公开(公告)号：US20090023863A1

公开(公告)日：2009-01-22

申请号：US11664653

申请日：2005-09-09

申请人： Jun Kanega ,  Takashi Obara ,  Takashi Enokida

发明人： Jun Kanega ,  Takashi Obara ,  Takashi Enokida

IPC分类号： C08F214/26

CPC分类号： C08L27/12 ,  C08K5/14 ,  C08L2205/02 ,  C08L2666/04

摘要： A cross-linked fluorine-containing copolymer moldings applicable to a plasma irradiation step, which is molded as a peroxide cross-linking product of a fluorine-containing copolymer blend comprising a fluorine-containing elastomer copolymer and a fluorine-containing resin copolymer, which is a vinylidene fluoride-tetrafluoroethylene copolymer, both of the copolymers having reaction sites capable of reacting with a common peroxide-based cross-linking agent, respectively, has desired normal state physical properties and compression set value, even if applied to a plasma irradiation step, while reducing particle generation quantity of the fluorine-containing copolymers themselves.

摘要翻译： 一种适用于等离子体照射步骤的交联含氟共聚物成型体，其被模制为包含含氟弹性体共聚物和含氟树脂共聚物的含氟共聚物共混物的过氧化物交联产物，其为 偏氟乙烯 - 四氟乙烯共聚物，即使应用于等离子体照射工序也能够分别具有能够与常用的基于过氧化物的交联剂反应的具有反应部位的共聚物具有期望的正常状态物性和压缩永久变形量， 同时减少含氟共聚物本身的颗粒产生量。

公开(公告)号：US08357757B2

公开(公告)日：2013-01-22

申请号：US12085195

申请日：2006-10-23

申请人： Jun Kanega ,  Takashi Obara ,  Katsumi Suzuki ,  Takashi Enokida

发明人： Jun Kanega ,  Takashi Obara ,  Katsumi Suzuki ,  Takashi Enokida

IPC分类号： C08L27/14 ,  C08F8/00

CPC分类号： C08L27/16 ,  C08K5/0025 ,  C08K5/14 ,  C08L27/18 ,  C08L2205/02 ,  C08L2666/04

摘要： A fluorine-containing alloyed copolymer, which comprises a fluorine-containing elastomer copolymer having a fluorine content of not less than 64% by weight, and a resinous tetrafluoroethylene-perfluoro(alkyl vinyl ether) copolymer having an amount of heat of crystal fusion ΔH of not more than 10 J/g, can give crosslinked moldings having a distinguished plasma resistance against both CF4 plasma treatment and O2 plasma treatment, and also a distinguished cracking resistance at the plasma irradiation, and showing necessary normal state physical properties and compression set when used as seals, and capable of providing soft seals of low hardness, and attaining molding at relatively low temperatures.

摘要翻译： 含有氟含量为64重量％以上的含氟弹性体共聚物和具有结晶熔融热量Dgr的树脂四氟乙烯 - 全氟（烷基乙烯基醚）共聚物的含氟合金共聚物， H不超过10J / g，可以提供对CF4等离子体处理和O 2等离子体处理都具有显着等离子体电阻的交联模制品，并且还可以在等离子体照射下具有显着的抗裂性，并且显示必要的正常状态物理性能和压缩永久变形 用作密封件，并且能够提供低硬度的软密封，并且在相对低的温度下进行成型。

公开(公告)号：US20090312473A1

公开(公告)日：2009-12-17

申请号：US12085195

申请日：2006-10-23

申请人： Jun Kanega ,  Takashi Obara ,  Katsumi Suzuki ,  Takashi Enokida

发明人： Jun Kanega ,  Takashi Obara ,  Katsumi Suzuki ,  Takashi Enokida

IPC分类号： C08K5/14 ,  C08L27/12

CPC分类号： C08L27/16 ,  C08K5/0025 ,  C08K5/14 ,  C08L27/18 ,  C08L2205/02 ,  C08L2666/04

摘要： A fluorine-containing alloyed copolymer, which comprises a fluorine-containing elastomer copolymer having a fluorine content of not less than 64% by weight, and a resinous tetrafluoroethylene-perfluoro(alkyl vinyl ether) copolymer having an amount of heat of crystal fusion ΔH of not more than 10 J/g, can give crosslinked moldings having a distinguished plasma resistance against both CF4 plasma treatment and O2 plasma treatment, and also a distinguished cracking resistance at the plasma irradiation, and showing necessary normal state physical properties and compression set when used as seals, and capable of providing soft seals of low hardness, and attaining molding at relatively low temperatures.

