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    Compound having silsesquioxane skeleton and its polymer
    1.
    发明授权
    Compound having silsesquioxane skeleton and its polymer 有权
    具有倍半硅氧烷骨架的化合物及其聚合物

    公开(公告)号：US08420764B2

    公开(公告)日：2013-04-16

    申请号：US13423548

    申请日：2012-03-19

    申请人： Jyun-ichi Inagaki ,  Yasuyuki Sasada ,  Takashi Kato

    发明人： Jyun-ichi Inagaki ,  Yasuyuki Sasada ,  Takashi Kato

    IPC分类号： C08G77/00

    CPC分类号： C09D183/14 ,  C07F7/21 ,  C08G59/306 ,  C08G63/695 ,  C08G69/42 ,  C08G77/045 ,  C08G77/42 ,  C08G77/455 ,  Y10T428/31663

    摘要： A polymer having a structural unit represented by Formula (3): wherein R1 is phenyl in which any hydrogen may be replaced by halogen or alkyl having 1 to 5 carbon atoms; in the alkyl having 1 to 5 carbon atoms, any —CH2—, which is not adjacent to each other, may be replaced by —O—, and any hydrogen may be replaced by halogen; Q1 is hydrogen, halogen, alkyl having 1 to 10 carbon atoms, cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cyclohexenyl, or phenyl in which any hydrogen may be replaced by halogen or alkyl having 1 to 5 carbon atoms; in the alkyl having 1 to 10 carbon atoms and alkyl having 1 to 5 carbon atoms which is a substituent of phenyl, any —CH2—, which is not adjacent to each other, may be replaced by —O—, —CH═CH— or —C≡C—, and any hydrogen may be replaced by halogen; and Q3 is a group represented by Formula (4):

    摘要翻译： 具有由式（3）表示的结构单元的聚合物：其中R 1是其中任何氢可以被卤素或具有1至5个碳原子的烷基取代的苯基; 在具有1至5个碳原子的烷基中，不相邻的任何-CH 2 - 可以被-O-代替，并且任何氢可以被卤素取代; Q1是氢，卤素，具有1-10个碳原子的烷基，环丙基，环丁基，环戊基，环己基，环己烯基或苯基，其中任何氢可以被卤素或具有1-5个碳原子的烷基取代; 在具有1至10个碳原子的烷基和具有1至5个碳原子的烷基作为苯基的取代基时，任何不相邻的-CH 2 - 可以被-O - ， - CH = CH- 或-C≡C-，并且任何氢可以被卤素取代; Q3为由式（4）表示的基团：<-Z0A1-Z1lA2-Z2mA3-Z3nA4p-Z5-（4）其中代码<表示与硅的键合点; l，m，n和p独立地为0,1,2或3; A1，A2，A3，A4，Z0，Z1，Z2，Z3和Z5如权利要求1中所定义。

    Compound having silsesquioxane skeleton and its polymer
    2.
    发明授权
    Compound having silsesquioxane skeleton and its polymer 有权
    具有倍半硅氧烷骨架的化合物及其聚合物

    公开(公告)号：US08236917B2

    公开(公告)日：2012-08-07

    申请号：US12659478

    申请日：2010-03-10

    申请人： Jyun-ichi Inagaki ,  Yasuyuki Sasada ,  Takashi Kato

    发明人： Jyun-ichi Inagaki ,  Yasuyuki Sasada ,  Takashi Kato

    IPC分类号： C08G77/00

    CPC分类号： C09D183/14 ,  C07F7/21 ,  C08G59/306 ,  C08G63/695 ,  C08G69/42 ,  C08G77/045 ,  C08G77/42 ,  C08G77/455 ,  Y10T428/31663

    摘要： A compound represented by Formula (1) and a polymer obtained using the compound: wherein R1 is phenyl which may have substituents, Q1 is hydrogen, halogen, alkyl having 1 to 10 carbon atoms, cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cyclohexenyl or phenyl in which optional hydrogen may be replaced by halogen or alkyl having 1 to 5 carbon atoms, Q2 is a group represented by Formula (2):

