公开(公告)号：US07420017B2

公开(公告)日：2008-09-02

申请号：US10550479

申请日：2004-03-12

申请人： Jun Kanega ,  Shigeru Kumamoto ,  Takashi Enokida

发明人： Jun Kanega ,  Shigeru Kumamoto ,  Takashi Enokida

IPC分类号： C08F114/18

CPC分类号： C08F214/18 ,  C08F6/22 ,  C08L27/12

摘要： A process for preparing a fluorine-containing copolymer by an emulsion polymerization method in the presence of aqueous ammonia as a pH modifier, and a molded article obtainable by melt molding or crosslinking molding the fluorine-containing copolymer. In preparing the fluorine-containing copolymer by coagulation of the fluorine-containing copolymer contained in a fluorine-containing copolymer dispersed aqueous solution, it is preferred to use a cationic surfactant and a water soluble organic solvent as a coagulating agent used for the above coagulation. The surfactant is preferably represented by the, formula (R4N+)X− wherein R is an alkyl group of 1 to 22 carbon atoms, a fluoroalkyl group obtainable by fluorine substituting at least a part of hydrogen atoms present in the above alkyl group or hydrogen, four R's may be the same or different provided that they are not hydrogen atoms simultaneously, and X is a halogen atom. The process for preparing a fluorine-containing copolymer provides a decrease in a concentration of metal elements, which act as an impurity source, for example, having a metal element concentration of not more than 1 ppm.

摘要翻译： 在氨水作为pH调节剂的存在下，通过乳液聚合法制备含氟共聚物的方法，以及通过熔融模塑或交联成型含氟共聚物得到的成型体。 在通过含氟共聚物分散水溶液中含有的含氟共聚物的凝结制备含氟共聚物时，优选使用阳离子性表面活性剂和水溶性有机溶剂作为上述凝结剂所使用的凝固剂。 表面活性剂优选由式（R 4 S）N - （O）X-X）表示，其中R是1至22个碳原子的烷基 可以通过氟取代存在于上述烷基中的至少一部分氢原子的氟代烷基或氢，四个R可以相同或不同，条件是它们不同时为氢原子，X为卤素原子。 制备含氟共聚物的方法使作为杂质源的金属元素的浓度降低，例如金属元素浓度不大于1ppm。

公开(公告)号：US5587413A

公开(公告)日：1996-12-24

申请号：US583642

申请日：1996-01-05

申请人： Takashi Enokida ,  Akihiro Naraki ,  Eiichi Yamashita ,  Haruyoshi Tatsu

发明人： Takashi Enokida ,  Akihiro Naraki ,  Eiichi Yamashita ,  Haruyoshi Tatsu

IPC分类号： B32B15/06 ,  B32B15/08 ,  B32B15/082 ,  C07C275/14 ,  C07C275/40 ,  C08G18/80 ,  C08K5/17 ,  C08K5/205 ,  C08K5/29 ,  C08L27/12 ,  C09K3/10 ,  C08K5/33

CPC分类号： C09K3/1009 ,  B32B15/06 ,  C07C275/40 ,  C08K5/205 ,  C09K2200/0208 ,  C09K2200/0239 ,  Y10T428/3154 ,  Y10T428/31544

摘要： A fluorine rubber composition comprising a fluorine rubber and a polyfluoroalkyl group-containing block isocyanate compound represented by the following general formula:Rf(CH.sub.2)nXCONHRNHCOO(N.dbd.C--R.sup.2)mR.sup.1where Rf is a polyfluoroalkyl group having 4 to 20 carbon atoms; R is a divalent organic group; R.sup.1 is a lower alkyl group or phenyl group; R.sup.2 is a lower alkyl group; X is NH or O; n is an integer of 1 to 4 and m is 0 or 1, has a good vulcanization bond to metals without any substantial decrease in the rubber stretchability properly owned by the fluorine rubber.

