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    Method of preparing halogenoalkyldialkyl chlorosilane
    4.
    发明申请
    Method of preparing halogenoalkyldialkyl chlorosilane 审中-公开
    卤代烷基二烷基氯硅烷的制备方法

    公开(公告)号：US20070185344A1

    公开(公告)日：2007-08-09

    申请号：US10561223

    申请日：2004-06-16

    申请人： Nathalie Guennouni ,  Jean-Christopher Galland

    发明人： Nathalie Guennouni ,  Jean-Christopher Galland

    IPC分类号： C07F7/14

    CPC分类号： C07F7/14

    摘要： 3-Chloropropyldimethylchlorosilane is prepared by hydrosilylation reaction in a reaction medium comprising dimethylhydrochlorosilane and allyl chloride, in the presence of a catalytically effective amount of di-p-chlorobis(η-1,5-cyclooctadiene)diiridium and wherein at least one auxiliary in the free or supported state selected from the group of compounds consisting of: (i) ketones, (ii) ethers, (iii) quinones, (iv) anhydrides, (v) unsaturated hydrocarbon compounds (UHC) whether aromatic and/or comprising at least one C═C double bond and/or at least one C≡C triple bond, it being possible for these unsaturated bonds to be conjugated or nonconjugated, the said UHCs being linear or cyclic (mono- or polycyclic), having from 4 to 30 carbon atoms, having from 1 to 8 ethylenic and/or acetylenic sites of unsaturation and optionally comprising one or more heteroatoms, and (vi) mixtures thereof, is added to the reaction medium, with the proviso that, when the auxiliary comprises one or more UHCs as defined above, then this (these) UHC(s) is (are) mixed with at least one other auxiliary other than a UHC.

    摘要翻译： 在催化有效量的二 - 对 - 氯双（η-1,5-环辛二烯）二铱的存在下，在包含二甲基氢氯硅烷和烯丙基氯的反应介质中通过氢化硅烷化反应制备3-氯丙基二甲基氯硅烷，其中至少一种在 （i）酮，（ii）醚，（iii）醌，（iv）酸酐，（v）不饱和烃化合物（UHC）和/或至少包含至少 一个CC双键和/或至少一个C≡C三键，这些不饱和键可能是共轭或非共轭的，所述UHC是具有4-30个碳原子的直链或环状（单环或多环） 具有1至8个不饱和键和/或炔属不饱和位点并且任选地包含一个或多个杂原子的化合物，和（vi）其混合物，加入到反应介质中，条件是当辅助剂包含一个或多个U 如上定义的HC，则（这些）UHC与至少一种除UHC之外的其它辅助剂混合。

    Method for preparing metallic carbene-based catalysts for hydrosilylation of unsaturated compounds and resulting catalysts
    5.
    发明授权
    Method for preparing metallic carbene-based catalysts for hydrosilylation of unsaturated compounds and resulting catalysts 有权
    制备用于不饱和化合物和所得催化剂的氢化硅烷化的金属卡宾催化剂的方法

    公开(公告)号：US07019145B2

    公开(公告)日：2006-03-28

    申请号：US10479808

    申请日：2002-06-04

    申请人： Olivier Buisine ,  Istvan Marko ,  Sebastien Sterin

    发明人： Olivier Buisine ,  Istvan Marko ,  Sebastien Sterin

    IPC分类号： C07F15/00 ,  C07F7/08 ,  B01J31/00

    CPC分类号： C07F7/1876 ,  C07F7/14 ,  C07F15/0086

    摘要： The invention concerns an improved method for preparing catalysts for hydrosilylation reactions of compounds with ethylene or acetylene unsaturation (for example olefins or acetylene derivatives), in particular but not exclusively those involving polyorganosiloxanes (POS) bearing Si—H units and POS bearing Si-(ethylene or acetylene unsaturation) units. Said preparation corresponds to the following synthesis (I), wherein: A=B=carbon: T1, T2=cyclohexyl, t-butyl or methyl; T3, T4=H; DVTMS=divinyltetramethylsiloxane; t-BuOK=potassium tert-butylate; T.A=room temperature. The invention is characterised in that it consists in carrying out said synthesis in a single step by bringing together salt (III) above, Karstedt (IV) in the presence of a solvent (V) (THF) and a base (VI) (t-BuOK) at room temperature.