    摘要翻译： 由式（1）表示的化合物和使用该化合物获得的聚合物：其中R1是可具有取代基的苯基，Q1是氢，卤素，具有1-10个碳原子的烷基，环丙基，环丁基，环戊基，环己基，环己烯基或苯基 其中任选的氢可以被卤素或具有1至5个碳原子的烷基取代，Q2是由式（2）表示的基团：<-Z0A1-Z1lA2-Z2mA3-Z3nA4p-Z4-（2）其中代码<表示 与硅，l，m，n和p的键合点分别独立为0,1,2或3，A1至A4，Z0至Z4和Y1在本说明书中定义。

    Compound having silsesquioxane skeleton and its polymer
    3.
    发明申请
    Compound having silsesquioxane skeleton and its polymer 有权
    具有倍半硅氧烷骨架的化合物及其聚合物

    公开(公告)号：US20100240855A1

    公开(公告)日：2010-09-23

    申请号：US12659478

    申请日：2010-03-10

    申请人： Jyun-ichi Inagaki ,  Yasuyuki Sasada ,  Takashi Kato

    发明人： Jyun-ichi Inagaki ,  Yasuyuki Sasada ,  Takashi Kato

    IPC分类号： C08G77/04

    CPC分类号： C09D183/14 ,  C07F7/21 ,  C08G59/306 ,  C08G63/695 ,  C08G69/42 ,  C08G77/045 ,  C08G77/42 ,  C08G77/455 ,  Y10T428/31663

    摘要： A compound represented by Formula (1) and a polymer obtained using the compound: wherein R1 is phenyl which may have substituents, Q1 is hydrogen, halogen, alkyl having 1 to 10 carbon atoms, cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cyclohexenyl or phenyl in which optional hydrogen may be replaced by halogen or alkyl having 1 to 5 carbon atoms, Q2 is a group represented by Formula (2):

    摘要翻译： 由式（1）表示的化合物和使用该化合物获得的聚合物：其中R1是可具有取代基的苯基，Q1是氢，卤素，具有1-10个碳原子的烷基，环丙基，环丁基，环戊基，环己基，环己烯基或苯基 其中任选的氢可以被卤素或具有1至5个碳原子的烷基取代，Q2是由式（2）表示的基团：其中A为-Z 0，A 1 -Z 1，A 2 -Z 2， （2）其中代码<表示具有硅的键合点，1，m，n和p独立地为0,1,2或3，并且A1至A4，Z0至Z4和Y1定义 在规范中。

    Compound having silsequioxane skeleton and its polymer
    4.
    发明授权
    Compound having silsequioxane skeleton and its polymer 有权
    具有硅氧烷骨架的化合物及其聚合物

    公开(公告)号：US07705105B2

    公开(公告)日：2010-04-27

    申请号：US11704253

    申请日：2007-02-09

    申请人： Jyun-ichi Inagaki ,  Yasuyuki Sasada ,  Takashi Kato

    发明人： Jyun-ichi Inagaki ,  Yasuyuki Sasada ,  Takashi Kato

    IPC分类号： C08G77/00

    CPC分类号： C09D183/14 ,  C07F7/21 ,  C08G59/306 ,  C08G63/695 ,  C08G69/42 ,  C08G77/045 ,  C08G77/42 ,  C08G77/455 ,  Y10T428/31663

    摘要： A compound represented by Formula (1) and a polymer obtained using the compound: wherein R1 is phenyl which may have substituents, Q1 is hydrogen, halogen, alkyl having 1 to 10 carbon atoms, cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cyclohexenyl or phenyl in which optional hydrogen may be replaced by halogen or alkyl having 1 to 5 carbon atoms, Q2 is a group represented by Formula (2): wherein the code

    摘要翻译： 由式（1）表示的化合物和使用该化合物获得的聚合物：其中R1是可具有取代基的苯基，Q1是氢，卤素，具有1-10个碳原子的烷基，环丙基，环丁基，环戊基，环己基，环己烯基或苯基 其中任选的氢可以被卤素或具有1至5个碳原子的烷基取代，Q2是由式（2）表示的基团：其中代码<表示与硅的键合点，l，m，n和p独立地为0 ，1,2或3，A1至A4，Z0至Z4和Y1在本说明书中定义。

    Verification of translation
    5.
    发明申请
    Verification of translation 有权
    验证翻译

    公开(公告)号：US20070190344A1

    公开(公告)日：2007-08-16

    申请号：US11704253

    申请日：2007-02-09

    申请人： Jyun-ichi Inagaki ,  Yasuyuki Sasada ,  Takashi Kato

    发明人： Jyun-ichi Inagaki ,  Yasuyuki Sasada ,  Takashi Kato

    IPC分类号： B32B27/00 ,  C08G77/04 ,  C08L83/04

    CPC分类号： C09D183/14 ,  C07F7/21 ,  C08G59/306 ,  C08G63/695 ,  C08G69/42 ,  C08G77/045 ,  C08G77/42 ,  C08G77/455 ,  Y10T428/31663