摘要翻译： 一种氟橡胶组合物，其包含氟橡胶和由以下通式表示的含多氟烷基的嵌段异氰酸酯化合物：Rf（CH2）nXCONHRNHCOO（N = C-R2）mR1其中Rf为碳原子数为4〜20的多氟烷基; R是二价有机基团; R1是低级烷基或苯基; R2是低级烷基; X是NH或O; n为1〜4的整数，m为0或1，与金属具有良好的硫化键，而且橡胶拉伸性能不会显着降低。

公开(公告)号：US20090023863A1

公开(公告)日：2009-01-22

申请号：US11664653

申请日：2005-09-09

申请人： Jun Kanega ,  Takashi Obara ,  Takashi Enokida

发明人： Jun Kanega ,  Takashi Obara ,  Takashi Enokida

IPC分类号： C08F214/26

CPC分类号： C08L27/12 ,  C08K5/14 ,  C08L2205/02 ,  C08L2666/04

摘要： A cross-linked fluorine-containing copolymer moldings applicable to a plasma irradiation step, which is molded as a peroxide cross-linking product of a fluorine-containing copolymer blend comprising a fluorine-containing elastomer copolymer and a fluorine-containing resin copolymer, which is a vinylidene fluoride-tetrafluoroethylene copolymer, both of the copolymers having reaction sites capable of reacting with a common peroxide-based cross-linking agent, respectively, has desired normal state physical properties and compression set value, even if applied to a plasma irradiation step, while reducing particle generation quantity of the fluorine-containing copolymers themselves.

摘要翻译： 一种适用于等离子体照射步骤的交联含氟共聚物成型体，其被模制为包含含氟弹性体共聚物和含氟树脂共聚物的含氟共聚物共混物的过氧化物交联产物，其为 偏氟乙烯 - 四氟乙烯共聚物，即使应用于等离子体照射工序也能够分别具有能够与常用的基于过氧化物的交联剂反应的具有反应部位的共聚物具有期望的正常状态物性和压缩永久变形量， 同时减少含氟共聚物本身的颗粒产生量。

公开(公告)号：US20060235157A1

公开(公告)日：2006-10-19

申请号：US10550479

申请日：2004-03-12

申请人： Jun Kanega ,  Shigeru Kumamoto ,  Takashi Enokida

发明人： Jun Kanega ,  Shigeru Kumamoto ,  Takashi Enokida

IPC分类号： C08L27/12

CPC分类号： C08F214/18 ,  C08F6/22 ,  C08L27/12

摘要： A process for preparing a fluorine containing copolymer by an emulsion polymerization method in the presence of aqueous ammonia as a pH modifier, and a molded article obtainable by melt molding or crosslinking molding the fluorine containing copolymer are disclosed. In preparing the fluorine containing copolymer by coagulation of the fluorine containing copolymer contained in a fluorine containing copolymer dispersed aqueous solution, it is preferred to use a cationic surfactant and a water soluble organic solvent as a coagulating agent used for the above coagulation. The surfactant is preferably represented by the formula (R4N+)X− wherein R is an alkyl group of 1 to 22 carbon atoms, a fluoroalkyl group obtainable by fluorine substituting at least a part of hydrogen atoms present in the above alkyl group or hydrogen, four R's may be the same or different provided that they are not hydrogen atoms simultaneously, and X is a halogen atom. The process for preparing a fluorine containing copolymer provides a decrease in a concentration of metal elements, which act as an impurity source, for example, having a metal element concentration of not more than 1 ppm.

摘要翻译： 公开了一种通过乳液聚合法在氨水作为pH调节剂的存在下制备含氟共聚物的方法，以及通过熔融模塑或交联模塑含氟共聚物得到的成型制品。 在通过含氟共聚物分散水溶液中含有的含氟共聚物的凝聚来制备含氟共聚物时，优选使用阳离子表面活性剂和水溶性有机溶剂作为上述凝结用的凝结剂。 表面活性剂优选由下式（R 4 N - ）其中R是1至22个碳原子的烷基， 可以通过氟取代存在于上述烷基中的氢原子的至少一部分的氟烷基或氢，四个R可以相同或不同，条件是它们不同时为氢原子，X为卤素原子。 制备含氟共聚物的方法提供了作为杂质源的金属元素的浓度降低，例如金属元素浓度不大于1ppm。

