and the anode material.
摘要翻译： 提供了一种改进的金属空气纽扣电池。 电池由以下部件组成：导电金属罐，罐中的阴极组件，导电金属盖和阴极组件之间的隔板，其中金属盖和隔板提供了空间的边界，在该空间中阳极材料 可以放置。 改善的是阳极材料的量不足以填充为其提供的空间，并且其中，阳极材料抵靠隔板定位，并且在盖和阳极材料之间存在空隙。
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公开(公告)号：US06265102B1
公开(公告)日：2001-07-24
申请号：US09187567
申请日：1998-11-05
申请人： Yaron Shrim , Mariano Abramson , Robert B. Dopp
发明人： Yaron Shrim , Mariano Abramson , Robert B. Dopp
IPC分类号： H01M202
CPC分类号： H01M2/0222 , H01M12/06
摘要： The invention provides a metal-air electrochemical cell, having a leak-proof, metal prismatic casing comprising a pair of interfacing interengaging rectangular tray-like casing components, a first substantially rectangular tray-like casing component having a first major surface and contiguous side walls for encompassing a cathode of the cell and a second inverted substantially tray-like casing component having a second major surface and contiguous depending side walls for encompassing an anode of the cell, the side walls of one of the casing components being of a height to facilitate the curling and crimping of an upper portion thereof over a peripheral edge area of the major surface of the other casing component to form a leak-proof, closed prismatic casing.
摘要翻译： 本发明提供了一种金属 - 空气电化学电池，其具有防漏的金属棱柱形壳体，其包括一对相互接合的矩形托盘状壳体部件，第一基本矩形的托盘状壳体部件，其具有第一主表面和相邻的侧壁 用于包围电池的阴极和具有第二主表面和邻接的悬垂侧壁的第二倒置的基本上为托盘状的壳体部件，用于包围电池的阳极，其中一个壳体部件的侧壁的高度便于 其上部的卷曲和卷曲在另一壳体部件的主表面的周缘区域上方形成防漏闭合的棱柱形壳体。
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