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1.发明申请USE OF SILICON-CONTAINING PARTICLES FOR PROTECTION OF INDUSTRIAL MATERIALS FROM UV RADIATION 审中-公开使用含硅颗粒保护紫外线辐射下的工业材料公开(公告)号：US20160152836A1
公开(公告)日：2016-06-02
申请号：US14950493
申请日：2015-11-24
CPC分类号： C09D5/03 , A61K8/25 , C01B33/029 , C08K3/34 , C08K3/36
摘要： Silicon-containing particles are used for protection of industrial materials, such as electrooptical layers or electrooptical components, from electromagnetic radiation in the UV range and optionally in the visible as far as the IR range, wherein the particles take the form of primary particles having a particle size in the range from 1 to 100 nm and may optionally take the form of clusters of the primary particles. A particular advantage is the possibility of matching the absorption of the electromagnetic radiation to the wavelength region to be absorbed that is of interest in a defined manner via the particle size and the particle size distribution. The silicon-containing particles can be used as biocompatible and biodegradable UV protection in industrial applications and compositions for industrial applications as formulations, such as preferably in coating compositions, such as paint.
摘要翻译： 含硅颗粒用于保护工业材料，例如电光层或电光元件，来自UV范围内的电磁辐射，并且任选地在可见的范围内至少为IR范围，其中颗粒采用具有 粒度在1至100nm的范围内，并且可以任选地采取初级颗粒的簇的形式。 特别的优点是可以通过粒度和粒度分布将电磁辐射的吸收与所规定的感兴趣的待吸收波长区域进行匹配。 含硅颗粒可用作工业应用中的生物相容性和可生物降解的UV保护，以及用于工业应用的组合物作为制剂，例如优选在涂料组合物中，例如涂料。
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2.发明申请公开(公告)号：US20140341794A1
公开(公告)日：2014-11-20
申请号：US14212191
申请日：2014-03-14
IPC分类号： C01B21/087
CPC分类号： C01B21/087 , C01C1/164
摘要： The invention relates to a process for preparing trisilylamine and polysilazanes in the liquid phase, in which ammonia dissolved in an inert solvent is initially introduced in a substoichiometric amount relative to monochlorosilane which is likewise present in an inert solvent. The reaction is carried out in a reactor in which trisilylamine formed according to the following equation 4NH3+3H3SiCl→3NH4Cl+(SiH3)3N and polysilazanes are formed. The reactor is subsequently depressurized and TSA is separated off in gaseous form from the product mixture. The TSA obtained is purified by filtration and distillation and obtained in high or very high purity. Further ammonia dissolved in an inert solvent is subsequently introduced into the reactor, using, together with the previously introduced amount of ammonia, a stoichiometric excess of ammonia relative to the amount of MCS previously present. Excess ammonia is subsequently discharged, inert gas is introduced and the bottom product mixture from the reactor is passed through a filter unit, with solid ammonium chloride being separated off and a liquid mixture of polysilazanes and solvent being obtained.
摘要翻译： 本发明涉及在液相中制备三甲胺和聚硅氮烷的方法，其中溶解在惰性溶剂中的氨相对于同样存在于惰性溶剂中的一氯硅烷，最初以亚化学计量的量引入。 该反应在其中形成根据下列等式4NH 3 + 3H 3 SiCl→3NH 4 Cl +（SiH 3）3 N和聚硅氮烷形成的三乙胺的反应器中进行。 随后将反应器减压，并将TSA从产物混合物中分离出气态。 通过过滤和蒸馏纯化获得的TSA，得到高纯度或非常高的纯度。 随后将溶解在惰性溶剂中的氨加入到反应器中，与先前导入的氨一起使用相对于先前存在的MCS的量的化学计量过量的氨。 随后排出过多的氨，引入惰性气体，将来自反应器的底部产物混合物通过过滤器单元，分离固体氯化铵，得到聚硅氮烷和溶剂的液体混合物。
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公开(公告)号：US20150259206A1
公开(公告)日：2015-09-17
申请号：US14658011
申请日：2015-03-13
IPC分类号： C01B21/087 , B01J19/18
CPC分类号： C01B21/087 , B01J2219/00006 , C07F7/10 , C08G77/62
摘要： A process for producing trisilylamine in the liquid phase by charging monochlorosilane in the liquid state in a solvent at elevated temperature, and reacting the monochlorosilane with NH3 in a stoichiometric excess is provided. Additionally provided is a production unit for carrying out the process.