    摘要： A compound represented by Formula (1) and a polymer obtained using the compound: wherein R1 is phenyl which may have substituents, Q1 is hydrogen, halogen, alkyl having 1 to 10 carbon atoms, cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cyclohexenyl or phenyl in which optional hydrogen may be replaced by halogen or alkyl having 1 to 5 carbon atoms, Q2 is a group represented by Formula (2): wherein the code

    摘要翻译： 由式（1）表示的化合物和使用以下化合物获得的聚合物：其中R 1是具有取代基的苯基，Q 1是氢，卤素，具有1个 至10个碳原子，环丙基，环丁基，环戊基，环己基，环己烯基或苯基，其中任选的氢可以被卤素或具有1至5个碳原子的烷基取代，Q 2是由式 2）：其中代码<表示具有硅的键合点，l，m，n和p独立地为0,1,2或3，并且A 1至A 4 >，Z 0> 0 Z 4和Y 1在本说明书中定义。

    Silsesquioxane derivative and production process for the same
    7.
    发明授权
    Silsesquioxane derivative and production process for the same 有权
    倍半硅氧烷衍生物和生产工艺相同

    公开(公告)号：US07449539B2

    公开(公告)日：2008-11-11

    申请号：US11545594

    申请日：2006-10-11

    申请人： Yoshitaka Morimoto ,  Kenichi Watanabe ,  Nobumasa Ootake ,  Jyun-ichi Inagaki ,  Kazuhiro Yoshida ,  Koji Ohguma

    发明人： Yoshitaka Morimoto ,  Kenichi Watanabe ,  Nobumasa Ootake ,  Jyun-ichi Inagaki ,  Kazuhiro Yoshida ,  Koji Ohguma

    IPC分类号： C07F7/21

    CPC分类号： C08G77/20 ,  C07F7/21 ,  C08G77/04 ,  C08G77/045 ,  C08G77/14

    摘要： The present inventors have obtained a PSQ derivative of a completely condensed type into which a functional group is readily introduced by using a novel PSQ derivative of an incompletely condensed type in which four alkaline metal atoms are bonded to silsesquioxane of a cage type having eight Si's. The above silsesquioxane derivative is represented by Formula (1). A silsesquioxane derivative to which alkaline metal atoms are bonded is represented by Formula (2). In Formula (1) and Formula (2), R is a group selected from alkyl, aryl and arylalkyl; Y is a group represented by Formula (a) or Formula (b); and M is a monovalent alkaline metal atom. X in Formula (a) and Formula (b) is hydrogen, halogen, a hydroxyl group or a monovalent organic group, and Z is —O—, —CH2— or a single bond. The preferred organic group is a functional group or a group having a functional group.

    摘要翻译： 本发明人已经获得了一种完全冷凝型的PSQ衍生物，其中通过使用四种碱金属原子与具有八个Si的笼型的倍半硅氧烷结合的不完全冷凝型的新型PSQ衍生物容易地引入官能团。 上述倍半硅氧烷衍生物由式（1）表示。 碱金属原子键合的倍半硅氧烷衍生物由式（2）表示。 在式（1）和式（2）中，R是选自烷基，芳基和芳烷基的基团; Y为式（a）或式（b）所示的基团。 M为单价碱金属原子。 式（a）和式（b）中的X为氢，卤素，羟基或一价有机基团，Z为-O-，-CH 2 - 或单键。 优选的有机基团是官能团或具有官能团的基团。

    Silsesquioxane derivatives and process for production thereof
    8.
    发明授权
    Silsesquioxane derivatives and process for production thereof 有权
    倍半硅氧烷衍生物及其制备方法

    公开(公告)号：US07169873B2

    公开(公告)日：2007-01-30

    申请号：US10490163

    申请日：2002-09-17

    申请人： Yoshitaka Morimoto ,  Kenichi Watanabe ,  Nobumasa Ootake ,  Jyun-ichi Inagaki ,  Kazuhiro Yoshida ,  Koji Ohguma