公开(公告)号：US4783817A

公开(公告)日：1988-11-08

申请号：US002242

申请日：1987-01-12

申请人： Hareo Hamada ,  Takashi Enokida ,  Tanetoshi Miura ,  Minoru Takahashi ,  Takashi Kuribayashi ,  Kinichiro Asami ,  Yoshitaka Oguri

发明人： Hareo Hamada ,  Takashi Enokida ,  Tanetoshi Miura ,  Minoru Takahashi ,  Takashi Kuribayashi ,  Kinichiro Asami ,  Yoshitaka Oguri

IPC分类号： H04R3/00 ,  G10K11/16 ,  G10K11/178 ,  H03B29/00

CPC分类号： G10K11/1784 ,  G10K2210/112 ,  G10K2210/3045 ,  G10K2210/3219 ,  G10K2210/503 ,  G10K2210/506

摘要： An electronic noise attenuation system for attenuation of non-steady noise occurring in a propagation passage such a duct line by conducting adaptive controls by use of a computer system including a digital filter therein. Sensing microphones M.sub.1, M.sub.2 are located in the propagation passage with a cancellation sound source S therebetween at positions where the transfer functions Hr, Ht of a sound wave generated from the cancellation sound source are equivalent to each other. The output signal of the sensing microphone M.sub.1 and the phase-inverted version of the output signal of the sensing microphone M.sub.2 are input via an add circuit to the control part of the system. The system can prevent the occurrence of an acoustic feedback from the cancellation sound source to the sensing microphone M.sub.1 so as to realize a stable and highly accurate noise attenuation.

摘要翻译： 一种电子噪声衰减系统，用于通过使用包括数字滤波器的计算机系统进行自适应控制来衰减在诸如管道线路的传播通道中发生的非稳定噪声。 感测麦克风M1，M2位于传播路径中，其中取消声源S在从取消声源产生的声波的传递函数Hr，Ht彼此相等的位置处。 感测麦克风M1的输出信号和感测麦克风M2的输出信号的相位反转版本经由加法电路输入到系统的控制部分。 该系统可以防止从消除声源到感测麦克风M1的声反馈的发生，以实现稳定和高精度的噪声衰减。

公开(公告)号：US08357757B2

公开(公告)日：2013-01-22

申请号：US12085195

申请日：2006-10-23

申请人： Jun Kanega ,  Takashi Obara ,  Katsumi Suzuki ,  Takashi Enokida

发明人： Jun Kanega ,  Takashi Obara ,  Katsumi Suzuki ,  Takashi Enokida

IPC分类号： C08L27/14 ,  C08F8/00

CPC分类号： C08L27/16 ,  C08K5/0025 ,  C08K5/14 ,  C08L27/18 ,  C08L2205/02 ,  C08L2666/04

摘要： A fluorine-containing alloyed copolymer, which comprises a fluorine-containing elastomer copolymer having a fluorine content of not less than 64% by weight, and a resinous tetrafluoroethylene-perfluoro(alkyl vinyl ether) copolymer having an amount of heat of crystal fusion ΔH of not more than 10 J/g, can give crosslinked moldings having a distinguished plasma resistance against both CF4 plasma treatment and O2 plasma treatment, and also a distinguished cracking resistance at the plasma irradiation, and showing necessary normal state physical properties and compression set when used as seals, and capable of providing soft seals of low hardness, and attaining molding at relatively low temperatures.

