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1.发明授权Silver halide photographic material capable of being handled in a bright room during steps of photomechanical process 失效卤化银照相材料能够在光机械过程的步骤中在明亮的房间中处理
公开(公告)号：US4847180A
公开(公告)日：1989-07-11
申请号：US44856
申请日：1987-05-01
CPC分类号： G03C1/061 , Y10S430/15
摘要： A silver halide photographic material which may be handled in a bright room, which comprises a support having provided thereon at least one silver halide emulsion layer containing silver chlorobromide grains (bromide content: not more than 20 mol %) or silver chloride grains, said emulsion layer containing 1.times.10.sup.-7 mol to 5.times.10.sup.-4 mol of a rhodium salt per mol of silver, and said emulsion layer or at least one other hydrophilic colloid layer containing at least one hydrazine derivative represented by the following general formula (I): ##STR1## wherein R represents an organic group having 1 to 30 carbon atoms; A represents a substituted or unsubstituted phenylene group or a substituted or unsubstituted naphthylene group; X represents --NH--or --O--; L.sub.1 represents a straight, branched or cyclic alkylene group having 1 to 20 carbon atoms, an aralkylene group having 7 to 20 carbon atoms, a phenylene group, or a divalent group having 1 to 20 carbon atoms, wherein these groups are linked to each other through --O--, --S--, --CO--, --CONH--or --COO--; L.sub.2 represents --CONH--, --SO.sub.2 NH--, --O--or --S--; i and j each independently represents 0 or 1; and B represents a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted phenyl group having 6 to 20 carbon atoms, a substituted or unsubstituted aralkyl group having a total of 7 to 20 carbon atoms and 1 to 3 carbon atoms in the alkyl moiety thereof, a substituted or unsubstituted alkoxy group haivng 1 to 20 carbon atoms, or a substituted or unsubstituted phenoxy group having 6 to 20 carbon atoms.
摘要翻译： 一种卤化银照相材料，其可以在明亮的房间中处理，其包括其上提供有至少一个含有氯化银溴化银颗粒（溴含量：不大于20mol％）的卤化银乳剂层或氯化银颗粒的载体，所述乳液 含有每摩尔银1×10-7摩尔至5×10-4摩尔铑盐的层，所述乳剂层或至少一种含有至少一种由以下通式（I）表示的肼衍生物的其它亲水胶体层：
（I）其中R表示碳原子数1〜30的有机基团。 A表示取代或未取代的亚苯基或取代或未取代的亚萘基; X表示-NH-或-O-; L1表示碳原子数1〜20的直链，支链或环状亚烷基，碳原子数7〜20的亚芳基，亚苯基或碳原子数1〜20的二价基，其中，这些基彼此相连 -O - ， - S - ， - CO - ， - CONH-或-COO-; L 2表示-CONH-，-SO 2 NH-， - O-或-S-; i和j各自独立地表示0或1; B表示氢原子，取代或未取代的碳原子数1〜20的烷基，取代或未取代的碳原子数6〜20的苯基，取代或未取代的碳原子数为7〜20的芳烷基和1 至少3个碳原子，取代或未取代的碳原子数1〜20的烷氧基，或取代或未取代的碳原子数6〜20的苯氧基。 -
2.发明授权
公开(公告)号：US4740453A
公开(公告)日：1988-04-26
申请号：US813308
申请日：1985-12-24
申请人： Koki Nakamura , Shigeo Hirano , Tadashi Ikeda , Keiji Mihayashi , Mitsunori Ono , Toshiro Takahashi , Ken-ichi Kuwabara , Morio Yagihara , Isamu Itoh
发明人： Koki Nakamura , Shigeo Hirano , Tadashi Ikeda , Keiji Mihayashi , Mitsunori Ono , Toshiro Takahashi , Ken-ichi Kuwabara , Morio Yagihara , Isamu Itoh
CPC分类号： G03C1/43 , G03C7/305 , G03C2005/168 , Y10S430/156 , Y10S430/158 , Y10S430/16
摘要： A silver halide photosensitive material is described, comprising a support and at least one silver halide emulsion layer, wherein said emulsion layer or another layer contains a compound represented by formula (I) ##STR1## wherein X represents an atomic group forming a redox center of benzene type having substituents by linking with C.sub.A and C.sub.B, and which does not enable Time-PUG to be released until the redox center is oxidized during development processing; EWG represents an electron withdrawing group having a Hammet's .sigma. para value exceeding 0.3; C.sub.A and C.sub.B each represents a carbon atom; R.sub.1 and R.sub.2 each represents a hydrogen atom or a suitable substituent; Time represents a timing group connecting to C.sub.B through a sulfur, nitrogen, or selenium atom thereof, t is an integer of 0 or 1, and when t=0, Time is a chemical bond; PUG represents a photographically useful group and connects to C.sub.B through a sulfur, nitrogen, or selenium atom thereof when t=0; and n is an integer of 0 or 1.
