公开(公告)号：US20040082803A1

公开(公告)日：2004-04-29

申请号：US10400875

申请日：2003-03-28

Applicant: KOREA INSTITUTE OF SCIENCE AND TECHNOLOGY

Inventor： Il Nam Jung ,  Bok Ryul Yoo ,  Joon Soo Han ,  Seung-Hyun Kang

IPC: C07F007/04

CPC classification number: C07F7/12 ,  C07F7/14

Abstract: The present invention provides organosilicon compounds containing two trichlorosilyl groups and their preparation methods. Organosilicon compounds of formula II are prepared by reacting linear chain or cyclic olefins of formula I with trichlorosilane in the presence of quaternary organophosphonium salt as a catalyst.R1nullHCnullCHnullR2nullnull(I) 1 In formulas I and II, R1 and R2 may be identical or different and represent a hydrogen atom, a linear or a cyclic C1-C8 alkyl, a linear or a cyclic C1-C8 alkenyl, benzyl, phenyl, a C1-C8 alkyl substituted phenyl group, two functional groups between R1 and R2 may be covalently bonded to form a C4-C8 ring with or without a carbon-carbon double bond.

Abstract translation: 本发明提供含有两个三氯甲硅烷基的有机硅化合物及其制备方法。 式Ⅱ的有机硅化合物是通过在季有机鏻盐作为催化剂的存在下使式I的直链或环烯烃与三氯硅烷反应来制备的。 R 1 -HC = CH-R 2（I）在式I和II中，R 1和R 2可以相同或不同，表示氢原子，直链或环状C 1 -C 8 烷基，直链或环状C 1 -C 8烯基，苄基，苯基，C 1 -C 8烷基取代的苯基，R 1和R 2之间的两个官能团可共价键合以形成具有 或没有碳 - 碳双键。

公开(公告)号：US20030166958A1

公开(公告)日：2003-09-04

申请号：US10335084

申请日：2002-12-31

Applicant: Korea Institute of Science and Technology

Inventor： Il Nam Jung ,  Bok Ryul Yoo ,  Joon Soo Han ,  Weon Cheol Lim ,  Mu Yeol Kim

IPC: C07F007/02

CPC classification number: C07F7/16 ,  C07F7/126

Abstract: A method for preparing alkyldichlorosilanes having a SinullH bond by directly reacting metallic silicon with a mixture of alkyl chloride and hydrogen chloride or alkyl chloride which generates hydrogen chloride at a reaction temperature in the presence of copper catalyst.

Abstract translation: 通过使金属硅与在氯化铜或氯化氢的混合物直接反应制备烷基二氯硅烷的方法，在铜催化剂存在下，在反应温度下产生氯化氢。