摘要翻译： 含有氟含量为64重量％以上的含氟弹性体共聚物和具有结晶熔融热量Dgr的树脂四氟乙烯 - 全氟（烷基乙烯基醚）共聚物的含氟合金共聚物， H不超过10J / g，可以提供对CF4等离子体处理和O 2等离子体处理都具有显着等离子体电阻的交联模制品，并且还可以在等离子体照射下具有显着的抗裂性，并且显示必要的正常状态物理性能和压缩永久变形 用作密封件，并且能够提供低硬度的软密封，并且在相对低的温度下进行成型。

公开(公告)号：US20110251427A1

公开(公告)日：2011-10-13

申请号：US12310641

申请日：2007-07-17

申请人： Daisuke Murai ,  Takashi Enokida ,  Seiichiro Murata

发明人： Daisuke Murai ,  Takashi Enokida ,  Seiichiro Murata

IPC分类号： C07C53/21 ,  C07C51/58 ,  C07C53/50

CPC分类号： C08F2/24 ,  C07C51/04 ,  C07C51/412 ,  C07C51/58 ,  C07C53/21 ,  C08F14/18 ,  C08F114/02 ,  C08F2/16 ,  C08F2/02

摘要： A polyfluoroalkane carboxylic acid represented by the following general formula: CnF2n+1(CH2CF2)m(CF2CF2)l−1CF2COOM (M: an alkali metal, a NH4 group or H; n: an integer of 1 to 6; m: an integer of 1 to 4; and l: 1 or 2) can be produced by hydrolysis reaction of polyfluoroalkane carboxylic acid fluoride represented by the following general formula: CnF2n+1(CH2CF2)m(CF2CF2)l−1CF2COF , where its carboxylic acid salt can be formed as an alkali metal salt, or a NH4 salt. The polyfluoroalkane carboxylic acid (or its salt) can act as a surfactant having distinguished monomer emulsificability and latex stability when used as an emulsifying agent or as a dispersing agent for polymerization reaction of fluorine-containing monomers, or as an effective surfactant capable of enhancing the micelles solubility of fluorine-containing monomers such as vinylidene fluoride, etc., when used as an emulsifying agent or a dispersing agent for homopolymerization or copolymerization reaction of vinylidene fluoride.

摘要翻译： 由以下通式表示的多氟烷烃羧酸：CnF 2 n + 1（CH 2 CF 2）m（CF 2 CF 2）1-1CF 2 COOM（M：碱金属，NH 4基或H; n：1〜6的整数; m：整数 1〜4;以及1：1或2）可以通过以下通式表示的多氟烷基羧酸氟化物的水解反应制备：CnF2n + 1（CH2CF2）m（CF2CF2 )1-1CF2COF，其中羧酸盐可以 形成为碱金属盐或NH 4盐。 当用作乳化剂或用作含氟单体的聚合反应的分散剂时，多氟烷烃羧酸（或其盐）可以用作具有突出的单体乳化性和胶乳稳定性的表面活性剂，或作为能够增强 当用作乳化剂或偏氟乙烯的均聚或共聚反应的分散剂时，含氟单体如偏二氟乙烯等的胶束溶解度。

公开(公告)号：US20080108769A1

公开(公告)日：2008-05-08

申请号：US11791307

申请日：2005-11-18

申请人： Jun Kanega ,  Ji-Shan Jin ,  Katsumi Suzuki ,  Takashi Enokida ,  Keisuke Kokin

发明人： Jun Kanega ,  Ji-Shan Jin ,  Katsumi Suzuki ,  Takashi Enokida ,  Keisuke Kokin

IPC分类号： C08F16/12

CPC分类号： C08F214/184

摘要： A fluorine-containing copolymer, which comprises a hydroxyl-terminated fluorine-containing vinyl ether, represented by the following general formula: CF2═CFORfCH2OH (where Rf is a fluoroalkylene group, a fluoroalkyl ether group, or a fluoroalkoxyfluoroalkyl ether group, having 1-25 carbon atoms), and at least one of other fluorine-containing unsaturated monomers, where a high-molecular weight fluorine-containing copolymer having a melt viscosity (230° C.) of 0.1-100 g/10 min. is insoluble in a solvent, and can be used suitably for melt molding, whereas a low-molecular weight fluorine-containing copolymer having a glass transition temperature Tg of 20° C., or higher, and a number average molecular weight Mn of 1,000, or more is soluble in a solvent, and can be used suitably for coating agents, etc. The fluorine-containing copolymer has a high light transmissivity, and a low refractive index, and also has, as such, a good adhesiveness to various substrated without any surface treatment, any adhesives, or the like.