摘要翻译： 描述了卤化银感光材料，其包括载体和至少一种卤化银乳剂层，其中所述乳剂层或另一层含有由式（I）表示的化合物（I），其中X表示形成 通过与CA和CB连接而具有取代基的苯类氧化还原中心，并且不能使Time-PUG释放直到氧化还原中心在显影处理期间被氧化; EWG代表Hammet sigma值超过0.3的吸电子基团; CA和CB各自表示碳原子; R1和R2各自表示氢原子或适当的取代基; 时间表示通过其硫，氮或硒原子与CB连接的定时基团，t为0或1的整数，当t = 0时，为化学键; PUG表示当t = 0时，通过其硫，氮或硒原子连接CB; n为0或1的整数。
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公开(公告)号：US5085970A
公开(公告)日：1992-02-04
申请号：US581435
申请日：1990-09-13
申请人： Kimitaka Kameoka , Ken-ichi Kuwabara , Toshiro Takahashi , Shigenori Moriuchi , Morio Yagihara , Yoshio Inagaki , Keiichi Adachi
发明人： Kimitaka Kameoka , Ken-ichi Kuwabara , Toshiro Takahashi , Shigenori Moriuchi , Morio Yagihara , Yoshio Inagaki , Keiichi Adachi
摘要： A method for forming an image is disclosed which comprises providing a photosensitive material comprising at least one light-sensitive layer and having a gamma value of not less than 10 and a capability of being handled under bright light, subjecting said light-sensitive layer image-wise exposure to light having substantially exclusive of wavelengths of 370 nm or shorter through originals, for example, a line original and a halftone original arranged in a superposed condition, followed by contrast development processing, whereby excellent quality of images, for example, letter images, can be obtained.
摘要翻译： 公开了一种用于形成图像的方法，其包括提供包含至少一个感光层并且具有不小于10的伽马值和在亮光下处理的能力的感光材料，对所述感光层图像进行处理， 通过原稿实质上不具有370nm或更短波长的光，例如以叠加状态布置的原稿和半色调原稿，然后进行对比度显影处理，由此优异的图像质量，例如字母图像 ， 可以获得。
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4.发明授权Silver halide photographic materials for photochemical process which can be used in a bright room 失效用于光化学过程的卤化银照相材料，可用于明亮的房间
公开(公告)号：US4818659A
公开(公告)日：1989-04-04
申请号：US35549
申请日：1987-04-07
CPC分类号： G03C1/46 , G03C1/061 , Y10S430/15
摘要： A silver halide photographic material for use in a bright room is disclosed comprising a support having thereon at least two silver halide emulsion layers, each of the emulsion layers having a different sensitivity and comprising silver chloride grains or silver chlorobromide grains having at least about 80 mol % silver chloride, each of the silver halide emulsions layers containing from about 1.times.10.sup.-7 mol to about 1.times.10.sup.-4 mol of a rhodium salt per mol of silver, wherein the sensitivity of the lower emulsion layer (the emulsion layer coated nearer to the support) is higher than the sensitivity of the upper emulsion layer (the emulsion layer coated farther from the support) and at least one of the silver halide emulsion layers or different hydrophilic colloid layers contains a hydrazine derivative and at least one of the silver halide emulsion layers of different hydrophilic colloid layers contains a dry compound having a .sup..lambda. max of from about 400 nm to about 550 nm.