摘要翻译： 含有氟含量为64重量％以上的含氟弹性体共聚物的氟系合金化共聚物和具有结晶熔融热量DeltaH的树脂四氟乙烯 - 全氟（烷基乙烯基醚）共聚物， 不超过10J / g，可以提供对CF4等离子体处理和O 2等离子体处理具有突出的等离子体电阻的交联模制品，以及在等离子体照射下的显着的耐龟裂性，并且在使用时显示必要的正常状态物理性能和压缩永久变形 作为密封件，并且能够提供低硬度的软密封，并且在相对低的温度下实现模制。

公开(公告)号：US07420017B2

公开(公告)日：2008-09-02

申请号：US10550479

申请日：2004-03-12

申请人： Jun Kanega ,  Shigeru Kumamoto ,  Takashi Enokida

发明人： Jun Kanega ,  Shigeru Kumamoto ,  Takashi Enokida

IPC分类号： C08F114/18

CPC分类号： C08F214/18 ,  C08F6/22 ,  C08L27/12

摘要： A process for preparing a fluorine-containing copolymer by an emulsion polymerization method in the presence of aqueous ammonia as a pH modifier, and a molded article obtainable by melt molding or crosslinking molding the fluorine-containing copolymer. In preparing the fluorine-containing copolymer by coagulation of the fluorine-containing copolymer contained in a fluorine-containing copolymer dispersed aqueous solution, it is preferred to use a cationic surfactant and a water soluble organic solvent as a coagulating agent used for the above coagulation. The surfactant is preferably represented by the, formula (R4N+)X− wherein R is an alkyl group of 1 to 22 carbon atoms, a fluoroalkyl group obtainable by fluorine substituting at least a part of hydrogen atoms present in the above alkyl group or hydrogen, four R's may be the same or different provided that they are not hydrogen atoms simultaneously, and X is a halogen atom. The process for preparing a fluorine-containing copolymer provides a decrease in a concentration of metal elements, which act as an impurity source, for example, having a metal element concentration of not more than 1 ppm.

摘要翻译： 在氨水作为pH调节剂的存在下，通过乳液聚合法制备含氟共聚物的方法，以及通过熔融模塑或交联成型含氟共聚物得到的成型体。 在通过含氟共聚物分散水溶液中含有的含氟共聚物的凝结制备含氟共聚物时，优选使用阳离子性表面活性剂和水溶性有机溶剂作为上述凝结剂所使用的凝固剂。 表面活性剂优选由式（R 4 S）N - （O）X-X）表示，其中R是1至22个碳原子的烷基 可以通过氟取代存在于上述烷基中的至少一部分氢原子的氟代烷基或氢，四个R可以相同或不同，条件是它们不同时为氢原子，X为卤素原子。 制备含氟共聚物的方法使作为杂质源的金属元素的浓度降低，例如金属元素浓度不大于1ppm。

公开(公告)号：US20060235157A1

公开(公告)日：2006-10-19

申请号：US10550479

申请日：2004-03-12

申请人： Jun Kanega ,  Shigeru Kumamoto ,  Takashi Enokida

发明人： Jun Kanega ,  Shigeru Kumamoto ,  Takashi Enokida

IPC分类号： C08L27/12

CPC分类号： C08F214/18 ,  C08F6/22 ,  C08L27/12

摘要： A process for preparing a fluorine containing copolymer by an emulsion polymerization method in the presence of aqueous ammonia as a pH modifier, and a molded article obtainable by melt molding or crosslinking molding the fluorine containing copolymer are disclosed. In preparing the fluorine containing copolymer by coagulation of the fluorine containing copolymer contained in a fluorine containing copolymer dispersed aqueous solution, it is preferred to use a cationic surfactant and a water soluble organic solvent as a coagulating agent used for the above coagulation. The surfactant is preferably represented by the formula (R4N+)X− wherein R is an alkyl group of 1 to 22 carbon atoms, a fluoroalkyl group obtainable by fluorine substituting at least a part of hydrogen atoms present in the above alkyl group or hydrogen, four R's may be the same or different provided that they are not hydrogen atoms simultaneously, and X is a halogen atom. The process for preparing a fluorine containing copolymer provides a decrease in a concentration of metal elements, which act as an impurity source, for example, having a metal element concentration of not more than 1 ppm.