摘要翻译： 包含由以下通式表示的羟基封端的含氟乙烯基醚的含氟共聚物：<？in-line-formula description =“In-line formula”end =“lead”？> CF _{其中R f是氟代亚烷基，氟代烷基醚 基团，或具有1-25个碳原子的氟代烷氧基氟烷基醚基团）和至少一种其它含氟不饱和单体，其中熔体粘度（230℃）为0.1的高分子量含氟共聚物 -100g / 10min。 不溶于溶剂，可适用于熔融成型，而玻璃化转变温度Tg为20℃以上，数均分子量Mn为1000的低分子量含氟共聚物， 以上的溶剂可溶于溶剂，可以适用于涂布剂等。含氟共聚物透光性高，折射率低，并且具有良好的粘合性，适合各种不带底漆 任何表面处理，任何粘合剂等。}

公开(公告)号：US20060003175A1

公开(公告)日：2006-01-05

申请号：US11128753

申请日：2005-05-13

申请人： Jun Kanega ,  Takashi Enokida

发明人： Jun Kanega ,  Takashi Enokida

IPC分类号： B32B27/08

CPC分类号： B32B27/30 ,  B29C59/14 ,  B29C65/02 ,  B29C65/18 ,  B29C66/02 ,  B29C66/71 ,  B29K2027/18 ,  B32B25/08 ,  B32B27/34 ,  B32B27/40 ,  Y10T428/31725 ,  B29K2077/00 ,  B29K2075/00 ,  B29K2033/08 ,  B29K2027/12 ,  B29K2021/00

摘要： A fluoropolymer molding, which comprises a perfluoropolymer capable of undergoing low-temperature melt molding and having a calorimetric value of crystal fusion of not more than 10 J/g and an MFR (230° C.) of 0.1 to 100 g/min. the molding having a surface modified to have bonds of nitrogen atom origin, where the modification to the surface having bonds of nitrogen atom origin is carried out by electric discharge treatment in an ammonia gas atmosphere. The thus obtained perfluoropolymer molding with a high fluorine content of not less than 72 wt. % can be easily formed into a laminate with other substrates.

摘要翻译： 一种含氟聚合物模制品，其包含能够进行低温熔融模塑并且具有不超过10J / g的晶体熔化的热值和MFR（230℃）为0.1至100g / min的全氟聚合物。 具有被修饰成具有氮原子键的表面的成型体，其中通过在氨气气氛中的放电处理进行对具有氮原子键的键的表面的改性。 由此获得的氟含量高于72重量％的全氟聚合物成型体 ％可以容易地形成为具有其它基底的层压体。

公开(公告)号：US5994487A

公开(公告)日：1999-11-30

申请号：US733243

申请日：1996-10-02

申请人： Takashi Enokida ,  Shinichi Sonobe ,  Haruyoshi Tatsu

发明人： Takashi Enokida ,  Shinichi Sonobe ,  Haruyoshi Tatsu

IPC分类号： C08K5/107 ,  C08F14/22 ,  C08F214/22 ,  C08K5/04 ,  C08K5/13 ,  C08L27/12 ,  C08F16/24

CPC分类号： C08F214/222 ,  C08K5/13

摘要： A fluoroelastomer comprising 74 to 80% by mole of vinylidene fluoride, 4 to 12% by mole of tetrafluoroethylene, 14 to 18% by mole of hexafluoropropene and 0.3 to 1.3% by mole of perfluoro(alkyl vinyl ether), the sum total being 100% by mole, gives vulcanization products having well balanced high levels of low-temperature characteristics and methanol resistance, and suppressed change in the hardness with time after the secondary vulcanization.

摘要翻译： 含有74〜80摩尔％的偏二氟乙烯，4〜12摩尔％的四氟乙烯，14〜18摩尔％的六氟丙烯和0.3〜1.3摩尔％的全氟（烷基乙烯基醚）的含氟弹性体，总和为100 以摩尔比计，得到具有良好平衡的高温低温特性和耐甲醇性的硫化产品，并且在二次硫化后抑制硬度随时间的变化。