摘要翻译： 公开了一种用于明亮室中的卤化银照相材料，其包括其上具有至少两个卤化银乳剂层的载体，每个乳液层具有不同的灵敏度，并且包含氯化银颗粒或具有至少约80mol 每个银的卤化银乳剂层中含有约1×10-7mol至约1×10-4mol的铑盐，其中下乳剂层（涂层更接近载体的乳剂层）的灵敏度 ）高于上层乳剂层（涂布在离支撑体上的乳剂层）的敏感性，并且卤化银乳剂层或不同亲水胶体层中的至少一种含有肼衍生物和至少一种卤化银乳剂层 的不同亲水胶体层含有λmax为约400nm至约550nm的干燥化合物。
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公开(公告)号：US4803149A
公开(公告)日：1989-02-07
申请号：US915593
申请日：1986-10-06
CPC分类号： G03C1/815 , G03C1/825 , Y10S430/15
摘要： A silver halide photographic material for a bright room and a process for producing the photographic material are disclosed, wherein the silver halide photographic material for a bright room comprises a support having thereon at least one silver halide emulsion layer containing silver chloride grains or silver chlorobromide grains containing at least 80 mol % silver chloride, at least one of said silver halide emulsion layer or another hydrophilic colloid layer(s) present containing a yellow dye making the silver halide photographic material substantially insensitive to visible light of 420 n.m. or more and an ultraviolet absorbent in an amount sufficient to reduce the specific sensitivity of the silver halide emulsion at 360 n.m. to 1/2 or lower than 1/2 thereof in the absence of the ultraviolet absorbent, and the .gamma. value of the silver halide photographic material being at least 10.
摘要翻译： 公开了一种用于明亮室的卤化银照相材料和用于生产照相材料的方法，其中用于光亮室的卤化银照相材料包括其上具有至少一个含有氯化银颗粒或氯溴化银颗粒的卤化银乳剂层的载体 含有至少80mol％氯化银，至少一种所述卤化银乳剂层或存在的另一亲水胶体层，其含有黄色染料，使得卤化银照相材料基本上对420nm的可见光不敏感 以上的紫外线吸收剂，其量足以降低卤化银乳剂在360纳米的特异性。 在不存在紫外线吸收剂的情况下为1/2或低于1/2，并且卤化银照相材料的γ值为至少10。
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公开(公告)号：US4762769A
公开(公告)日：1988-08-09
申请号：US909670
申请日：1986-09-22
CPC分类号： G03C1/061 , Y10S430/15
摘要： A silver halide photographic material which has at least one silver halide emulsion layer comprising silver chloride or silver chlorobromide grains which has a bromide content of 5 mol % or less, and containing a rhodium salt in an amount of from 1.times.10.sup.-6 to 5.times.10.sup.-4 mole per mole of silver in said layer, and contains both a hydrazine derivative and a dye having an absorption peak in the wavelength region of from 400 nm to 550 nm in at least one of said emulsion layer another hydrophilic colloid layer, to thereby control the ratio of sensitivity at 360 nm to sensitivity at 400 nm (S.sub.360 /S.sub.400 ratio) to not less than 30, thereby achieving ultra-high contrast, high sensitivity, and a satisfactory aptitude for safelight.
摘要翻译： 一种卤化银照相材料，其具有至少一种卤化银乳剂层，其包含溴化物含量为5mol％或更少的氯化银或氯溴化银颗粒，并且含有1x10 -6至5×10 -4 并且在至少一个所述乳剂层的另一个亲水胶体层中含有肼衍生物和在波长范围为400nm至550nm具有吸收峰的染料，从而控制 360nm处的灵敏度与400nm处的灵敏度比（S360 / S400比）不小于30，从而实现超高对比度，高灵敏度和令人满意的安全性。
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7.发明授权
公开(公告)号：US4786587A
公开(公告)日：1988-11-22
申请号：US115645
申请日：1987-10-26
申请人： Ken-ichi Kuwabara
发明人： Ken-ichi Kuwabara
CPC分类号： G03C1/061 , G03C1/015 , G03C2001/03564 , G03C2001/0357 , G03C2200/06 , Y10S430/149
摘要： A silver halide photographic material comprising at least one negative type silver halide emulsion layer coated on a support, said emulsion comprising two kinds of monodisperse emulsions each having a means grain sizes of not more than 0.5 micron and, differing in mean grain size from each other at least by 0.1 micron, and said photographic material further comprising a hydrazine derivative in at least one photographic layer, whereby negative images of high density and very high contrast can be obtained with a high photographic speed and without black spots.
