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公开(公告)号：US11565942B2
公开(公告)日：2023-01-31
申请号：US17230476
申请日：2021-04-14
发明人： Robert Peter Hodgkins , Omer Refa Koseoglu , Jean-Marie Maurice Basset , Kuo-Wei Huang , Anissa Bendjeriou Sedjerari , Manoj K. Gangwar , Sathiyamoorthy Murugesan
IPC分类号： C01B33/26 , C01B39/40 , B01J29/40 , B01J35/10 , B01J35/02 , B01J37/16 , B01J37/02 , C01B39/02
摘要： Disclosed herein are modified zeolites and methods for making modified zeolites. In one or more embodiments disclosed herein, a modified zeolite may include a microporous framework including a plurality of micropores having diameters of less than or equal to 2 nm. The microporous framework may include at least silicon atoms and oxygen atoms. The modified zeolite may further include organometallic moieties each bonded to bridging oxygen atoms. The organometallic moieties may include a platinum atom. The platinum atom may be bonded to a bridging oxygen atom, and the bridging oxygen atom may bridge the platinum atom of the organometallic moiety and a silicon atom of the microporous framework.
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公开(公告)号：US20220340432A1
公开(公告)日：2022-10-27
申请号：US17230476
申请日：2021-04-14
发明人： Robert Peter Hodgkins , Omer Refa Koseoglu , Jean-Marie Maurice Basset , Kuo-Wei Huang , Anissa Bendjeriou Sedjerari , Manoj K. Gangwar , Sathiyamoorthy Murugesan
摘要： Disclosed herein are modified zeolites and methods for making modified zeolites. In one or more embodiments disclosed herein, a modified zeolite may include a microporous framework including a plurality of micropores having diameters of less than or equal to 2 nm. The microporous framework may include at least silicon atoms and oxygen atoms. The modified zeolite may further include organometallic moieties each bonded to bridging oxygen atoms. The organometallic moieties may include a platinum atom. The platinum atom may be bonded to a bridging oxygen atom, and the bridging oxygen atom may bridge the platinum atom of the organometallic moiety and a silicon atom of the microporous framework.
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公开(公告)号：US20180337416A1
公开(公告)日：2018-11-22
申请号：US15776915
申请日：2016-12-14
发明人： Kuo-Wei Huang , Junrong Zheng
IPC分类号： H01M8/0612 , H01M16/00 , H01M8/04223 , H01M8/04302 , H01M8/04701 , H01M8/04007 , H02J7/00 , B01J6/00 , C01B3/22 , B60L11/18
CPC分类号： H01M16/003 , B01J19/00 , B60L11/1883 , B60L11/1887 , B60L11/1894 , C01B3/26 , H01M8/04067 , H01M8/04216 , H01M8/04268 , H01M8/04302 , H01M8/04738 , H01M8/0631 , H01M16/006 , H01M2250/20 , H01M2250/402 , Y02B90/12 , Y02T90/32 , Y02T90/34
摘要： The present disclosure relates generally to new forms of portable energy generation devices and methods. The devices are designed to covert formic acid into released hydrogen, alleviating the need for a hydrogen tank as a hydrogen source for fuel cell power.
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公开(公告)号：US20230085197A1
公开(公告)日：2023-03-16
申请号：US17412732
申请日：2021-08-26
发明人： Robert Peter Hodgkins , Omer Refa Koseoglu , Jean-Marie Maurice Basset , Kuo-Wei Huang , Anissa Bendjeriou Sedjerari , Sathiyamoorthy Murugesan , Manoj Kumar Gangwar
摘要： A functionalized fibrous hierarchical zeolite includes a framework comprising aluminum atoms, silicon atoms, and oxygen atoms, the framework further comprising a plurality of micropores and a plurality of mesopores. The functionalized fibrous hierarchical zeolite is functionalized with at least one terminal amine bonded to a silicon atom. Terminal organometallic functionalities are bonded to a nitrogen atom of the at least one terminal amine, the terminal organometallic functionalities comprising a platinum atom.
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公开(公告)号：US11591230B2
公开(公告)日：2023-02-28
申请号：US17231191
申请日：2021-04-15
发明人： Robert Peter Hodgkins , Omer Refa Koseoglu , Jean-Marie Maurice Basset , Kuo-Wei Huang , Anissa Bendjeriou Sedjerari , Manoj K. Gangwar , Sathiyamoorthy Murugesan
摘要： Disclosed herein are modified zeolites and methods for making modified zeolites. In one or more embodiments disclosed herein, a modified zeolite may include a microporous framework including a plurality of micropores having diameters of less than or equal to 2 nm. The microporous framework includes at least silicon atoms and oxygen atoms. The modified zeolite may further include organometallic moieties each bonded to bridging oxygen atoms. The organometallic moieties include a hafnium atom. The hafnium atom is bonded to a bridging oxygen atom, and bridging oxygen atom bridges the hafnium atom of the organometallic moiety and a silicon atom of the microporous framework.
