Stabilized copolyester material
    1.
    发明授权
    Stabilized copolyester material 失效
    稳定的共聚酯材料

    公开(公告)号:US4340718A

    公开(公告)日:1982-07-20

    申请号:US155811

    申请日:1980-06-02

    IPC分类号: C08G63/54 C08G63/60 C08G63/68

    CPC分类号: C08G63/60 C08G63/54 C08G63/68

    摘要: Disclosed are novel copolyester materials having improved weatherability and useful, for example, as films, fibers, sheeting and the like in outdoor applications where long and daily exposure to actinic radiation is encountered. These copolyesters comprise, for example, polyethylene terephthalate containing a total of from about 0.3 to about 5.0%, preferably from about 0.6 to about 2.0% by weight of one or more moieties having the formula ##STR1## where R.sub.1 is cyano, alkylcarbonyl, cycloalkylcarbonyl or arylcarbonyl; R.sub.2 and R.sub.3 are, for example, alkyl, cycloalkyl, or aryl which may be substituted with a large variety of groups; and --X-- is ortho, meta, or para to the -ylene linkage and is selected from groups of the formulae ##STR2## wherein R is alkylene of 1-10 carbons, aryl, or cycloalkyl, each of which may be substituted.

    摘要翻译: 公开了具有改善的耐候性的新型共聚酯材料,例如在室外应用中,例如在遇到长时间和日常暴露于光化辐射的室外应用中是有用的。 这些共聚酯包括例如聚对苯二甲酸乙二醇酯,其总重量为约0.3至约5.0%,优选约0.6至约2.0%重量的一种或多种具有式的化合物其中R 1为氰基,烷基羰基,环烷基羰基 或芳基羰基; R2和R3是例如可以被各种基团取代的烷基,环烷基或芳基; 并且-X-是亚芳基键的邻位,间位或对位,并且选自下式的基团:其中R是1-10个碳的亚烷基,芳基或环烷基,其中每一个 可以被替代。

    Process for the preparation of cyclohexanedicarboxylic acids
    5.
    发明授权
    Process for the preparation of cyclohexanedicarboxylic acids 失效
    环己烷二羧酸的制备方法

    公开(公告)号:US5286903A

    公开(公告)日:1994-02-15

    申请号:US993537

    申请日:1992-12-21

    IPC分类号: C07C51/09 C07C61/09

    CPC分类号: C07C51/09

    摘要: Disclosed are processes for the preparation of cyclohexanedicarboxylic acids by the non-catalytic hydrolysis or acidolysis of dialkyl cyclohexanedicarboxylate esters. The processes provide a means for converting dialkyl cyclohexanedicarboxylate esters to cyclohexanedicarboxylic acids without the co-production of solid by-products which present disposal problems.

    摘要翻译: 公开了通过非催化水解或酸解二烷基环己烷二羧酸酯来制备环己烷二羧酸的方法。 这些方法提供了将二烷基环己烷二羧酸酯转化成环己烷二羧酸而不共同生产出现处置问题的固体副产物的方法。

    Bichromophoric benzotriazole-styrene ester ultraviolet stabilizers and
their use in organic compositions
    6.
    发明授权
    Bichromophoric benzotriazole-styrene ester ultraviolet stabilizers and their use in organic compositions 失效
    双色荧光苯并三唑 - 苯乙烯酯紫外线稳定剂及其在有机组合物中的应用

    公开(公告)号:US4235999A

    公开(公告)日:1980-11-25

    申请号:US43861

    申请日:1979-05-29

    IPC分类号: C07D249/20 C08K5/3475

    CPC分类号: C07D249/20 C08K5/3475

    摘要: The invention relates to bichromophoric benzotriazole-styrene ester compounds which have been found to be effective ultraviolet stabilizers. The invention also relates to ultraviolet degradable organic compositions containing a stabilizing amount of the bichromophoric composition to prevent such degradation. These stabilizers are effective in the presence of other additives commonly employed in polymeric compositions including, for example, pigments, colorants, fillers, reinforcing agents and the like. These ultraviolet stabilizers may also be incorporated into the organic compositions in the polymer melt or dissolved in the polymer dope, coated on the exterior of the molded article, film or extruded fiber.

    摘要翻译: 本发明涉及已被发现是有效的紫外线稳定剂的双色性苯并三唑 - 苯乙烯酯化合物。 本发明还涉及含有稳定量的显色组合物以防止这种降解的紫外可降解有机组合物。 这些稳定剂在通常用于聚合物组合物中的其它添加剂的存在下是有效的,包括例如颜料,着色剂,填料,增强剂等。 这些紫外线稳定剂也可以掺入聚合物熔体中的有机组合物中或溶解在聚合物涂料中,涂覆在模塑制品,薄膜或挤出纤维的外部上。

    Thermally stabilized polyolefin compositions
    7.
    发明授权
    Thermally stabilized polyolefin compositions 失效
    热稳定的聚烯烃组合物

    公开(公告)号:US4216137A

    公开(公告)日:1980-08-05

    申请号:US912632

    申请日:1978-06-05

    摘要: Polyolefins are rendered resistant to degradation upon exposure to heat by incorporating therein a stabilizing amount of a synergistic combination of a phenol-terpene resin, a sulfur-containing secondary antioxidant and a phosphonitrilic composition derived rom a phosphonitrilic halide and certain hydroxy compounds. The above synergistic combination is especially effective for stabilizing polyolefins containing carbon black.

