(METH)ACRYLIC ESTER COPOLYMER AND CURABLE COMPOSITION CONTAINING THE SAME

    公开(公告)号:US20230144994A1

    公开(公告)日:2023-05-11

    申请号:US18149299

    申请日:2023-01-03

    Inventor: Kiyoshi Miyafuji

    CPC classification number: C08F290/04 C08L71/02

    Abstract: Provided is a (meth)acrylic ester copolymer (B) having a reactive silicon group represented by the following formula (1): —SiR5cX3-c (1). R5 is a substituted or unsubstituted hydrocarbon group having 1 to 20 carbon atoms, X is a hydroxy group or a hydrolyzable group, and c is 0 or 1. A monomer component of the copolymer includes a (meth)acrylic ester (b1), a (meth)acrylic ester polymer (b2) having more than one (meth)acryloyl groups per molecule, and a chain transfer agent (b3) having a mercapto group. The monomer component further includes a monomer (b4) having a reactive silicon group and a polymerizable unsaturated group, and/or the chain transfer agent (b3) having a mercapto group further has a reactive silicon group.

    CURABLE COMPOSITION
    2.
    发明申请
    CURABLE COMPOSITION 审中-公开
    可固化组合物

    公开(公告)号:US20160137872A1

    公开(公告)日:2016-05-19

    申请号:US14894977

    申请日:2014-05-29

    Abstract: Provided is a curable composition having low viscosity and good workability before curing, and affording a cured product having high strength. The above-mentioned problem can be solved by using a curable composition containing organic polymer (A) having a reactive silicon group and (meth)acrylate-based polymer (B) having a trifunctional reactive silicon group, and having a reactive silicon group equivalent of not less than 0.30 mmol/g, wherein monomer (b1) having a glass transition temperature of a homopolymer of not more than 80° C. is contained as a monomer constituting polymer (B) in a proportion of not less than 40 wt % per 100 wt % of the total monomer unit.

    Abstract translation: 本发明提供固化前粘度低,加工性好的固化性组合物,提供强度高的固化物。 上述问题可以通过使用含有具有反应性硅基团的有机聚合物(A)和具有三官能反应性硅基的(甲基)丙烯酸酯类聚合物(B),并且具有反应性硅基当量的可固化组合物 不低于0.30mmol / g,其中包含均聚物不超过80℃的玻璃化转变温度的单体(b1)作为构成聚合物(B)的单体,其比例不小于40重量% 100重量%的总单体单元。

    CURABLE COMPOSITION, AND CURED PRODUCT THEREOF
    3.
    发明申请
    CURABLE COMPOSITION, AND CURED PRODUCT THEREOF 审中-公开
    可固化组合物及其固化产品

    公开(公告)号:US20160108235A1

    公开(公告)日:2016-04-21

    申请号:US14894976

    申请日:2014-05-30

    Inventor: Kiyoshi Miyafuji

    Abstract: The present invention provides a curable composition containing oxyalkylene-based polymer (A) having more than one reactive silicon group represented by the formula (1): —SiR1aX3-a on average in one molecule, (meth)acrylate-based polymer (B) having a reactive silicon group represented by the formula (2): —SiX3 and a reactive silicon group equivalent of not less than 0.30 mmol/g, and high-molecular weight plasticizer (C) having 0-1 reactive silicon group on average in one molecule (the groups in the formulas (1) and (2) are as defined in the DESCRIPTION).

    Abstract translation: 本发明提供一种含有氧化烯系聚合物(A)的固化性组合物,其具有一个以上式(1)表示的反应性硅基团:一分子中的-SiR1aX3-a,(甲基)丙烯酸酯系聚合物(B) 具有由式(2)表示的反应性硅基团:-SiX 3和不小于0.30mmol / g的反应性硅基团当量,以及平均具有0-1个反应性硅基团的高分子量增塑剂(C) 分子(式(1)和(2)中的基团如说明书中所定义)。

