摘要:
A process for preparing ethylene amines and ethanolamines by hydrogenative amination of monoethylene glycol and ammonia in the presence of a catalyst, wherein a catalyst having an active composition comprising ruthenium and cobalt and no further additional metal of group VIII and also no metal of group IB is used in the form of shaped catalyst bodies which in the case of a spherical shape or rod shape in each case have a diameter of
摘要:
A process for preparing ethylene amines and ethanolamines by hydrogenative amination of monoethylene glycol and ammonia in the presence of a catalyst, wherein the process is carried out in two process stages in whichin the first process stage, the amination is carried out over a hydroamination catalyst to a monoethylene glycol conversion of not more than 40% andin the second process stage, a supported catalyst having an active composition comprising ruthenium and cobalt and no further additional metal of group VIII and also no metal of group IB is used in the form of shaped catalyst bodies which in the case of a spherical shape or rod shape in each case have a diameter of
摘要:
Processes comprising: providing a mixture comprising monoethylene glycol and diethylenetriamine; and subjecting the mixture to extractive distillation with a diethylenetriamine-selective solvent comprising triethylene glycol to provide a first stream comprising monoethylene glycol and a second stream comprising diethylenetriamine; wherein the first stream is substantially free of diethylenetriamine, and wherein the second stream is substantially free of monoethylene glycol.
摘要:
A process for preparing ethylene amines and ethanolamines by hydrogenative amination of monoethylene glycol and ammonia in the presence of a catalyst, wherein the process is carried out in two process stages in which in the first process stage, the amination is carried out over a hydroamination catalyst to a monoethylene glycol conversion of not more than 40% and in the second process stage, a supported catalyst having an active composition comprising ruthenium and cobalt and no further additional metal of group VIII and also no metal of group IB is used in the form of shaped catalyst bodies which in the case of a spherical shape or rod shape in each case have a diameter of
摘要:
Processes comprising: providing a mixture comprising monoethylene glycol and diethylenetriamine; and subjecting the mixture to extractive distillation with a diethylenetriamine-selective solvent comprising triethylene glycol to provide a first stream comprising monoethylene glycol and a second stream comprising diethylenetriamine; wherein the first stream is substantially free of diethylenetriamine, and wherein the second stream is substantially free of monoethylene glycol.
摘要:
A process for preparing ethylene amines and ethanolamines by hydrogenative amination of monoethylene glycol and ammonia in the presence of a catalyst, wherein a catalyst having an active composition comprising ruthenium and cobalt and no further additional metal of group VIII and also no metal of group IB is used in the form of shaped catalyst bodies which in the case of a spherical shape or rod shape in each case have a diameter of
摘要:
Processes comprising: providing a starting material comprising monoethanolamine; and reacting the starting material with ammonia in the presence of a heterogeneous transition metal catalyst to form a reaction product comprising one or more ethylene amines; wherein the catalyst comprises a catalytically active composition, which prior to treatment with hydrogen, comprises a mixture of oxygen-containing compounds of aluminum, copper, nickel and cobalt; and wherein the catalyst is present as one or more shaped catalyst particles selected from spheres, extrudates, pellets and other geometries, wherein the sphere or extrudate has a diameter of
摘要:
The present invention relates to an amine composition comprising linear triethylene-tetramine and one or more amine compounds selected from the group consisting of tertiary amines derived from the condensation of ethylenediamine and methyl-substituted compounds derived from linear triethylenetetramine as well as a method of production for said composition.The present invention also relates to the use of linear triethylenetetramine or an amine composition according to the invention as amine curing agents.The present invention also relates to amine curing agent compositions comprising linear triethylenetetramine as well as to curable compositions comprising linear triethylenetetramine and to a method for producing said curable compositions.Additionally, the present invention relates to a cured epoxy resin comprising linear triethylenetetramine, especially a reinforced composite, and a method for producing said cured epoxy resins.Furthermore, the present invention relates to reactive polyamide resins obtainable from linear triethylenediamine and dimer fatty acids.
摘要:
Processes are described comprising: (i) providing a reactant comprising 1,2-dichloroethane; and (ii) reacting the reactant with ammonia to form a reaction product comprising one or more ethylene amines and hydrogen chloride, wherein the reaction is carried out in the presence of an organic, nitrogen- or phosphorus-containing compound which reacts with the hydrogen chloride to form an ionic liquid.
摘要:
Processes are described comprising: (i) providing a reactant comprising 1,2-dichloroethane; and (ii) reacting the reactant with ammonia to form a reaction product comprising one or more ethylene amines and hydrogen chloride, wherein the reaction is carried out in the presence of an organic, nitrogen- or phosphorus-containing compound which reacts with the hydrogen chloride to form an ionic liquid.