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公开(公告)号:US11676770B2
公开(公告)日:2023-06-13
申请号:US17357441
申请日:2021-06-24
Applicant: KEMET Electronics Corporation
Inventor: Yaru Shi , Antony P. Chacko , Ajaykumar Bunha , Qingping Chen , Elisabeth Crittendon Key
CPC classification number: H01G9/15 , H01G9/0036 , H01G9/028 , H01G9/0425 , H01G9/0525 , H01G9/08 , H01G11/48 , H01G9/012
Abstract: Provided is an improved capacitor formed by a process comprising: providing an anode comprising a dielectric thereon wherein the anode comprises a sintered powder wherein the powder has a powder charge of at least 45,000 μFV/g; and forming a first conductive polymer layer encasing at least a portion of the dielectric by applying a first slurry wherein the first slurry comprises a polyanion and a conductive polymer and wherein the polyanion and conductive polymer are in a weight ratio of greater than 3 wherein the conductive polymer and polyanion forms conductive particles with an average particle size of no more than 20 nm.
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公开(公告)号:US20220262569A1
公开(公告)日:2022-08-18
申请号:US17178631
申请日:2021-02-18
Applicant: KEMET Electronics Corporation
Inventor: Antony P. Chacko , John Joseph Ols , Ajaykumar Bunha , Yaru Shi
Abstract: An improved electrolytic capacitor, and method of making the electrolytic capacitor, is provided. The electrolytic capacitor comprises an anode comprising a dielectric layer on the anode. A primary conductive polymer layer is on dielectric and a mordant layer on the primary conductive layer wherein the mordant layer comprises a mordant compound of Formula A; wherein:
each of R1-R6 is independently selected from H and —PO(OR7)2 wherein each R7 is independently selected from H, substituted or unsubstituted alkyl of 1-20 carbons, substituted or unsubstituted aryl of 6-20 carbons or an alkylaryl of 7-21 carbons; with the proviso that at least one of R1-R6 is —PO(OH)2. A secondary conductive polymer layer is on the mordant layer.-
公开(公告)号:US20190115159A1
公开(公告)日:2019-04-18
申请号:US16165649
申请日:2018-10-19
Applicant: KEMET Electronics Corporation
Inventor: Ajaykumar Bunha , Antony P. Chacko , Qingping Chen , Yaru Shi , Philip M. Lessner
IPC: H01G9/042 , C09D125/18 , C09D4/06 , C09D7/65 , C09D5/24 , C09D165/00
Abstract: An improved capacitor is provided wherein the capacitor comprises a conductive polymer layer. The conductive polymer comprises first particles comprising conductive polymer and polyanion and second particles comprising the conductive polymer and said polyanion wherein the first particles have an average particle diameter of at least 1 micron to no more than 10 microns and the second particles have an average particle diameter of at least 1 nm to no more than 600 nm.
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公开(公告)号:US11935708B2
公开(公告)日:2024-03-19
申请号:US17831138
申请日:2022-06-02
Applicant: KEMET Electronics Corporation
Inventor: Ajaykumar Bunha , Antony P. Chacko
Abstract: The present invention if related to an improved electrolytic capacitor and a method of making the improved electrolytic capacitor. The electrolytic capacitor comprises an anode comprising a dielectric layer on the anode. A first mordant layer is on the dielectric wherein the first mordant layer comprises a mordant compound of Formula A:
wherein:
R1 and R2 is independently selected from H; cation, linear alkyl, cyclic alkyl or substituted alkyl of 1 to 10 carbons;
R3 is selected from —CR4R5R6 wherein R4 represents a hydrogen, an alkyl of 1-20 carbons or an aryl of 6-20 carbons; R4 and R5 can be taken together to represent a cyclic alkyl or substituted cyclic alkyl or (—CR6OP(O)OR1OR2)n;
R5 represents an alkyl of 1-20 carbons or an aryl of 6-20 carbons; R4 and R5 can be taken together to represent a cyclic alkyl or substituted cyclic alkyl or (—CR6OP(O)OR1OR2)n;
R6 represents a hydrogen, an alkyl of 1-20 carbons or an aryl of 6-20 carbons; and
n is an integer from 1 to 20; and
a crosslinker. A primary conductive polymer layer is on the first mordant layer.-
公开(公告)号:US11694851B2
公开(公告)日:2023-07-04
申请号:US17178631
申请日:2021-02-18
Applicant: KEMET Electronics Corporation
Inventor: Antony P. Chacko , John Joseph Ols , Ajaykumar Bunha , Yaru Shi
Abstract: An improved electrolytic capacitor, and method of making the electrolytic capacitor, is provided. The electrolytic capacitor comprises an anode comprising a dielectric layer on the anode. A primary conductive polymer layer is on dielectric and a mordant layer on the primary conductive layer wherein the mordant layer comprises a mordant compound of Formula A;
wherein:
each of R1-R6 is independently selected from H and —PO(OR7)2 wherein each R7 is independently selected from H, substituted or unsubstituted alkyl of 1-20 carbons, substituted or unsubstituted aryl of 6-20 carbons or an alkylaryl of 7-21 carbons; with the proviso that at least one of R1-R6 is —PO(OH)2. A secondary conductive polymer layer is on the mordant layer.-
公开(公告)号:US11482382B2
公开(公告)日:2022-10-25
申请号:US16992714
申请日:2020-08-13
Applicant: KEMET Electronics Corporation
Inventor: Yaru Shi , Antony P. Chacko , Chenyi Gu , Ajaykumar Bunha , Qingping Chen
Abstract: The invention is related to an improved capacitor and an improved process for forming a capacitor. The process comprises forming an anode comprising a dielectric on the anode. A cathode layer is then formed on the dielectric wherein the cathode layer comprises a self-doped conductive polymer and a cross-linker wherein a weight ratio of crosslinker to self-doped conductive polymer is at least 0.01 to no more than 2.