摘要翻译： 提供在液相中通过在溶剂中在液态下加入一氯硅烷在高温下制备三甲胺的方法，并且使一氯硅烷与化学计量过量的NH 3反应。 另外提供了用于执行该过程的生产单元。
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4.发明申请公开(公告)号：US20150147256A1
公开(公告)日：2015-05-28
申请号：US14344801
申请日：2013-06-25
IPC分类号： C01B21/087 , B01J19/24
CPC分类号： C01B21/087 , B01J19/24 , B01J2219/24 , C08G77/62
摘要： The invention relates to a process for preparing trisilylamine and polysilazanes in the liquid phase, in which ammonia dissolved in an inert solvent is initially introduced in a substoichiometric amount relative to monochlorosilane which is likewise present in an inert solvent. The reaction is carried out in a reactor in which trisilylamine formed according to the following equation 4NH3+3H3SiCl→3NH4Cl+(SiH3)3N and polysilazanes are formed. The reactor is subsequently depressurized and TSA is separated off in gaseous form from the product mixture. The TSA obtained is purified by filtration and distillation and obtained in high or very high purity. Further ammonia dissolved in an inert solvent is subsequently introduced into the reactor, using, together with the previously introduced amount of ammonia, a stoichiometric excess of ammonia relative to the amount of MCS previously present. Excess ammonia is subsequently discharged, inert gas is introduced and the bottom product mixture from the reactor is passed through a filter unit, with solid ammonium chloride being separated off and a liquid mixture of polysilazanes and solvent being obtained.
摘要翻译： 本发明涉及在液相中制备三甲胺和聚硅氮烷的方法，其中溶解在惰性溶剂中的氨相对于同样存在于惰性溶剂中的一氯硅烷，最初以亚化学计量的量引入。 该反应在其中形成根据下列等式4NH 3 + 3H 3 SiCl→3NH 4 Cl +（SiH 3）3 N和聚硅氮烷形成的三乙胺的反应器中进行。 随后将反应器减压，并将TSA从产物混合物中分离出气态。 通过过滤和蒸馏纯化获得的TSA，得到高纯度或非常高的纯度。 随后将溶解在惰性溶剂中的氨加入到反应器中，与先前导入的氨一起使用相对于先前存在的MCS的量的化学计量过量的氨。 随后排出过多的氨，引入惰性气体，将来自反应器的底部产物混合物通过过滤器单元，分离出固体氯化铵，得到聚硅氮烷和溶剂的液体混合物。
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5.发明授权Process for the coupled preparation of trisilylamine and polysilazanes having a molar mass of up to 500 g/mol 有权具有摩尔质量高达500g / mol的三甲胺和聚硅氮烷的偶联制备方法公开(公告)号：US09446954B2
公开(公告)日：2016-09-20
申请号：US14345587
申请日：2013-06-05
IPC分类号： C01B21/087 , B01D3/14 , C08G77/62 , B01J19/24
CPC分类号： C01B21/087 , B01D3/143 , B01J19/24 , B01J2219/24 , C08G77/62
摘要： The invention relates to a process for preparing trisilylamine and polysilazanes in the liquid phase, in which ammonia is introduced in a superstoichiometric amount relative to 5 monochlorosilane which is present in an inert solvent. Here, a reaction in which trisilylamine and polysilazanes are formed proceeds. TSA is subsequently separated off in gaseous form from the product mixture. The TSA obtained is purified by filtration and distillation and obtained in high or very high purity. The bottom product mixture is conveyed from the reactor through a filter unit in which solid ammonium chloride is separated off to give a liquid mixture of polysilazanes and solvent. This is fed to a further distillation to recover solvent. As a result of the NH3 being introduced in a superstoichiometric amount relative to monochlorosilane, monochlorosilane is completely reacted in the reactor. This completely prevents the reaction of monochlorosilane with additional disilylamine formed in small amounts to form solid ammonium chloride in the downstream plant parts for purification of the TSA. The solutions filtered downstream of the reactor are accordingly completely free of solids.
摘要翻译： 本发明涉及一种在液相中制备三甲胺和聚硅氮烷的方法，其中相对于存在于惰性溶剂中的5个一氯硅烷，以超化学计量的量引入氨。 这里，形成三甲基胺和聚硅氮烷的反应。 TSA随后从产物混合物中分离出气态。 通过过滤和蒸馏纯化获得的TSA，得到高纯度或非常高的纯度。 底部产物混合物从反应器通过过滤器单元输送，其中分离固体氯化铵以得到聚硅氮烷和溶剂的液体混合物。 将其进料进一步蒸馏以回收溶剂。 作为相对于一氯硅烷以超化学计量量引入NH 3的结果，一氯硅烷在反应器中完全反应。 这完全防止一氯甲硅烷与少量形成的另外的二甲硅烷的反应在下游的植物部分中形成固体氯化铵，用于纯化TSA。 因此，在反应器下游过滤的溶液完全不含固体。
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