摘要翻译： 公开了一种通过乳液聚合法在氨水作为pH调节剂的存在下制备含氟共聚物的方法，以及通过熔融模塑或交联模塑含氟共聚物得到的成型制品。 在通过含氟共聚物分散水溶液中含有的含氟共聚物的凝聚来制备含氟共聚物时，优选使用阳离子表面活性剂和水溶性有机溶剂作为上述凝结用的凝结剂。 表面活性剂优选由下式（R 4 N - ）其中R是1至22个碳原子的烷基， 可以通过氟取代存在于上述烷基中的氢原子的至少一部分的氟烷基或氢，四个R可以相同或不同，条件是它们不同时为氢原子，X为卤素原子。 制备含氟共聚物的方法提供了作为杂质源的金属元素的浓度降低，例如金属元素浓度不大于1ppm。

公开(公告)号：US20080108769A1

公开(公告)日：2008-05-08

申请号：US11791307

申请日：2005-11-18

申请人： Jun Kanega ,  Ji-Shan Jin ,  Katsumi Suzuki ,  Takashi Enokida ,  Keisuke Kokin

发明人： Jun Kanega ,  Ji-Shan Jin ,  Katsumi Suzuki ,  Takashi Enokida ,  Keisuke Kokin

IPC分类号： C08F16/12

CPC分类号： C08F214/184

摘要： A fluorine-containing copolymer, which comprises a hydroxyl-terminated fluorine-containing vinyl ether, represented by the following general formula: CF2═CFORfCH2OH (where Rf is a fluoroalkylene group, a fluoroalkyl ether group, or a fluoroalkoxyfluoroalkyl ether group, having 1-25 carbon atoms), and at least one of other fluorine-containing unsaturated monomers, where a high-molecular weight fluorine-containing copolymer having a melt viscosity (230° C.) of 0.1-100 g/10 min. is insoluble in a solvent, and can be used suitably for melt molding, whereas a low-molecular weight fluorine-containing copolymer having a glass transition temperature Tg of 20° C., or higher, and a number average molecular weight Mn of 1,000, or more is soluble in a solvent, and can be used suitably for coating agents, etc. The fluorine-containing copolymer has a high light transmissivity, and a low refractive index, and also has, as such, a good adhesiveness to various substrated without any surface treatment, any adhesives, or the like.

摘要翻译： 包含由以下通式表示的羟基封端的含氟乙烯基醚的含氟共聚物：<？in-line-formula description =“In-line formula”end =“lead”？> CF _{其中R f是氟代亚烷基，氟代烷基醚 基团，或具有1-25个碳原子的氟代烷氧基氟烷基醚基团）和至少一种其它含氟不饱和单体，其中熔体粘度（230℃）为0.1的高分子量含氟共聚物 -100g / 10min。 不溶于溶剂，可适用于熔融成型，而玻璃化转变温度Tg为20℃以上，数均分子量Mn为1000的低分子量含氟共聚物， 以上的溶剂可溶于溶剂，可以适用于涂布剂等。含氟共聚物透光性高，折射率低，并且具有良好的粘合性，适合各种不带底漆 任何表面处理，任何粘合剂等。}

公开(公告)号：US20060003175A1

公开(公告)日：2006-01-05

申请号：US11128753

申请日：2005-05-13

申请人： Jun Kanega ,  Takashi Enokida

发明人： Jun Kanega ,  Takashi Enokida

IPC分类号： B32B27/08

CPC分类号： B32B27/30 ,  B29C59/14 ,  B29C65/02 ,  B29C65/18 ,  B29C66/02 ,  B29C66/71 ,  B29K2027/18 ,  B32B25/08 ,  B32B27/34 ,  B32B27/40 ,  Y10T428/31725 ,  B29K2077/00 ,  B29K2075/00 ,  B29K2033/08 ,  B29K2027/12 ,  B29K2021/00

摘要： A fluoropolymer molding, which comprises a perfluoropolymer capable of undergoing low-temperature melt molding and having a calorimetric value of crystal fusion of not more than 10 J/g and an MFR (230° C.) of 0.1 to 100 g/min. the molding having a surface modified to have bonds of nitrogen atom origin, where the modification to the surface having bonds of nitrogen atom origin is carried out by electric discharge treatment in an ammonia gas atmosphere. The thus obtained perfluoropolymer molding with a high fluorine content of not less than 72 wt. % can be easily formed into a laminate with other substrates.