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公开(公告)号：US20220340433A1
公开(公告)日：2022-10-27
申请号：US17230500
申请日：2021-04-14
发明人： Robert Peter Hodgkins , Omer Refa Koseoglu , Jean-Marie Maurice Basset , Kuo-Wei Huang , Anissa Bendjeriou Sedjerari , Manoj K. Gangwar , Sathiyamoorthy Murugesan
摘要： Disclosed herein are modified zeolites and methods for making modified zeolites. In one or more embodiments disclosed herein, a modified zeolite may include a microporous framework comprising a plurality of micropores having diameters of less than or equal to 2 nm. The microporous framework may include at least silicon atoms and oxygen atoms. The modified zeolite may further include organometallic moieties each bonded to bridging oxygen atoms. The organometallic moieties may include a titanium atom. The titanium atom may be bonded to a bridging oxygen atom, and the bridging oxygen atom may bridge the titanium atom of the organometallic moiety and a silicon atom of the microporous framework.
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公开(公告)号：US11097243B2
公开(公告)日：2021-08-24
申请号：US16670243
申请日：2019-10-31
发明人： Kuo-Wei Huang , Zhiping Lai
IPC分类号： B01J16/00 , B01J8/02 , B01J8/00 , B01J23/46 , C07C67/40 , B01J31/18 , C07C67/00 , B01J15/00 , B01J19/24
摘要： Embodiments include a system that may include a reactor including a reaction zone and a gas release zone separated by a selectively permeable membrane, wherein the selectively permeable membrane permits hydrogen to pass through the membrane and substantially blocks a substrate and its dehydrogenative coupling product from passing through the membrane. Embodiments further include a method of producing a dehydrogenative coupling product, wherein the method may include exposing a substrate to a catalyst in a reaction zone of a reactor; coupling the substrate to form the dehydrogenative coupling product and hydrogen; and separating the hydrogen from the dehydrogenative coupling product using a selectively permeable membrane and passing the hydrogen to a gas release zone of the reactor.
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公开(公告)号：US10399072B2
公开(公告)日：2019-09-03
申请号：US15510119
申请日：2015-09-09
发明人： Kuo-Wei Huang , Qianyi Zhao
IPC分类号： B01J31/18 , C07F9/58 , B01J31/12 , C07C29/14 , C07C29/15 , C07D317/36 , C07F15/04 , C07C231/10 , C07C29/09 , B01J31/02 , B01J37/04
摘要： The invention describes phospho-amino pincer-type ligands, metal complexes thereof, and catalytic methods comprising such metal complexes for conversion of carbon dioxide to methanol, conversion of aldehydes into alcohols, conversion of aldehydes in the presence of a trifluoromethylation agent into trifluorinated secondary alcohols, cycloaddition of carbon dioxide to an epoxide to provide cyclic carbonates or preparation of an amide from the combination of an alcohol and an amine.
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公开(公告)号：US11591229B2
公开(公告)日：2023-02-28
申请号：US17230500
申请日：2021-04-14
发明人： Robert Peter Hodgkins , Omer Refa Koseoglu , Jean-Marie Maurice Basset , Kuo-Wei Huang , Anissa Bendjeriou Sedjerari , Manoj K. Gangwar , Sathiyamoorthy Murugesan
摘要： Disclosed herein are modified zeolites and methods for making modified zeolites. In one or more embodiments disclosed herein, a modified zeolite may include a microporous framework comprising a plurality of micropores having diameters of less than or equal to 2 nm. The microporous framework may include at least silicon atoms and oxygen atoms. The modified zeolite may further include organometallic moieties each bonded to bridging oxygen atoms. The organometallic moieties may include a titanium atom. The titanium atom may be bonded to a bridging oxygen atom, and the bridging oxygen atom may bridge the titanium atom of the organometallic moiety and a silicon atom of the microporous framework.
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10.发明申请公开(公告)号：US20220348474A1
公开(公告)日：2022-11-03
申请号：US17230491
申请日：2021-04-14
发明人： Robert Peter Hodgkins , Omer Refa Koseoglu , Jean-Marie Maurice Basset , Kuo-Wei Huang , Anissa Bendjeriou Sedjerari , Sathiyamoorthy Murugesan , Manoj K. Gangwar
摘要： Disclosed herein are modified zeolites and methods for making modified zeolites. In one or more embodiments disclosed herein, a modified zeolite may include a microporous framework including a plurality of micropores having diameters of less than or equal to 2 nm. The microporous framework may include at least silicon atoms and oxygen atoms. The modified zeolite may further include organometallic moieties each bonded to a nitrogen atom of a secondary amine functional group including a nitrogen atom and a hydrogen atom. The organometallic moieties may include a zirconium atom that is bonded to the nitrogen atom of the secondary amine functional group. The nitrogen atom of the secondary amine function group may bridge the zirconium atom of the organometallic moiety and a silicon atom of the microporous framework.
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