    摘要翻译： 本发明涉及一种用于制备具有乙烯或乙炔不饱和键（例如烯烃或乙炔衍生物）的化合物的氢化硅烷化反应的催化剂的改进方法，特别但不仅限于涉及含有Si-H单元的聚有机硅氧烷（POS）和承载Si-（ 乙烯或乙炔不饱和度）单元。 所述制备对应于以下合成（I），其中：A = B =碳：T 1，T 2 =环己基，叔丁基或甲基; T 3，T 4 = H; DVTMS =二乙烯基四甲基硅氧烷; t-BuOK =叔丁醇钾; T.A =室温。 本发明的特征在于其包括在溶剂（V）（THF）和碱（VI）（t）存在下将上述盐（III），Karstedt（Ⅳ） -BuOK）在室温下。

    Preparation of organochlorosilanes by the silylation of conjugated dienes with trichlorosilane
    6.
    发明授权
    Preparation of organochlorosilanes by the silylation of conjugated dienes with trichlorosilane 失效
    通过用三氯硅烷甲硅烷基化共轭二烯制备有机氯硅烷

    公开(公告)号：US06740766B2

    公开(公告)日：2004-05-25

    申请号：US10385538

    申请日：2003-03-11

    申请人： Il Nam Jung ,  Bok Ryul Yoo ,  Joon Soo Han ,  Seung-Hyun Kang

    发明人： Il Nam Jung ,  Bok Ryul Yoo ,  Joon Soo Han ,  Seung-Hyun Kang

    IPC分类号： C07F708

    CPC分类号： C07F7/14 ,  Y02P20/584

    摘要： The present invention relates to a process for preparing organosilicon compounds by the silylation of conjugated dienes and more particularly, to the process for preparing organosilicon compounds expressed by the following Formulas 1a and 1b in high yield, comprising the steps of heating trichlorosilane in the presence of quaternary organophosphonium salt catalystto generate dichlorosilylene (:SiCl2); and silylating the result with linear or cyclic conjugated dienes, wherein R1, R2, R3, R4, R5 and R6 are independently a hydrogen atom, a C1-C6 alkyl, phenyl group, or two functional groups among R1, R2, R3, R4, R5 and R6 may be covalently bonded to each other to form a cyclic compound of C4-C8.

    摘要翻译： 本发明涉及通过共轭二烯的甲硅烷基化制备有机硅化合物的方法，更具体地说，涉及以高产率由下式1a和1b表示的制备有机硅化合物的方法，包括以下步骤：在存在下加热三氯硅烷 季铵有机鏻盐催化剂生成二氯二甲苯（（SiCl2））; 并用线性或环状共轭二烯甲硅烷基化，其中R 1，R 2，R 3，R 4，R 5和R 6独立地是氢原子， R 1，R 2，R 3，R 4，R 5和R 6中的C 6烷基，苯基或两个官能团可以彼此共价键合形成 C4-C8的环状化合物。

    Preparation of halopropyldimethylchlorosilanes
    7.
    发明申请
    Preparation of halopropyldimethylchlorosilanes 有权
    制备卤代丙基二甲基氯硅烷

    公开(公告)号：US20010053861A1

    公开(公告)日：2001-12-20

    申请号：US09852638

    申请日：2001-05-11

    发明人： Yoichi Tonomura ,  Tohru Kubota ,  Mikio Endo

    IPC分类号： C07F007/16

    CPC分类号： C07F7/14

    摘要： A halopropyldimethylchlorosilane is prepared by reacting dimethylchlorosilane with an allyl halide in the presence of an iridium catalyst. The reaction is effected in the presence of an internal olefin compound, typically 1,5-cyclooctadiene. The internal olefin compound suppresses deactivation of the iridium catalyst during reaction. Using a smaller amount of the iridium catalyst, the process produces the halopropyldimethylchlorosilane in high yields.