摘要翻译： 一种含氟聚合物模制品，其包含能够进行低温熔融模塑并且具有不超过10J / g的晶体熔化的热值和MFR（230℃）为0.1至100g / min的全氟聚合物。 具有被修饰成具有氮原子键的表面的成型体，其中通过在氨气气氛中的放电处理进行对具有氮原子键的键的表面的改性。 由此获得的氟含量高于72重量％的全氟聚合物成型体 ％可以容易地形成为具有其它基底的层压体。

公开(公告)号：US07932335B2

公开(公告)日：2011-04-26

申请号：US11793861

申请日：2007-04-20

申请人： Mitsuru Maeda ,  Takashi Enokida ,  Keisuke Kokin ,  Satoru Saito ,  Jun Kanega

发明人： Mitsuru Maeda ,  Takashi Enokida ,  Keisuke Kokin ,  Satoru Saito ,  Jun Kanega

IPC分类号： C08F16/24

CPC分类号： C08F214/222 ,  C08F214/22 ,  C08K5/0025 ,  Y10S277/915 ,  Y10S277/945 ,  Y10T428/215 ,  C08L27/16

摘要： A fluorine-containing elastomer having a copolymer composition, which comprises (a) 50-85 mol. % of vinylidene fluoride, (b) 0-25 mol. % of tetrafluoroethylene, (c) 7-20 mol. % of perfluoro(methyl vinyl ether), (d) 2.5-15 mol. % of CF2═CFO[CF2CF(CF3)O]nCF3 (n: 2-6), (e) 0.1-2 mol. % of CF2═CFO[CF2CF(CF3)O]mCF2CF3 (m: 2-6), and (f) 0.1-2 mol. % of RfX (Rf: an unsaturated fluorohydrocarbon group having 2-8 carbon atoms, which can contain at least one ether bond, X: bromine or iodine), can provide a fluorine-containing elastomer composition, which comprises 100 parts by weight of the fluorine-containing elastomer, 0.1-10 parts by weight of an organic peroxide, 0.1-10 parts by weight of a polyfunctional unsaturated compound, and at least 2 parts by weight of an acid acceptor. The composition can give vulcanizates having a distinguished elongation at break at high temperatures such as 100° C., and distinguished compression set characteristics at low temperatures such as 0° C.

摘要翻译： 具有共聚物组成的含氟弹性体，其包含（a）50-85mol。 ％偏二氟乙烯，（b）0-25mol。 ％的四氟乙烯，（c）7-20摩尔。 ％的全氟（甲基乙烯基醚），（d）2.5-15mol。 CF 2 = CFO [CF 2 CF（CF 3）O] n CF 3（n = 2-6）的％，（e）0.1-2mol。 CF 2 = CFO [CF 2 CF（CF 3）O] m CF 2 CF 3（m：2-6）的％，和（f）0.1-2mol。 RfX（Rf：具有2-8个碳原子的不饱和氟代烃基，其可以含有至少一个醚键，X：溴或碘）的％可以提供含氟弹性体组合物，其包含100重量份的 含氟弹性体，0.1-10重量份有机过氧化物，0.1-10重量份多官能不饱和化合物和至少2重量份酸受体。 组合物可以在高温如100℃下得到具有明显的断裂伸长率的硫化橡胶，并且在低温如0℃下具有显着的压缩变形特性。

公开(公告)号：US20100004415A1

公开(公告)日：2010-01-07

申请号：US11793861

申请日：2007-04-20

申请人： Mitsuru Maeda ,  Takashi Enokida ,  Keisuke Kokin ,  Satoru Saito ,  Jun Kanega

发明人： Mitsuru Maeda ,  Takashi Enokida ,  Keisuke Kokin ,  Satoru Saito ,  Jun Kanega