    POLYMER BLEND, COMPOSITION, SEALANT, AND SEALANT FOR TIRE

    公开(公告)号:US20210388204A1

    公开(公告)日:2021-12-16

    申请号:US17461197

    申请日:2021-08-30

    Abstract: A polymer blend including an organic polymer with a reactive silicon-containing group which gives cured objects excellent elongation property and stress relaxation, a composition including the polymer blend, a specific filler, and a curing catalyst, a sealant including the composition; and a sealant for tires, are provided. A polymer blend including an organic polymer with a bifunctional reactive silicon-containing group of a specific structure is mixed with polyoxyalkylene (A). Polyoxyalkylene (A) has an average molecular weight of 13,000 or higher and 100,000 or lower, a reactive-silicon-containing-group equivalent Eqa of 0.010 mmol/g or more and 0.29 mmol/g or less, and contains more than one silicon-containing group per molecule and polyoxyalkylene (B). Polyoxyalkylene (B) has an average molecular weight of 3,000 or higher and 25,000 or lower, a reactive-silicon-containing group only at one end, and a reactive-silicon-containing-group equivalent Eqb of 0.03 mmol/g or more and 0.58 mmol/g or less.

    CURABLE COMPOSITION AND CURED OBJECT OBTAINED THEREFROM

    公开(公告)号:US20170107374A1

    公开(公告)日:2017-04-20

    申请号:US15395382

    申请日:2016-12-30

    Abstract: A curable composition iaciudes a polyoxyalkylene-based polymer (A); and a (meth)acrylate-based polymer (B), wherein the polyoxyalkylene-based polyer (A) has more than 1.0 reactive silicon group on average per one terminal portion, and the (meth)acrylate-based polymer (B) has more than or equal to 1.0 reactive silicon group on average per one molecule, wherein the (meth)acrylate-based polymer (B) is represented by the formula (1): —SiRX2 (1) wherein R is a hydrocarbon group having 1-20 carbon atoms or a hydrocarbon group having 1-20 carbon atoms substituted with a hetero atom-containing group or a halogen atom, and X is a hydroxyl group or a hydrolyzable group.

    Curable composition
    6.
    发明授权
    Curable composition 有权
    可固化组合物

    公开(公告)号:US09328272B2

    公开(公告)日:2016-05-03

    申请号:US14426836

    申请日:2013-09-06

    Inventor: Kiyoshi Miyafuji

    Abstract: The present invention aims to provide a curable composition that is usable in fast curing adhesives and the like and has excellent curability and excellent initial adhesion. The aim is accomplished by use of a curable composition that contains a polyoxyalkylene polymer (a1) having a reactive silyl group (e.g., trimethoxysilyl group) equivalent of 0.15 mmol/g to 1.5 mmol/g and a polyoxyalkylene polymer (a2) having a reactive silyl group equivalent of 0.010 to 0.14 mmol/g. Preferably, the polymers (a1) and (a2) both have a backbone with at least one branch.

    Abstract translation: 本发明旨在提供可用于快速固化粘合剂等的可固化组合物,并且具有优异的固化性和优异的初始粘合性。 目的是通过使用含有当量为0.15mmol / g〜1.5mmol / g的反应性甲硅烷基(例如三甲氧基甲硅烷基)的聚氧化烯聚合物(a1)和具有反应性的聚氧化烯聚合物(a2)的固化性组合物 甲硅烷基当量为0.010至0.14mmol / g。 优选地,聚合物(a1)和(a2)都具有至少一个分支的主链。

    CURABLE COMPOSITION
    7.
    发明申请

    公开(公告)号:US20210363347A1

    公开(公告)日:2021-11-25

    申请号:US17398331

    申请日:2021-08-10

    Inventor: Kiyoshi Miyafuji

    Abstract: A multi-part curable composition includes: an A part including a polyoxyalkylene polymer (A) having a reactive silicon group, a (meth)acrylic ester polymer (B) having a reactive silicon group, and an epoxy resin curing agent (D); and a B part including an epoxy resin (C) and a silanol condensation catalyst (E). The (meth)acrylic ester polymer (B) is a polymer containing constituent monomers including 40 to 70% by weight of an alkyl (meth)acrylate (b1) having an alkyl having 1 to 3 carbon atoms, a monomer (b2) having a reactive silicon group and a polymerizable unsaturated group, and a macromonomer (b3) that is a (meth)acrylic ester polymer having a polymerizable unsaturated group.

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