公开(公告)号：US20040260124A1

公开(公告)日：2004-12-23

申请号：US10761010

申请日：2004-01-20

发明人： Toshiaki Murai ,  Masahiro Murakami ,  Yuichiro Mutoh ,  Yukiyasu Ohta

IPC分类号： C07F007/04 ,  C07C239/08

CPC分类号： C07C211/28 ,  C07C211/27 ,  C07F7/081

摘要： The present invention relates to a method for easily producing a tertiary amine with high yield. A tertiary amine represented by general formula (1) is produced by adding a metal-containing reagent represented by general formula (6) into a reaction system consisting of thioamide represented by general formula (4), a methylating agent represented by general formula (5) and a solvent, and then adding thereto a Grignard reagent represented by general formula (7). 1 nullCH3nullXnullnull(5)R8-M1nullnull(6)R7-M2nullnull(7)

摘要翻译： 本发明涉及以高产率容易地制备叔胺的方法。 由通式（1）表示的叔胺通过将由通式（6）表示的含金属试剂加入到由通式（4）表示的硫代酰胺，由通式（5）表示的甲基化剂 ）和溶剂，然后加入通式（7）表示的格氏试剂。 CH 3 -X（5）R 8 -M 1（6）R 7 -M 2（7）

公开(公告)号：US20040176600A1

公开(公告)日：2004-09-09

申请号：US10477986

申请日：2003-11-12

发明人： Didier Juhue ,  Maria Jose Lina ,  Anne Claire Gayon ,  Jean-Marc Corpart

IPC分类号： C07F007/04

CPC分类号： C07F7/12 ,  C07F7/1804

摘要： The invention relates to a composition comprising a compound having formula (I): RfnullBnullRo-Z and a compound having formula (II) and/or the reaction product thereof. The invention is suitable for treating surfaces, in particular, transparent substrates. 1

摘要翻译： 本发明涉及包含式（I）化合物：Rf-B-Ro-Z和具有式（II）的化合物和/或其反应产物的组合物。 本发明适用于处理表面，特别是透明基材。

公开(公告)号：US20040082803A1

公开(公告)日：2004-04-29

申请号：US10400875

申请日：2003-03-28

申请人： KOREA INSTITUTE OF SCIENCE AND TECHNOLOGY

发明人： Il Nam Jung ,  Bok Ryul Yoo ,  Joon Soo Han ,  Seung-Hyun Kang

IPC分类号： C07F007/04

CPC分类号： C07F7/12 ,  C07F7/14

摘要： The present invention provides organosilicon compounds containing two trichlorosilyl groups and their preparation methods. Organosilicon compounds of formula II are prepared by reacting linear chain or cyclic olefins of formula I with trichlorosilane in the presence of quaternary organophosphonium salt as a catalyst.R1nullHCnullCHnullR2nullnull(I) 1 In formulas I and II, R1 and R2 may be identical or different and represent a hydrogen atom, a linear or a cyclic C1-C8 alkyl, a linear or a cyclic C1-C8 alkenyl, benzyl, phenyl, a C1-C8 alkyl substituted phenyl group, two functional groups between R1 and R2 may be covalently bonded to form a C4-C8 ring with or without a carbon-carbon double bond.

摘要翻译： 本发明提供含有两个三氯甲硅烷基的有机硅化合物及其制备方法。 式Ⅱ的有机硅化合物是通过在季有机鏻盐作为催化剂的存在下使式I的直链或环烯烃与三氯硅烷反应来制备的。 R 1 -HC = CH-R 2（I）在式I和II中，R 1和R 2可以相同或不同，表示氢原子，直链或环状C 1 -C 8 烷基，直链或环状C 1 -C 8烯基，苄基，苯基，C 1 -C 8烷基取代的苯基，R 1和R 2之间的两个官能团可共价键合以形成具有 或没有碳 - 碳双键。

公开(公告)号：US20040049064A1

公开(公告)日：2004-03-11

申请号：US10451499

申请日：2003-06-20

发明人： Thomas Kammel ,  Rainer Winkler ,  Bernd Pachaly

IPC分类号： C07F007/04

CPC分类号： C07F7/1892 ,  C07F7/1804

摘要： The invention relates to a method for producing isocyanato-organosilane of general formula (I) R2R3R4SinullR1nullNnullCnullO. According to said method, gaseous carbamato-organosilane of general formula (II) R2R3R4SinullR1nullNHnullCOnullOR (II), wherein R represents a monovatlent C1-C10 alkyl radical, R1 represents a bivalent C1-C6 hydrocarbon radical and R2, R3 and R4 respectively represent a methyl, ethyl, n-propyl, i-propyl, methoxy, ethoxy, n-propoxy or i-propoxy radical, is heated in the presence of a heterogeneous catalyst.