    摘要翻译: 通过在其中加入稳定量的苯酚 - 萜烯树脂,含硫次级抗氧化剂和由膦酰基卤化物衍生的膦酸组合物和某些羟基化合物的协同组合,使聚烯烃暴露于耐热降解。 上述协同组合对于稳定含有炭黑的聚烯烃特别有效。

    Multiheterocyclic ultraviolet stabilizers and their use in organic
compositions
    8.
    发明授权
    Multiheterocyclic ultraviolet stabilizers and their use in organic compositions 失效
    多杂环紫外线稳定剂及其在有机组合物中的应用

    公开(公告)号:US4187213A

    公开(公告)日:1980-02-05

    申请号:US868087

    申请日:1978-01-09

    摘要: The invention relates to multiheterocyclic compounds which have been found to be effective ultraviolet stabilizers. The invention also relates to ultraviolet degradable organic compositions containing a stabilizing amount of the multiheterocyclic composition to prevent such degradation. These stabilizers are effective in the presence of other additives commonly employed in polymeric compositions including, for example, pigments, colorants, fillers, reinforcing agents and the like. These ultraviolet stabilizers may also be incorporated into the organic compositions in the polymer melt or dissolved in the polymer dope, coated on the exterior of the molded article, film or extruded fiber.

    摘要翻译: 本发明涉及已发现是有效的紫外线稳定剂的多杂环化合物。 本发明还涉及含有稳定量的多杂环组合物以防止这种降解的紫外可降解有机组合物。 这些稳定剂在通常用于聚合物组合物中的其它添加剂的存在下是有效的,包括例如颜料,着色剂,填料,增强剂等。 这些紫外线稳定剂也可以掺入聚合物熔体中的有机组合物中或溶解在聚合物涂料中,涂覆在模塑制品,薄膜或挤出纤维的外部上。

    Bichromophoric benzotriazole-styrene ultraviolet stabilizers
    9.
    发明授权
    Bichromophoric benzotriazole-styrene ultraviolet stabilizers 失效
    双色苯并三唑 - 苯乙烯紫外线稳定剂

    公开(公告)号:US4159270A

    公开(公告)日:1979-06-26

    申请号:US857732

    申请日:1977-12-05

    摘要: The invention relates to bichromophoric benzotriazole-styrene compounds which have been found to be effective ultraviolet stabilizers. The invention also relates to ultraviolet degradable organic compositions containing a stabilizing amount of the bichromophoric composition to prevent such degradation. These stabilizers are effective in the presence of other additives commonly employed in polymeric compositions including, for example, pigments, colorants, fillers, reinforcing agents and the like. These ulraviolet stablizers may also be incorporated into the organic compositions in the polymer melt or dissolved in the polymer dope, coated on the exterior of the molded article, film or extruded fiber.

    摘要翻译: 本发明涉及已发现是有效的紫外线稳定剂的双色荧光苯并三唑 - 苯乙烯化合物。 本发明还涉及含有稳定量的显色组合物以防止这种降解的紫外可降解有机组合物。 这些稳定剂在通常用于聚合物组合物中的其它添加剂的存在下是有效的,包括例如颜料,着色剂,填料,增强剂等。 这些紫外线稳定剂也可以掺入聚合物熔体中的有机组合物中或溶解在聚合物涂料中,涂覆在模制品,膜或挤出纤维的外部。

    Heterocylic ester, ultraviolet stabilizers and their use in organic
compositions
    10.
    发明授权
    Heterocylic ester, ultraviolet stabilizers and their use in organic compositions 失效
    异辛酯,紫外线稳定剂及其在有机组合物中的用途

    公开(公告)号:US4116928A

    公开(公告)日:1978-09-26

    申请号:US751632

    申请日:1976-12-17

    IPC分类号: C08K5/353 C08K5/34 C08K5/35

    CPC分类号: C08K5/353

    摘要: The invention relates to heterocyclic ester compounds which have been found to be extremely effective ultraviolet stabilizers. The invention also relates to ultraviolet degradable organic compositions containing an amount of a heterocyclic ester composition to prevent such degradation. These stabilizers are effective in the presence of other additives commonly empolyed in polymeric compositions including, for example, pigments, colorants, fillers, reinforcing agents and the like. These ultraviolet stabilizers may also be incorporated into the organic compositions such as polymers by adding to the polymer melt or dissolved in the polymer dope, coated on the exterior of the shaped or molded article, film or extruded fiber.

    摘要翻译: 本发明涉及已被发现是非常有效的紫外线稳定剂的杂环酯化合物。 本发明还涉及含有一定量的用于防止这种降解的杂环酯组合物的紫外可降解有机组合物。 这些稳定剂在通常在聚合物组合物中赋予的其它添加剂的存在下是有效的,包括例如颜料,着色剂,填料,增强剂等。 这些紫外线稳定剂也可以通过添加到聚合物熔体中或溶解在聚合物涂料中而被包含在有机组合物如聚合物中,涂覆在成形或模制品的外部,膜或挤出纤维上。