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公开(公告)号:US20070269360A1
公开(公告)日:2007-11-22
申请号:US11801056
申请日:2007-05-08
IPC分类号: C01B6/15
CPC分类号: C01B6/21
摘要: A method for preparing a metal borohydride salt, M(BH4)n, where n is 1 or 2, from a slurry of sodium borohydride and a sodium alkoxide in a liquid hydrocarbon, wherein M is Li, K, Rb, Cs, Mg, Ca, Sr or Ba.
摘要翻译: 从硼氢化钠和醇钠溶液在液体中制备金属硼氢化物盐的方法,其中n为1或2,M(BH 4)n N 烃,其中M为Li,K,Rb,Cs,Mg,Ca,Sr或Ba。
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公开(公告)号:US08039666B2
公开(公告)日:2011-10-18
申请号:US12592180
申请日:2009-11-20
申请人: Anthony Rocco Cartolano , Sergei Vladimirovich Ivanov , Cheryl Irene Teich , John Hiroshi Yamamoto
发明人: Anthony Rocco Cartolano , Sergei Vladimirovich Ivanov , Cheryl Irene Teich , John Hiroshi Yamamoto
IPC分类号: C07F5/02
CPC分类号: C07F5/00
摘要: A method for preparing an amine borane from an alkali metal borohydride and an amine salt. The alkali metal borohydride is allowed to react with 0.95 to 1.05 equivalents of the amine salt in a solvent which contains water and an amine.
摘要翻译: 从碱金属硼氢化物和胺盐制备胺硼烷的方法。 使碱金属硼氢化物与0.95〜1.05当量的胺盐在含有水和胺的溶剂中反应。
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公开(公告)号:US20100130780A1
公开(公告)日:2010-05-27
申请号:US12592180
申请日:2009-11-20
申请人: Anthony Rocco Cartolano , Sergei Vladimirovich Ivanov , Cheryl Irene Teich , John Hiroshi Yamamoto
发明人: Anthony Rocco Cartolano , Sergei Vladimirovich Ivanov , Cheryl Irene Teich , John Hiroshi Yamamoto
IPC分类号: C07F5/02
CPC分类号: C07F5/00
摘要: A method for preparing an amine borane from an alkali metal borohydride and an amine salt. The alkali metal borohydride is allowed to react with 0.95 to 1.05 equivalents of the amine salt in a solvent which contains water and an amine.
摘要翻译: 从碱金属硼氢化物和胺盐制备胺硼烷的方法。 使碱金属硼氢化物与含有水和胺的溶剂中的0.95至1.05当量的胺盐反应。
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公开(公告)号:US20100178228A1
公开(公告)日:2010-07-15
申请号:US12653716
申请日:2009-12-16
申请人: Anthony Rocco Cartolano , Sergei Vladimirovich Ivanov , Cheryl Irene Teich , John Hiroshi Yamamoto
发明人: Anthony Rocco Cartolano , Sergei Vladimirovich Ivanov , Cheryl Irene Teich , John Hiroshi Yamamoto
CPC分类号: C01B6/21
摘要: A method for preparing M2B12H12, wherein M is an alkali metal, from an alkali metal borohydride and an amine borane. The method includes a step of allowing the alkali metal borohydride to react with excess amine borane in contact with a complexing agent.
摘要翻译: 从碱金属硼氢化物和胺硼烷制备M2B12H12(其中M为碱金属)的方法。 该方法包括使碱金属硼氢化物与与络合剂接触的过量胺硼烷反应的步骤。
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公开(公告)号:US20100143240A1
公开(公告)日:2010-06-10
申请号:US12592824
申请日:2009-12-03
IPC分类号: C01B3/08
CPC分类号: C01B3/065 , Y02E60/362 , Y02E60/364
摘要: A method for generation of hydrogen with reduced foaming by combining with water a solid composition containing a borohydride compound and a base in the presence of a transition metal catalyst.
摘要翻译: 一种通过在过渡金属催化剂存在下与水结合含有硼氢化合物和碱的固体组合物来生成氢的方法。
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公开(公告)号:US07648644B2
公开(公告)日:2010-01-19
申请号:US11823555
申请日:2007-06-28
CPC分类号: C01B6/21 , Y02E60/364
摘要: A stabilized aqueous mixture containing at least one borohydride compound and at least one metal hydroxide compound. The mixture has improved stability with regard to decomposition of borohydride, especially at elevated temperatures.
摘要翻译: 含有至少一种硼氢化合物和至少一种金属氢氧化物化合物的稳定的含水混合物。 该混合物在硼氢化合物的分解方面具有改善的稳定性,特别是在升高的温度下。
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公开(公告)号:US20080009575A1
公开(公告)日:2008-01-10
申请号:US11823555
申请日:2007-06-28
IPC分类号: C08K3/38
CPC分类号: C01B6/21 , Y02E60/364
摘要: A stabilized aqueous mixture containing at least one borohydride compound and at least one metal hydroxide compound. The mixture has improved stability with regard to decomposition of borohydride, especially at elevated temperatures.
摘要翻译: 含有至少一种硼氢化合物和至少一种金属氢氧化物化合物的稳定的含水混合物。 该混合物在硼氢化合物的分解方面具有改善的稳定性,特别是在升高的温度下。
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公开(公告)号:US20070187636A1
公开(公告)日:2007-08-16
申请号:US11705483
申请日:2007-02-12
IPC分类号: C99Z99/00
CPC分类号: C01B3/065 , C01B6/21 , C10L9/10 , H01M8/04216 , H01M8/065 , Y02E60/362 , Y02P70/56
摘要: A solid composition containing at least one borohydride compound and at least one base.
摘要翻译: 含有至少一种硼氢化合物和至少一种碱的固体组合物。
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公开(公告)号:US08377405B2
公开(公告)日:2013-02-19
申请号:US12322567
申请日:2009-02-03
申请人: Arthur Achhing Chin , Puja Jain , Suzanne Linehan , Francis Joseph Lipiecki , Stephen Gerard Maroldo , Samuel J. November , John Hiroshi Yamamoto
发明人: Arthur Achhing Chin , Puja Jain , Suzanne Linehan , Francis Joseph Lipiecki , Stephen Gerard Maroldo , Samuel J. November , John Hiroshi Yamamoto
IPC分类号: C01B6/11
CPC分类号: C01B6/21
摘要: A process for production of a borohydride compound. The process comprises combining a compound comprising boron and oxygen with an adduct of alane.
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公开(公告)号:US07029641B2
公开(公告)日:2006-04-18
申请号:US10263629
申请日:2002-10-03
申请人: John Hiroshi Yamamoto , Won Suh Park , Aaron Sarafinas , Michael Miller Cook , Stephen Gerard Maroldo
发明人: John Hiroshi Yamamoto , Won Suh Park , Aaron Sarafinas , Michael Miller Cook , Stephen Gerard Maroldo
IPC分类号: C01B35/00
摘要: The present invention relates to a method of making lithium borohydride that gives high yields while maintaining ease of purification.
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