Polymerization using mixed aluminum compounds
    1.
    发明授权
    Polymerization using mixed aluminum compounds 失效
    使用混合铝化合物进行聚合

    公开(公告)号:US4387202A

    公开(公告)日:1983-06-07

    申请号:US331099

    申请日:1981-12-15

    CPC分类号: C08F10/02 C08F210/16

    摘要: A process is described for the polymerization of ethylene or copolymerization of ethylene with a C.sub.3 to C.sub.15 alpha olefin in solution, suspension or in the gas phase at 20.degree. to 250.degree. C. and 1 to 100 bars in the presence of a mixed catalyst comprising a separately produced halogen-containing titanium(III) compound and an organoaluminum compound while controlling the molecular weight with oxygen, wherein a mixture of organoaluminum compounds is employed comprising a halogen-containing aluminum alkyl and a trialkyl aluminum compound in a molar ratio of 1:0.05 to 1:20, the combined amount of organoaluminum compounds being present in an amount of 0.01 to 20 moles per one mole of halogen-containing Ti(III) compound.

    摘要翻译: 描述了一种用于乙烯聚合或乙烯与C 3 -C 15α-烯烃在溶液,悬浮液或气相中在20-250℃和1至100巴下在含有混合催化剂存在下共聚的方法,该混合催化剂包含 单独制备的含卤素的钛(III)化合物和有机铝化合物,同时用氧控制分子量,其中使用有机铝化合物的混合物,其包含含卤素的烷基铝和三烷基铝化合物,其摩尔比为1: 0.05至1:20,相对于每摩尔含卤素的Ti(III)化合物,有机铝化合物的合用量为0.01至20摩尔。

    Process for the manufacture of polyolefins
    2.
    发明授权
    Process for the manufacture of polyolefins 失效
    制造聚烯烃的方法

    公开(公告)号:US4370458A

    公开(公告)日:1983-01-25

    申请号:US954021

    申请日:1978-10-23

    CPC分类号: C08F10/02 Y10S526/905

    摘要: An improvement in a process for the preparation of an ethylene homopolymer or a copolymer of ethylene with an .alpha.-olefin containing 3 to 15 carbon atoms by contacting the monomer or mixture of monomers in solution, suspension or in gas phase at 20.degree. to 250.degree. C. at a pressure of 1 to 50 bar with a mixed catalyst comprising a chlorine containing titanium (III) compound and an organoaluminum compound in the presence of hydrogen, the improvement residing in employing as the organoaluminum compound a trialkylaluminum compound in an amount of 0.1 to 20 mol per mol titanium (III) compound and including in the polymerization mixture oxygen at a concentration of 0.001 to 0.1 volume percent based upon the amount of ethylene. By carrying out the polymerization by including oxygen in the polymerization reaction mixture and employing trialkylaluminum compound as the organoaluminum compound the mean molecular weight of the polymer can be regulated while obtaining a desired molecular weight distribution.

    摘要翻译: 乙烯均聚物或乙烯与含有3至15个碳原子的α-烯烃的共聚物的制备方法的改进通过在20℃至250℃的溶液,悬浮液或气相中使单体或单体混合物接触。 在含氢的钛(III)化合物和有机铝化合物的混合催化剂的氢气存在下,在1至50巴的压力下,该改进剂用于作为有机铝化合物的三烷基铝化合物的用量为0.1 至20mol / mol钛(III)化合物,并且在聚合混合物中包含基于乙烯量的0.001至0.1体积%浓度的氧气。 通过在聚合反应混合物中包含氧并使用三烷基铝化合物作为有机铝化合物进行聚合,可以调节聚合物的平均分子量,同时获得所需的分子量分布。

    Process for the continuous manufacture of .alpha.-cyano-ethylated
aliphatic aldehydes
    4.
    发明授权
    Process for the continuous manufacture of .alpha.-cyano-ethylated aliphatic aldehydes 失效
    连续制造{60-氰基乙基化脂族醛的方法