    摘要翻译： 卤代丙基二甲基氯硅烷通过使二氯甲硅烷与烯丙基卤化物在铱催化剂存在下反应来制备。 反应在内部烯烃化合物（通常为1,5-环辛二烯）的存在下进行。 内部烯烃化合物抑制反应期间铱催化剂的失活。 使用较少量的铱催化剂，该方法以高产率生产卤代丙基二甲基氯硅烷。

    Method of preparing an organosilicon compound
    8.
    发明授权
    Method of preparing an organosilicon compound 有权
    制备有机硅化合物的方法

    公开(公告)号：US06326506B1

    公开(公告)日：2001-12-04

    申请号：US09877742

    申请日：2001-06-11

    申请人： Mamoru Tachikawa ,  Kasumi Takei

    发明人： Mamoru Tachikawa ,  Kasumi Takei

    IPC分类号： C07F708

    CPC分类号： C07F7/14 ,  C07F7/0829 ,  C07F7/1876

    摘要： A method of preparing an organosilicon compound comprising effecting a hydrosilylation reaction between (a) unsaturated compounds with terminal unsaturated groups and (b) silane compounds described by formula HSiR0mW3−m, where W is selected from the group consisting of C1 to C6 alkoxy groups, C6 to C10 aryloxy groups, and halogen atoms, R0 is an organic group, and m is 0, 1, or 2 in the presence of (c) a platinum catalyst and (d) an auxiliary catalyst selected from the group consisting of (1) silyl esters of acids derived from oxo acids of sulfur; (2) amide compounds having N—Si bonds; (3) urea compounds; (4) silyl esters of carbamic acid; (5) phosphoric acid compounds; and (6) cyclic compounds selected from the group consisting of (i) hydroxypyridine compounds, (ii) 8-hydroxyquinoline compounds, (iii) oxazolidinone compounds, and (iv) N-hydroxysuccinimide compounds.

    摘要翻译： 一种制备有机硅化合物的方法，包括在（a）不饱和化合物与末端不饱和基团之间进行氢化硅烷化反应和（b）式HSiR0mW3-m所述的硅烷化合物，其中W选自C1-C6烷氧基， （c）铂催化剂和（d）选自下组的辅助催化剂（1）：（C 1 -C 10）芳氧基和卤素原子，R 0是有机基团，m是0,1或2 ）衍生自硫的含氧酸的酸的甲硅烷基酯; （2）具有N-Si键的酰胺化合物; （3）尿素化合物; （4）氨基甲酸的甲硅烷基酯; （5）磷酸化合物; 和（6）选自（i）羟基吡啶化合物，（ii）8-羟基喹啉化合物，（iii）恶唑烷酮化合物和（iv）N-羟基琥珀酰亚胺化合物的环状化合物。

    Process for the continuous preparation of 3-halopropylorganosilanes
    9.
    发明授权
    Process for the continuous preparation of 3-halopropylorganosilanes 失效
    连续制备3-卤代丙基有机硅烷的方法

    公开(公告)号：US06242630B1

    公开(公告)日：2001-06-05

    申请号：US08908095

    申请日：1997-08-11

    申请人： Stefan Bade ,  Uwe Schoen ,  John Burkhard ,  Franz-Michael Bollenrath ,  Norbert Hofmann ,  Hermann-Josef Korte ,  Hartwig Rauleder ,  Uwe Tanger

    发明人： Stefan Bade ,  Uwe Schoen ,  John Burkhard ,  Franz-Michael Bollenrath ,  Norbert Hofmann ,  Hermann-Josef Korte ,  Hartwig Rauleder ,  Uwe Tanger