摘要翻译： 一种卤化银照相材料，其包含涂覆在载体上的至少一种负型卤化银乳剂层，所述乳液包含两种单分散乳液，每种均分乳剂均具有不大于0.5微米的平均粒度，并且平均粒径彼此不同 至少0.1微米，并且所述照相材料在至少一个照相层中进一步包含肼衍生物，由此可以以高摄影速度和无黑点获得高密度和非常高对比度的负像。
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8.发明授权公开(公告)号：US06458522B1
公开(公告)日：2002-10-01
申请号：US09663944
申请日：2000-09-18
IPC分类号： G03C106
摘要： A silver halide photographic light-sensitive material includes a compound selected from: (1) a quaternary nitrogen or phosphorus salt compound, having 20 or more of total recurring units consisting of an ethyleneoxy group and/or a propyleneoxy group; (2) a quaternary salt compound represented by formula (A): wherein Q represents nitrogen or phosphorus, R1, R2 and R3 represent an alkyl, aryl, alkenyl, alkynyl, or heterocyclic group, L1 represents an alkylene group, Y represents —C(═O) or —SO2—, L2 represents a divalent connecting group having at least one hydrophilic group, Xn− represents an n-valent counter anion, n being an integer of 1 to 3; and (3) a quaternary salt compound represented by formula (B): wherein A represents an organic moiety necessary to complete a nitrogen-containing aromatic heterocyclic ring. L2 represents a divalent connecting group having at least one hydrophilic group that divides L2. L1, Y and Xn− have the same meanings as above.
摘要翻译： 卤化银摄影感光材料包括选自以下的化合物：（1）具有20个或更多个由乙烯氧基和/或丙烯氧基组成的总重复单元的季氮或磷盐化合物;（2）四 由式（A）表示的盐化合物：其中Q表示氮或磷，R 1，R 2和R 3表示烷基，芳基，烯基，炔基或杂环基，L 1表示亚烷基，Y表示-C（= O）或 -SO 2 - ，L 2表示具有至少一个亲水基团的二价连接基团，Xn-表示n价抗衡阴离子，n为1〜3的整数， 和（3）由式（B）表示的季盐化合物：其中A表示完成含氮芳族杂环所必需的有机部分。 L2表示具有至少一个分隔L2的亲水基团的二价连接基团。 L1，Y和Xn-具有与上述相同的含义。
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公开(公告)号：US4999276A
公开(公告)日：1991-03-12
申请号：US372750
申请日：1989-06-28
摘要： A silver halide photographic material which comprises a support having thereon at least one of silver halide emulsion layer and other hydrophilic colloid layer where at least one of said silver halide emulsion layer and other hydrophilic colloid layer contains a hydrazine derivative represented by formula (I), and also having thereon, as a constitutional layer, at least one electroconductive layer having a surface resistivity of 1.times.10.sup.12 .OMEGA. or less in an atmosphere of 25.degree. C. and 25% RH; ##STR1## wherein R.sub.1 represents an aliphatic group or an aromatic group; R.sub.2 represents a hydrogen atom, an alkyl group, an aryl group, an alkoxy group, an aryloxy group, an amino group, a carbamoyl group or an oxycarbonyl group; G.sub.1 represents a carbonyl group, a sulfonyl group, a sulfoxy group, ##STR2## or an iminomethylene group; A.sub.1 and A.sub.2 are both hydrogen atoms, or one of them represents a hydrogen atom and the other represents a substituted or unsubstituted alkylsulfonyl group, a substituted or unsubstituted arylsulfonyl group, or a substituted or unsubstituted acyl group. The material can be processed with a stable developer under a bright room condition to give a high contrast image. The material processed has negligible pinholes.
