Method for removing iron sulfide and calcium carbonate scale

    公开(公告)号:US11421143B2

    公开(公告)日:2022-08-23

    申请号:US16133153

    申请日:2018-09-17

    Abstract: A method of removing a heterogeneous scale from a surface in fluid communication with a wellbore and/or subterranean formation comprising contacting the scale with a composition comprising tetrakis(hydroxmethyl)phosphonium sulfate (THPS) and N-(2-hydroxyethyl)ethylenediaminetriacetic acid (THEDTA) to dissolve the scale having a pH in the range of about 6.0 to 8.0. The composition is suitable to remove iron sulfide and calcium carbonate scale in the absence of corrosion resistance at a temperature up to about 150° C. Also, the composition may be used remove scale from surface pipe line and other petroleum oil handling equipment.

    Method of removing calcium carbonate-containing oil-based filter cake using a biodegradable acid solution

    公开(公告)号:US11414589B2

    公开(公告)日:2022-08-16

    申请号:US16749418

    申请日:2020-01-22

    Abstract: A method of removing calcium carbonate-containing oil-based filter cake from a wellbore involving contacting the calcium carbonate-containing oil-based filter cake with a biodegradable acid solution of water, hydrochloric acid, formic acid, citric acid, a surfactant, and a glycol ether mutual solvent. The method is performed at a pressure of 200 to 400 psi and a temperature of 50 to 125° C. The method removes calcium carbonate-containing oil-based filter cake made of a water-in-oil emulsion, calcium carbonate, a primary emulsifier, a secondary emulsifier, a contamination treatment agent, a viscosity control agent, a filtration control agent. The method meets industry standard steel corrosion rates of less than 0.049 lb/ft2 per day. Also disclosed is a biodegradable acid solution of water, hydrochloric acid, formic acid, citric acid, a surfactant, and a glycol ether mutual solvent that meets OECD 301B thresholds for ready biodegradability.

    METHOD OF REMOVING CALCIUM CARBONATE-CONTAINING OIL-BASED FILTER CAKE USING A BIODEGRADABLE ACID SOLUTION

    公开(公告)号:US20210222050A1

    公开(公告)日:2021-07-22

    申请号:US16749418

    申请日:2020-01-22

    Abstract: A method of removing calcium carbonate-containing oil-based filter cake from a wellbore involving contacting the calcium carbonate-containing oil-based filter cake with a biodegradable acid solution of water, hydrochloric acid, formic acid, citric acid, a surfactant, and a glycol ether mutual solvent. The method is performed at a pressure of 200 to 400 psi and a temperature of 50 to 125° C. The method removes calcium carbonate-containing oil-based filter cake made of a water-in-oil emulsion, calcium carbonate, a primary emulsifier, a secondary emulsifier, a contamination treatment agent, a viscosity control agent, a filtration control agent. The method meets industry standard steel corrosion rates of less than 0.049 lb/ft2 per day. Also disclosed is a biodegradable acid solution of water, hydrochloric acid, formic acid, citric acid, a surfactant, and a glycol ether mutual solvent that meets OECD 301B thresholds for ready biodegradability.

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