    发明人： Yoshitaka Morimoto ,  Kenichi Watanabe ,  Nobumasa Ootake ,  Jyun-ichi Inagaki ,  Kazuhiro Yoshida ,  Koji Ohguma

    IPC分类号： C07F7/21

    CPC分类号： C08G77/20 ,  C07F7/21 ,  C08G77/04 ,  C08G77/045 ,  C08G77/14

    摘要： The present inventors have obtained a PSQ derivative of a completely condensed type into which a functional group is readily introduced by using a novel PSQ derivative of an incompletely condensed type in which four alkaline metal atoms are bonded to silsesquioxane of a cage type having eight Si's. The above silsesquioxane derivative is represented by Formula (1). A silsesquioxane derivative to which alkaline metal atoms are bonded is represented by Formula (2). In Formula (1) and Formula (2), R is a group selected from alkyl, aryl and arylalkyl; Y is a group represented by Formula (a) or Formula (b); and M is a monovalent alkaline metal atom. X in Formula (a) and Formula (b) is hydrogen, halogen, a hydroxyl group or a monovalent organic group, and Z is —O—, —CH2— or a single bond. The preferred organic group is a functional group or a group having a functional group.

    摘要翻译： 本发明人已经获得了一种完全冷凝型的PSQ衍生物，其中通过使用四种碱金属原子与具有八个Si的笼型的倍半硅氧烷结合的不完全冷凝型的新型PSQ衍生物容易地引入官能团。 上述倍半硅氧烷衍生物由式（1）表示。 碱金属原子键合的倍半硅氧烷衍生物由式（2）表示。 在式（1）和式（2）中，R是选自烷基，芳基和芳烷基的基团; Y为式（a）或式（b）所示的基团。 M为单价碱金属原子。 式（a）和式（b）中的X为氢，卤素，羟基或一价有机基团，Z为-O-，-CH 2 - 或单键。 优选的有机基团是官能团或具有官能团的基团。

    Silsesquioxane derivative and production process for the same
    9.
    发明申请
    Silsesquioxane derivative and production process for the same 有权
    倍半硅氧烷衍生物和生产工艺相同

    公开(公告)号：US20070032454A1

    公开(公告)日：2007-02-08

    申请号：US11545594

    申请日：2006-10-11

    申请人： Yoshitaka Morimoto ,  Kenichi Watanabe ,  Nobumasa Ootake ,  Jyun-ichi Inagaki ,  Kazuhiro Yoshida ,  Koji Ohguma

    发明人： Yoshitaka Morimoto ,  Kenichi Watanabe ,  Nobumasa Ootake ,  Jyun-ichi Inagaki ,  Kazuhiro Yoshida ,  Koji Ohguma

    IPC分类号： A61K31/695 ,  C07F7/00

    CPC分类号： C08G77/20 ,  C07F7/21 ,  C08G77/04 ,  C08G77/045 ,  C08G77/14

    摘要： The present inventors have obtained a PSQ derivative of a completely condensed type into which a functional group is readily introduced by using a novel PSQ derivative of an incompletely condensed type in which four alkaline metal atoms are bonded to silsesquioxane of a cage type having eight Si's. The above silsesquioxane derivative is represented by Formula (1). A silsesquioxane derivative to which alkaline metal atoms are bonded is represented by Formula (2). In Formula (1) and Formula (2), R is a group selected from alkyl, aryl and arylalkyl; Y is a group represented by Formula (a) or Formula (b); and M is a monovalent alkaline metal atom. X in Formula (a) and Formula (b) is hydrogen, halogen, a hydroxyl group or a monovalent organic group, and Z is —O—, —CH2— or a single bond. The preferred organic group is a functional group or a group having a functional group.

    摘要翻译： 本发明人已经获得了一种完全冷凝型的PSQ衍生物，其中通过使用四种碱金属原子与具有八个Si的笼型的倍半硅氧烷结合的不完全冷凝型的新型PSQ衍生物容易地引入官能团。 上述倍半硅氧烷衍生物由式（1）表示。 碱金属原子键合的倍半硅氧烷衍生物由式（2）表示。 在式（1）和式（2）中，R是选自烷基，芳基和芳烷基的基团; Y为式（a）或式（b）所示的基团。 M为单价碱金属原子。 式（a）和式（b）中的X为氢，卤素，羟基或一价有机基团，Z为-O-，-CH 2 - 或单键。 优选的有机基团是官能团或具有官能团的基团。