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公开(公告)号:US11177076B2
公开(公告)日:2021-11-16
申请号:US17023870
申请日:2020-09-17
Applicant: KEMET Electronics Corporation
Inventor: Ajaykumar Bunha , Antony P. Chacko , Qingping Chen , Yaru Shi , Philip M. Lessner
IPC: H01G9/00 , C09D5/24 , C09D165/00 , C09D4/06 , C09D125/18 , C09D7/65 , H01G9/15 , H01G9/025 , C08F12/30 , H01B1/12 , C08F212/14 , C09D133/14 , H01G9/028 , H01G9/042
Abstract: A capacitor comprising an anode foil; and a conductive polymer layer on the anode foil. The conductive polymer layer comprises first particles comprising conductive polymer and polyanion and second particles comprising the conductive polymer and the polyanion wherein the first particles have an average particle diameter of at least 1 micron to no more than 10 microns. The second particles have an average particle diameter of at least 1 nm to no more than 600 nm.
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8.
公开(公告)号:US20180330888A1
公开(公告)日:2018-11-15
申请号:US16046154
申请日:2018-07-26
Applicant: KEMET Electronics Corporation
Inventor: Yaru Shi , Antony P. Chacko , Ajaykumar Bunha , Qingping Chen
CPC classification number: H01G9/15 , H01G9/0036 , H01G9/012 , H01G9/028 , H01G9/0425 , H01G9/08 , H01G11/48 , Y10T29/417
Abstract: Provided is an improved capacitor formed by a process comprising: providing an anode comprising a dielectric thereon wherein the anode comprises a sintered powder wherein the powder has a powder charge of at least 45,000 μFV/g; and forming a first conductive polymer layer encasing at least a portion of the dielectric by applying a first slurry wherein the first slurry comprises a polyanion and a conductive polymer and wherein the polyanion and conductive polymer are in a weight ratio of greater than 3 wherein the conductive polymer and polyanion forms conductive particles with an average particle size of no more than 20 nm.
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公开(公告)号:US20240331952A1
公开(公告)日:2024-10-03
申请号:US18126785
申请日:2023-03-27
Applicant: KEMET Electronics Corporation
Inventor: Subarna Banerjee , Ajaykumar Bunha , John T. Kinard , Antony P. Chacko
CPC classification number: H01G9/025 , C07F9/117 , H01G9/0032 , H01G9/042 , H01G9/052 , H01G9/15 , H01G2009/05 , H01G9/07
Abstract: An improved formation electrolyte suitable for formation of an oxide on a valve metal anode and an improved capacitor comprising an oxide formed in the formation electrolyte is provided. The formation electrolyte comprises a derivative of inositol is defined by Formula 1:
wherein:
each of R1-R6 is defined.-
公开(公告)号:US20210198469A1
公开(公告)日:2021-07-01
申请号:US17167176
申请日:2021-02-04
Applicant: KEMET Electronics Corporation
Inventor: Ajaykumar Bunha , Antony P. Chacko , Yaru Shi , Qingping Chen , Philip M. Lessner
IPC: C08L25/18 , H01G9/028 , H01G9/042 , C07C309/28 , C07C309/30 , H01G9/00 , H01G9/04 , H01G9/15 , H01M4/136 , H01M4/137
Abstract: An improved slurry of conductive polymer is provided. The slurry comprises a conductive polymer and a polyanion wherein the polyanion is a copolymer comprising groups A, B and C represented the ratio of Formula A: AxByCz Formula A wherein: A is polystyrenesulfonic acid or salt of polystyrenesulfonate; B and C separately represent polymerized units substituted by a group selected from: —C(O)OR6 wherein R6 is selected from the group consisting of: —(CHR17)b—R18. All other groups are defined. The conductive polymer has an average particle size of at least 1 nm to no more than 10 microns.
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