    公开(公告)号:US4102913A

    公开(公告)日:1978-07-25

    申请号:US790202

    申请日:1977-04-25

    CPC分类号: C07C255/00

    摘要: A continuous process for the manufacture of .alpha.-cyano-ethylated aliphatic aldehydes by continuously passing acrylonitrile and aldehyde through a tubular reaction zone and therein contacting the same with an alkali hydroxide at a temperature between 20.degree. and 120.degree. C, the contact of the acrylonitrile and aldehyde with the alkali hydroxide being for a brief period of time and thereafter immediately separating the reaction product from the alkali hydroxide. Unreacted acrylonitrile and aldehyde can be recycled to the tubular reactor and additional alkali hydroxide can be added to make up for any losses.

    摘要翻译: 通过连续使丙烯腈和醛通过管状反应区并在其中将其与碱金属氢氧化物在20-120℃的温度下接触来制备α-氰基乙基化的脂族醛的连续方法,丙烯腈与丙烯腈的接触 和醛与碱金属氢氧化物短暂的时间,然后立即从碱性氢氧化物中分离反应产物。 未反应的丙烯腈和醛可以再循环到管状反应器中,并且可以加入另外的碱金属氢氧化物以弥补任何损失。

    Transmission Mode Selection Based on Radio Link Quality and Radio Load on the Air Interface
    9.
    发明申请
    Transmission Mode Selection Based on Radio Link Quality and Radio Load on the Air Interface 有权
    基于无线链路质量和空中接口无线电负载的传输模式选择

    公开(公告)号:US20110243100A1

    公开(公告)日:2011-10-06

    申请号:US13131056

    申请日:2008-11-26

    IPC分类号: H04B7/216

    摘要: It is described a method for selecting a transmission mode for a radio data transfer between a user equipment and a base station of a telecommunication network. The method includes (a) determining the quality of a radio link, which extends between the user equipment and the base station, (b) determining the radio load within the telecommunication network, and (c) selecting a transmission mode based on the quality of the radio link and on the radio load. It is further described a control device for selecting a transmission mode for a radio data transfer between a user equipment and a base station and a computer program for controlling the described transmission mode selection method.

    摘要翻译: 描述了一种用于选择电信网络的用户设备和基站之间的无线电数据传输的传输模式的方法。 该方法包括:(a)确定在用户设备和基站之间延伸的无线电链路的质量,(b)确定电信网络内的无线电负载,以及(c)基于所述电信网络的质量来选择传输模式 无线电链路和无线电负载。 进一步描述了用于选择用户设备和基站之间的无线电数据传输的传输模式的控制设备和用于控制所述传输模式选择方法的计算机程序。

    Process for the homo- and copolymerization of ethylene
    10.
    发明授权
    Process for the homo- and copolymerization of ethylene 失效
    乙烯均聚和共聚方法

    公开(公告)号:US4663301A

    公开(公告)日:1987-05-05

    申请号:US797230

    申请日:1985-11-12

    CPC分类号: C08F10/00 Y10S526/904

    摘要: The homo- or copolymerization of ethylene at temperatures of 150.degree. C. to 350.degree. C. and pressures of 300 to 3500 bar is carried out in the presence of catalysts having an organometallic compound of a metal of Group III of the Periodic Table of the Elements and a titanium compound. The titanium compound is the reaction product of (a) a titanic acid ester and (b) the product of the reaction of a magnesium alcoholate and a halogen-containing aluminum alkyl compound.

    摘要翻译: 在150℃至350℃的温度和300至3500巴的压力下乙烯的均聚或共聚在具有元素周期表第III族金属的有机金属化合物的催化剂的存在下进行 元素和钛化合物。 钛化合物是(a)钛酸酯和(b)镁醇盐和含卤素的烷基铝化合物的反应产物的反应产物。