摘要翻译： 本发明涉及制备通式（I）R 2 R 3 Si-R 1 -N = C = O的异氰酸根合有机硅烷的方法。 根据所述方法，通式（II）的气态​​氨基甲酰甲烷 - 有机硅烷R 2 R 3 Si-R 1 -NH-CO-OR（II），其中R代表单价C1- C10烷基，R 1表示二价C 1 -C 6烃基，R 2，R 3和R 4分别表示甲基，乙基，正丙基，异丙基，甲氧基，乙氧基， 正丙氧基或异丙氧基在异相催化剂存在下加热。

公开(公告)号：US20030233005A1

公开(公告)日：2003-12-18

申请号：US10172443

申请日：2002-06-13

发明人： Binh T. Nguyen

IPC分类号： C07F007/04

CPC分类号： C07F7/122 ,  C07F7/0896

摘要： A one-step process for the preparation of organosilicon intermediates. The organosilicon intermediates comprise a group which includes such intermediates as 1,4-bis(dimethylsilyl)benzene, 1,4-bis(dimethylchlorosilyl)benzene, and their derivatives. The process comprises: combining a dihalobenzene with magnesium metal in a co-solvent mixture of an ether and an organic solvent and reacting them with an organosilicon compound of the general formula, R2bHcSiXd. The resulting mixture is allowed to react to completion. The resulting mixture is passed through a filtration device. The liquid, now free of solid magnesium halide, is subjected to a separation technique to recover the subject organosilicon intermediates and their derivatives.

摘要翻译： 制备有机硅中间体的一步法。 有机硅中间体包括包括1,4-双（二甲基甲硅烷基）苯，1,4-双（二甲基氯甲硅烷基）苯等中间体及其衍生物的基团。 该方法包括：将二卤代苯与镁金属在醚和有机溶剂的共溶剂混合物中混合并使其与通式为R 2 b HcSiXd的有机硅化合物反应。 使所得混合物反应完成。 将所得混合物通过过滤装置。 现在不含固体卤化镁的液体经受分离技术以回收目标有机硅中间体及其衍生物。

公开(公告)号：US20030229241A1

公开(公告)日：2003-12-11

申请号：US10328436

申请日：2002-12-23

发明人： Amos R. Anderson ,  Jeffrey G. Meyer

IPC分类号： C07F007/04 ,  C07F007/08 ,  C07F007/16

CPC分类号： C07F7/025 ,  C07F7/045

摘要： Process for the production of alkoxysilanes of the formula HSi(OR)3, where R is an alkyl group containing 1 to 6 carbon atoms, and/or alkyl orthosilicates of the formula Si(OR)4, where R is an alkyl group containing 1 to 6 carbon atoms. In a preferred embodiment, the process comprises reacting silicon metal with an alcohol in a suitable solvent in the presence of a cupric bis(diorganophosphate) catalyst. A polymeric form of ethyl orthosilicate, a by-product of the reaction, is the preferred solvent. The production of triethoxysilane and tetraethyl orthosilicate is preferred, with triethoxysilane being particularly preferred.

摘要翻译： 制备式HSi（OR）3的烷氧基硅烷的方法，其中R是含有1至6个碳原子的烷基，和/或式Si（OR）4的原硅酸烷基酯，其中R是含1个 至6个碳原子。 在优选的实施方案中，该方法包括在二（二有机磷酸盐）二氧化二铜催化剂存在下，使合适的溶剂中的硅金属与醇反应。 作为反应的副产物的原硅酸乙酯的聚合物形式是优选的溶剂。 优选三乙氧基硅烷和原硅酸四乙酯的生产，特别优选三乙氧基硅烷。

公开(公告)号：US20030229166A1

公开(公告)日：2003-12-11

申请号：US10443167

申请日：2003-05-22

发明人： Roland Krafczyk ,  Ulrich Deschler ,  Hans-Detlef Luginsland ,  Reimund Pieter ,  Andre Hasse ,  Melanie Mayer

IPC分类号： C08K005/24 ,  C07F007/04

CPC分类号： C08K5/548 ,  B60C1/0016 ,  C07F7/1804 ,  Y10S152/905 ,  C08L21/00

摘要： Abstract Organosilicon compounds having the formula I and/or II 1 wherein R1 is a mixture and the proportion of one component of the mixture is 10 to 50 mol %, are produced by reacting silanes having the formula III 2 with mixtures of alcohols having the general formula R1nullOH, with elimination of RnullOH, and RnullOH is continuously separated off from the reaction mixture by distillation. The organosilicon compounds can be used in rubber compounds.