摘要翻译： 一种卤化银照相材料，其包含其上具有卤化银乳剂层和其它亲水胶体层中的至少一种的载体，其中所述卤化银乳剂层和其它亲水胶体层中的至少一种含有式（I）表示的肼衍生物， 并且在25℃和25％RH的气氛中还具有作为结构层的表面电阻率为1×10 12欧米埃或更低的至少一种导电层; （I）其中R1表示脂族基团或芳族基团; R2表示氢原子，烷基，芳基，烷氧基，芳氧基，氨基，氨基甲酰基或氧羰基; G1表示羰基，磺酰基，亚砜氧基，亚氨基亚甲基， A1和A2都是氢原子，或者它们中的一个表示氢原子，另一个表示取代或未取代的烷基磺酰基，取代或未取代的芳基磺酰基或取代或未取代的酰基。 该材料可以在明亮的房间条件下用稳定的显影剂处理，以产生高对比度图像。 处理的材料具有可忽略的针孔。
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10.发明授权High-contrast silver halide photographic material and method for forming an image with the same 失效高对比度卤化银照相材料及其形成图像的方法
公开(公告)号：US5288590A
公开(公告)日：1994-02-22
申请号：US934232
申请日：1992-08-25
CPC分类号： G03C1/061 , G03C2001/03517 , G03C2001/03558 , G03C2001/091 , G03C2001/093 , G03C2001/094 , G03C2001/095
摘要： A high contrast photographic image is formed by development of a photographic material with an amine-free developer having a low pH value. The photographic material has at least one silver halide emulsion on a support. The silver halide emulsion in the emulsion layer contains an iridium salt and/or a rhodium salt and comprises a gold-sensitized and sulfur-sensitized silver chlorobromide emulsion or silver chloroiodobromide emulsion having a silver chloride content of 50 mol% or more and a silver iodide content of 5 mol% or less. The emulsion layer contains a hydrazine compound represented by formula (I): ##STR1## wherein R.sub.1 represents an aliphatic group or an aromatic group, which contains a partial structure, --O(--CH.sub.2 CH.sub.2 O).sub.n --, --O(--CH.sub.2 CH(CH.sub.3)O).sub.n -- or --O(--CH.sub.2 CH(OH)CH.sub.2 O).sub.n --, wherein n is an integer of 3 or more, as a part of the R.sub.1 substituent, or contains a quaternary ammonium cation as a part of the R.sub.1 substituent; G.sub.1 represents --CO--, --COCO--, --CS--, --C(=NG.sub.2 R.sub.2)--, --SO--, --SO.sub.2 -- or --P(O)(G.sub.2 R.sub.2)--, wherein G.sub.2 represents at least one chemical bond selected from the group consisting of --O--, --S-- or --N(R.sub.2)--, and R.sub.2 represents an aliphatic group, an aromatic group or a hydrogen atom. When the molecule has a plurality of R.sub.2 groups, they may be same as or different from each other. One of A.sub.1 and A.sub.2 is a hydrogen atom, and the other is a hydrogen atom, an acyl group, an alkylsulfonyl group or an arylsulfonyl group.
摘要翻译： 通过用具有低pH值的无胺显影剂显影照相材料来形成高对比度摄影图像。 照相材料在载体上具有至少一种卤化银乳剂。 乳剂层中的卤化银乳剂含有铱盐和/或铑盐，并且包括氯化银含量为50摩尔％以上的金增感和硫敏感氯化银氯化银乳剂或氯碘溴化银乳剂，以及碘化银 含量为5摩尔％以下。 乳液层含有由式（I）表示的肼化合物：（*化学结构*）（I）其中R 1表示脂族基或芳基，其含有部分结构，-O（-CH 2 CH 2 O）n - O（-CH 2 CH（CH 3）O）n - 或-O（-CH 2 CH（OH）CH 2 O）n - ，其中n为3以上的整数，作为R 1取代基的一部分，或含有季铵阳离子 部分R1取代基; G1表示-CO-，-COCO - ， - CS-，-C（= NG2R2） - ， - SO - ， - SO2-或-P（O）（G2R2） - ，其中G2表示至少一种选自 由-O - ， - S-或-N（R 2） - 组成的基团，R 2表示脂族基团，芳族基团或氢原子。 当分子具有多个R 2基团时，它们可以彼此相同或不同。 A1和A2之一是氢原子，另一个是氢原子，酰基，烷基磺酰基或芳基磺酰基。
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