    IPC分类号： C07F708

    CPC分类号： C07F7/14 ,  C07F7/0829 ,  C07F7/1876

    摘要： A process for the continuous preparation of 3-halopropylorganosilanes of the general structure RbH3-a-bXaSiCH2CH2CH2Y  (III), where: R is CH3, C2H5, C3H7, OCH3, OC2H5 or OC3H7, X is F, Cl, Br or I, Y is F, Cl, Br or I, and a and b are each one of the numbers 0, 1, 2 or 3 and the sum a+b is 1, 2 or 3, comprising reacting, as starting materials, an allyl halide with a silane carrying at least one H atom, wherein the starting materials are present in stoichiometric amounts or one of the starting materials is present in substoichiometric amounts, wherein the reaction carried out is a partial reaction of from 10% to 80%, on a molar basis, of the starting materials, based on either material, when both are present in stoichiometric amounts, or based on the substoichiometric material.

    摘要翻译： 连续制备通常结构的3-卤代丙基有机硅烷的方法，其中R为CH 3，C 2 H 5，C 3 H 7，OCH 3，OC 2 H 5或OC 3 H 7，X为F，Cl，Br或I，Y为F，Cl，Br或I， 和b分别为数字0,1,2或3中的一个，并且和a + b为1,2或3，包括使烯丙基卤化物与携带至少一个H原子的硅烷作为原料，其中， 原料以化学计量的量存在，或者一种起始原料以亚化学计量的量存在，其中进行的反应是基于摩尔的10％至80％的起始原料的部分反应，基于任一材料 ，当两者都以化学计量的量存在时，或基于亚化学计量的材料。

    Process for the preparation of alkylsilanes with bulky alkyl radicals
    10.
    发明授权
    Process for the preparation of alkylsilanes with bulky alkyl radicals 有权
    用于制备具有大体积烷基的烷基硅烷的方法

    公开(公告)号：US06169196A

    公开(公告)日：2001-01-02

    申请号：US09493396

    申请日：2000-01-28

    申请人： Gilbert Geisberger ,  Tassilo Lindner ,  Rudolf Reitmeier

    发明人： Gilbert Geisberger ,  Tassilo Lindner ,  Rudolf Reitmeier

    IPC分类号： C07F708

    CPC分类号： C07F7/14

    摘要： A process for the preparation of di- and trialkylsilanes of the general formula (I) RaR1bSiXc  (I), in which mono- or dialkylsilanes of the general formula (II) R1bSiHaXc  (II) are reacted with alkenes A which have at least 3 carbon atoms and are optionally substituted by fluorine, chlorine or bromine atoms or cyano groups, in the presence of a transition metal catalyst and a trihalogenosilane of the general formula (III) R2SiY3  (III) as an activator, wherein, in the above general formulae (I) to (III), R is a branched or cyclic hydrocarbon radical having at least 3 carbon atoms, optionally substituted by fluorine, chlorine, or bromine, or cyano groups, R1 is an alkyl radical optionally substituted by fluorine, chlorine, or bromine, or cyano groups, R2 is a hydrogen atom, or an alkyl radical optionally substituted by fluorine, chlorine, or bromine, or cyano groups, X is fluorine, chlorine, or bromine, or an alkoxy radical having 1 to 18 carbon atoms optionally substituted by fluorine, chlorine, or bromine, or cyano groups, Y is fluorine, chlorine or bromine, a is 1 or 2, b is 1 or 2, and c is 1 or 2.

    摘要翻译： 制备通式（I）的二 - 和三烷基硅烷的方法，其中通式（II）的单 - 或二烷基硅烷与具有至少3个碳原子且任选被氟，氯或氯原子取代的烯烃A反应 溴原子或氰基，在过渡金属催化剂和通式（III）的三卤代硅烷的存在下作为活化剂，其中在上述通式（I）至（III）中，R是支链或环状烃 具有至少3个碳原子的基团，任选被氟，氯或溴或氰基取代，R 1是任选被氟，氯或溴或氰基取代的烷基，R 2是氢原子或烷基 任选被氟，氯或溴或氰基取代的基团，X是氟，氯或溴，或具有任选被氟，氯或溴或氰基取代的具有1至18个碳原子的烷氧基，Y是 氟，c 芴或溴，a为1或2，b为1或2，c为1或2。