摘要翻译： 摘要具有式I和/或II的有机硅化合物，其中R 1是混合物，混合物中一种组分的比例为10至50mol％，通过使具有式III的硅烷与具有式 通式R 1 -OH，并且通过蒸馏从反应混合物中连续分离R-OH。 有机硅化合物可用于橡胶化合物。

公开(公告)号：US20030172471A1

公开(公告)日：2003-09-18

申请号：US10276567

申请日：2002-11-14

发明人： Laurent Chassot ,  Hans-Juergen Braun

IPC分类号： A61K007/13 ,  C07D207/46 ,  C07D241/04 ,  C07D211/26 ,  C07F007/04

CPC分类号： C07D295/135 ,  C07C211/51 ,  C07C215/14 ,  C07C217/08 ,  C07C233/36 ,  C07D211/46

摘要： 1,3-Diamino-4-(aminomethyl)-benzene derivatives of the general Formula (I) or their physiologically tolerated, water-soluble salts, 1 as well as agents for the oxidative dyeing of fibers, containing these compounds.

摘要翻译： 通式（I）的1,3-二氨基-4-（氨基甲基） - 苯衍生物或其生理上耐受的水溶性盐，以及含有这些化合物的纤维的氧化染色剂。

公开(公告)号：US20030168783A1

公开(公告)日：2003-09-11

申请号：US10053001

申请日：2002-01-17

发明人： Rudolf J. Dams

IPC分类号： B05D003/10 ,  B05D003/04 ,  C07F007/04 ,  C07F007/12 ,  C04B033/34

CPC分类号： C04B41/4933 ,  B05D5/083 ,  C03C17/30 ,  C04B41/009 ,  C04B41/84 ,  C07F7/1804 ,  C04B41/502 ,  C04B33/00

摘要： A water soluble or water dispersible fluorochemical silane represented by the general formula: X-MfnMhmMar-Gnullnull(I) wherein X represents the residue of an initiator or hydrogen; Mf represents units derived from one or more fluorinated monomer; Mh represents units derived from one or more non-fluorinated monomer; Ma represents units having a silyl group represented by the formula: 1 wherein each of Y4, Y5 and Y6 independently represents an alkyl group, an aryl group or a hydrolyzable group; G is a monovalent organic group comprising the residue of a chain transfer agent; n represents a value of 1 to 100; m represents a value of 0 to 100; and r represents a value of 0 to 100; and nnullmnullr is at least 2; with the proviso that at least one of the following conditions is fulfilled: (a) G contains a silyl group of the formula: 2 wherein Y1, Y2 and Y3 each independently represents an alkyl group, an aryl group or a hydrolyzable group and at least one of Y1, Y2 and Y3 represents a hydrolyzable water solubilising group; or (b) r is at least 1 and at least one of Y4, Y5 and Y6 represents a hydrolyzable water solubilizing group.

摘要翻译： 由通式X-MfnMhmMar-G（I）表示的水溶性或水分散性含氟硅烷，其中X表示引发剂或氢的残基; Mf表示衍生自一种或多种氟化单体的单元; Mh表示衍生自一种或多种非氟化单体的单元; Ma表示具有由下式表示的甲硅烷基的单元：其中Y4，Y5和Y6各自独立地表示烷基，芳基或可水解基团; G是包含链转移剂残基的一价有机基团; n表示1〜100的数值。 m表示0〜100的值。 r表示0〜100的值。 n + m + r为2以上; 条件是满足以下条件中的至少一个：（a）G包含下式的甲硅烷基：其中Y 1，Y 2和Y 3各自独立地表示烷基，芳基或可水解基团，并且至少一个 Y1，Y2和Y3表示可水解水增溶基团; 或（b）r为至少1，Y4，Y5和Y6中的至少一个表示可水解的水增溶基团。

公开(公告)号：US20030135051A1

公开(公告)日：2003-07-17

申请号：US10278442

申请日：2002-10-22

发明人： Michael E. Deason ,  Kathleen R. Whitten

IPC分类号： C07F007/04 ,  C07D213/46

CPC分类号： C07D209/48 ,  C07C69/017 ,  C07D217/26 ,  C07D263/14 ,  C07D317/24 ,  C07D327/10 ,  C07D413/04 ,  C07D413/06

摘要： HIV protease inhibitors inhibit or block the biological activity of the HIV protease enzyme, causing the replication of the HIV virus to terminate. These compounds can be prepared by the novel methods of the present invention using the novel inventive compounds and intermediates.