IPC分类号： C08F16/24

CPC分类号： C08F214/222 ,  C08F214/22 ,  C08K5/0025 ,  Y10S277/915 ,  Y10S277/945 ,  Y10T428/215 ,  C08L27/16

摘要： A fluorine-containing elastomer having a copolymer composition, which comprises (a) 50-85 mol. % of vinylidene fluoride, (b) 0-25 mol. % of tetrafluoroethylene, (c) 7-20 mol. % of perfluoro(methyl vinyl ether), (d) 2.5-15 mol. % of CF2═CFO[CF2CF(CF3)O]nCF3 (n: 2-6), (e) 0.1-2 mol. % of CF2═CFO[CF2CF(CF3)O]mCF2CF3 (m: 2-6), and (f) 0.1-2 mol. % of RfX (Rf: an unsaturated fluorohydrocarbon group having 2-8 carbon atoms, which can contain at least one ether bond, X: bromine or iodine), can provide a fluorine-containing elastomer composition, which comprises 100 parts by weight of the fluorine-containing elastomer, 0.1-10 parts by weight of an organic peroxide, 0.1-10 parts by weight of a polyfunctional unsaturated compound, and at least 2 parts by weight of an acid acceptor. The composition can give vulcanizates having a distinguished elongation at break at high temperatures such as 100° C., and distinguished compression set characteristics at low temperatures such as 0° C.

摘要翻译： 具有共聚物组成的含氟弹性体，其包含（a）50-85mol。 ％偏二氟乙烯，（b）0-25mol。 ％的四氟乙烯，（c）7-20摩尔。 ％的全氟（甲基乙烯基醚），（d）2.5-15mol。 ％CF 2 CF 2 CF 2 CF（CF 3）O] n CF 3（n = 2-6），（e）0.1-2mol。 ％CF 2 CF 2 CF 2 CF（CF 3）O] m CF 2 CF 3（m：2-6），（f）0.1-2mol。 RfX（Rf：具有2-8个碳原子的不饱和氟代烃基，其可以含有至少一个醚键，X：溴或碘）的％可以提供含氟弹性体组合物，其包含100重量份的 含氟弹性体，0.1-10重量份有机过氧化物，0.1-10重量份多官能不饱和化合物和至少2重量份酸受体。 组合物可以在高温如100℃下得到具有明显的断裂伸长率的硫化橡胶，并且在低温如0℃下具有显着的压缩变形特性。

公开(公告)号：US20090247691A1

公开(公告)日：2009-10-01

申请号：US12316179

申请日：2008-12-10

申请人： Jun Kanega ,  Ji-Shan Jin ,  Katsumi Suzuki ,  Takashi Enokida ,  Keisuke Kokin

发明人： Jun Kanega ,  Ji-Shan Jin ,  Katsumi Suzuki ,  Takashi Enokida ,  Keisuke Kokin

IPC分类号： C08L27/12 ,  C08F16/24

CPC分类号： C08G65/3355 ,  C07F9/4006 ,  C08G65/007

摘要： A fluorine-containing copolymer, which comprises a hydroxyl-terminated fluorine-containing vinyl ether, represented by the following general formula: CF2═CFORfCH2OH (where Rf is a fluoroalkylene group, a fluoroalkyl ether group, or a fluoroalkoxyfluoroalkyl ether group, having 1-25 carbon atoms), and at least one of other fluorine-containing unsaturated monomers, where a high-molecular weight fluorine-containing copolymer having a melt viscosity (230° C.) of 0.1-100 g/10 min. is insoluble in a solvent, and can be used suitably for melt molding, whereas a low-molecular weight fluorine-containing copolymer having a glass transition temperature Tg of 20° C., or higher, and a number average molecular weight Mn of 1,000, or more is soluble in a solvent, and can be used suitably for coating agents, etc. The fluorine-containing copolymer has a high light transmissivity, and a low refractive index, and also has, as such, a good adhesiveness to various substrated without any surface treatment, any adhesives, or the like.

摘要翻译： 包含由下述通式表示的羟基封端的含氟乙烯基醚的含氟共聚物：<？在线式描述=“在线式”末端=“lead”→CF 2 -CFORfCH 2 OH （其中，Rf为具有1-25个碳原子的氟代烷基，氟代烷基醚基或氟代烷氧基氟代烷基醚基），和 至少一种其它含氟不饱和单体，其中熔体粘度（230℃）为0.1-100g / 10min的高分子量含氟共聚物。 不溶于溶剂，可适用于熔融成型，而玻璃化转变温度Tg为20℃以上，数均分子量Mn为1000的低分子量含氟共聚物， 以上的溶剂可溶于溶剂，可以适合用于涂布剂等。含氟共聚物透光性高，折射率低，并且具有良好的粘合性，适合各种不含底物 任何表面处理，任何粘合剂等。